Emission dynamics of reactive oxygen species and oxidative potential in particles from a petrol car and wood stove
Aerosol Research,
Journal Year:
2025,
Volume and Issue:
3(1), P. 205 - 218
Published: April 22, 2025
Abstract.
Air
pollution
is
one
of
the
largest
environmental
health
risks
and
leading
causes
adverse
outcomes
mortality
worldwide.
The
possible
importance
oxidative
potential
(OP)
as
a
metric
to
quantify
particle
toxicity
in
air
increasingly
being
recognised.
In
this
work,
OP
reactive
oxygen
species
(ROS)
activity
particles
from
fresh
aged
petrol
passenger
car
emissions
residential
wood
combustion
(RWC)
were
investigated
using
two
novel
instruments.
Applying
online
instruments
an
ascorbic
acid
(AA)
2′,7′-dichlorodihydrofluorescein
(DCFH)
assay
provides
much
higher
temporal
resolution
compared
with
traditional
filter-based
methods
allows
for
new
insights
into
highly
dynamic
changes
ROS
these
sources.
Due
efficiency
particulate
filter
Euro
6d
car,
almost
no
primary
emitted
and,
thus,
or
was
detected
exhaust.
However,
substantial
ROSs
observed
after
photochemical
ageing
due
formation
secondary
particles.
Increasing
also
when
comparing
RWC
emissions.
Overall,
had
signals
This
suggests
that
could
be
major
contributor
may
intrinsically
more
harmful
emission
source
than
exhaust,
although
still
high.
These
measurements
illustrate
strong
differences
nature
toxicity-relevant
properties
sources
contribute
efficient
mitigation
policies.
Language: Английский
Real world particle size distribution from vehicle fleet and implication on emission control
Published: April 28, 2025
Abstract
Particle
size
distribution
(PSD)
of
vehicular
emissions
is
crucial
for
assessing
their
impacts
on
air
quality
and
human
health.
However,
real-world
PSD
data
from
vehicle
fleets
scarce.
Here,
we
conducted
a
two-week
tunnel
measurement
fleet
emission.
The
estimated
fleet-average
emission
factor
particle
number
(PN)
was
2.6
×
10
14
kg-fuel
−1
.
peaked
in
nucleation
mode,
indicating
significant
role
volatile
particles
likely
formed
outside
exhaust
pipes.
Diurnal
variations
PN
correlated
with
traffic
flow;
however,
high-emitting
diesel
vehicles,
particularly
those
other
cities,
caused
notable
spikes
black
carbon
during
off-peak
hours.
Positive
matrix
factorization
analysis
confirms
this
critical
vehicles
also
reveals
the
dominance
non-exhaust
PM
2.5
This
study
highlights
importance
stricter
regulations
measures
to
mitigate
mode
particles.
Language: Английский