Atomically Dispersed Metal Catalysts for the Conversion of CO2 into High‐Value C2+ Chemicals DOI
Qihao Yang,

Hao Liu,

Yichao Lin

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(37)

Published: May 19, 2024

Abstract The conversion of carbon dioxide (CO 2 ) into value‐added chemicals with two or more carbons (C 2+ is a promising strategy that cannot only mitigate anthropogenic CO emissions but also reduce the excessive dependence on fossil feedstocks. In recent years, atomically dispersed metal catalysts (ADCs), including single‐atom (SACs), dual‐atom (DACs), and single‐cluster (SCCs), emerged as attractive candidates for fixation reactions due to their unique properties, such maximum utilization active sites, tunable electronic structure, efficient elucidation catalytic mechanism, etc. This review provides an overview significant progress in synthesis characterization ADCs utilized photocatalytic, electrocatalytic, thermocatalytic toward high‐value C compounds. To provide insights designing chemical originating from , key factors influence activity selectivity are highlighted. Finally, relevant challenges opportunities discussed inspire new ideas generation ‐based products over ADCs.

Language: Английский

Modification engineering over single-atom catalysts for efficient heterogeneous photocatalysis DOI

Hongda Liu,

Weiping Xiong, Chengyun Zhou

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 529, P. 216468 - 216468

Published: Jan. 21, 2025

Language: Английский

Citations

2
Recent advances and challenges of double-atom catalysts in diverse environmental applications: A state-of-the-art review DOI
Tong Hu, Wenjun Zhou,

Wangwang Tang

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 532, P. 216545 - 216545

Published: Feb. 19, 2025

Language: Английский

Citations

2
Boosting Electrocatalytic Carbon Dioxide Reduction via Self‐Relaxation of Asymmetric Coordination in Fe‐Based Single Atom Catalyst DOI

Zhaoyong Jin,

Dongxu Jiao,

Yilong Dong

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 63(6)

Published: Dec. 16, 2023

Addressing the limitations arising from consistent catalytic behavior observed for various intermediates during electrochemical carbon dioxide reduction reaction (CO

Language: Английский

Citations

40
Recent Advances in Electrochemical CO2‐to‐Multicarbon Conversion: From Fundamentals to Industrialization DOI
Changli Wang,

Zunhang Lv,

Xiao Feng

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(47)

Published: Nov. 2, 2023

Abstract The electrochemical CO 2 (eCO )‐to‐multicarbon conversion with higher value is regarded as a potential way to promote the transformation of industrial production and green balance carbon cycle. Recently, series advances have been achieved in progress eCO ‐to‐multicarbon conversion, including in‐depth exploration coupling mechanisms, up‐to‐date development characterization techniques, novel interdisciplinary design strategies catalysts electrolytic systems. Therefore, it essential systematically overview from fundamentals industrialization, compensating for limited insufficient reviews that reported. To fill aforementioned research gap, this focused on industrialization. First, possible catalytic mechanisms are accordingly summarized order reduction, small molecule‐coupled tandem conversion. Second, situ technologies assisting rationalization presented. Third, optimizing systems briefly classified advance industrialization process. Finally, challenges perspectives further reasonably proposed, aiming offer insights following work field.

Language: Английский

Citations

31
Adjacent Metal Atomic Pairs Within Atomically Dispersed Catalysts for Reaching a Synergistic Electrocatalytic CO2 Reduction: A Review DOI
Changli Wang,

Zunhang Lv,

Xiao Feng

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(21)

Published: Feb. 27, 2024

Abstract In response to the global climate change and energy crisis, electrocatalytic CO 2 reduction reaction (ECR) is regarded as one of potential ways simultaneously reach conversion obtain various value‐added products. Currently, several challenges remain for in‐depth understanding ECR from fundamentals, including ambiguous structure‐activity relationships, uncontrollable catalytic selectivity, complex mechanisms. Compared traditional metal nanoparticle‐based materials, atomically dispersed catalysts (ADCs) have aroused significant interest owing their maximal atomic utilization simplified site configuration, offering a superior platform discussing relationships during ECR. Especially, adjacent pairs (AAPs) within ADCs are gradually emphasized novel concept follow synergistic mechanisms Herein, first time broad AAPs analyzed how reached effect summarized. view varying on different supports, three types supports illustrated (containing graphene model, functional porous frameworks, metals oxides), aiming help scholars with more insights in broadening feasible ADCs.

Language: Английский

Citations

14
Advancing Electrically Conductive Metal–Organic Frameworks for Photocatalytic Energy Conversion DOI
Xiaoyu Fang, Ji Yong Choi, Michael Stodolka

et al.

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(16), P. 2316 - 2325

Published: Aug. 7, 2024

ConspectusPhotocatalytic energy conversion is a pivotal process for harnessing solar to produce chemicals and presents sustainable alternative fossil fuels. Key strategies enhance photocatalytic efficiency include facilitating mass transport reactant adsorption, improving light absorption, promoting electron hole separation suppress electron-hole recombination. This Account delves into the potential advantages of electrically conductive metal-organic frameworks (EC-MOFs) in examines how manipulating electronic structures controlling morphology defects affect their unique properties, potentially impacting selectivity. Moreover, with proof-of-concept study hydrogen peroxide production by EC-MOF's structure, we highlight outlined this Account.EC-MOFs not only possess porosity surface areas like conventional MOFs, but exhibit conductivity through d-p conjugation between ligands metal nodes, enabling effective charge transport. Their narrow band gaps also allow visible making them promising candidates efficient photocatalysts. In EC-MOFs, modular design nodes allows fine-tuning both structure physical including particle morphology, which essential optimizing positions achieve selective conversion.Despite as photocatalysts, modulating or EC-MOFs nontrivial, fast growth kinetics make prone defect formation, To fully leverage discuss our group's efforts manipulate develop synthetic control healing. For tuning structures, diversifying combinations metals linkers available EC-MOF synthesis has been explored. Next, suggest that synthesizing ligand-based solid solutions will enable continuous positions, demonstrating distinguish reactions similar redox potentials. Lastly, present incorporating donor-acceptor system an spatially separate photogenerated carriers, could As strategy control, demonstrated electrosynthesis can modify enhancing electrochemical area, be beneficial adsorption. Finally, healing reducing traps on defects, efficiency.Our vision introduce platform conversion. Although are new class semiconductor materials have extensively studied conversion, inherent absorption properties indicate significant potential. We envision employing molecular applying customize repair promote separation, transfer reactants, realize high selectivity EC-MOF-based effort lays foundation rational advance use

Language: Английский

Citations

14
Metal-organic framework-derived diatomic catalysts for environmental remediation: Synthesis, applications and improvement strategies DOI
Tong Hu, Wenjun Zhou,

Wangwang Tang

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 526, P. 216357 - 216357

Published: Nov. 29, 2024

Language: Английский

Citations

14
Highly efficient CO2 electrochemical reduction on dual metal (Co–Ni)–nitrogen sites DOI Creative Commons
Jianping Chen,

Md Robayet Ahasan,

Jin‐Su Oh

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(8), P. 4601 - 4609

Published: Jan. 1, 2024

A new Co–Ni–N–C electrocatalyst for CO 2 reduction, featuring diatomic metal-nitrogen sites on N-doped carbon, has been developed. It shows high yield and faradaic efficiency, promising various electrochemical reactions.

Language: Английский

Citations

13
Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO2 Capture and Conversion DOI
Shangqing Chen, Ningyuan Wang, Huaidong Zhang

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2024, Volume and Issue: 63(8), P. 3443 - 3464

Published: Feb. 14, 2024

CO2 capture and conversion have garnered worldwide attention in view of the objective sustainable development carbon neutrality. Recently, ionic liquid-functionalized metal–organic frameworks (MOFs) or covalent–organic (COFs) (MOFs/COFs) offer a rising platform for effective separation from specific gas mixture into value-added chemicals. Benefiting synergistic effect offered by ILs MOFs/COFs, IL-MOFs/COFs exhibit better exceptional adsorption/catalytic performance than pristine MOFs/COFs ILs. Herein, review intends to establish primary database recently emerging conversion, covering functionalization strategies, interaction between representative applications, aiding rational design optimization novel with properties real-world application. Along this line, different systems (CO2/N2, CO2/CH4, CO2/C2H2) further multiproducts (cyclic carbonate, hydrocarbon, alcohol, others), along mechanism insight such processes are summarized discussed. Furthermore, challenges prospects topical fields been elaborated.

Language: Английский

Citations

12
Improving CO2‐to‐C2 Conversion of Atomic CuFONC Electrocatalysts through F, O‐Codrived Optimization of Local Coordination Environment DOI

Zunhang Lv,

Changli Wang, Yarong Liu

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(21)

Published: Feb. 27, 2024

Abstract Electrocatalytic CO 2 to multi‐carbon products is an attractive strategy achieve a carbon‐neutral energy cycle. Single‐atom catalysts (SACs) that the C selectivity always have low metal loading and inevitably undergo in situ reversible/irreversible metallic agglomerations under working conditions. Herein, high‐density Cu SA anchored F, O, N co‐doped carbon composites (CuFONC) with stable CuN O 1 configuration provided, which can reach remarkable of ≈80.5% Faradaic efficiency at −1.3 V versus RHE. In situ/ex experimental characterization density functional theory (DFT) calculations verified excellent stability during RR process be attributed F/O co‐derived regulation for CuFONC. Remarkably, as confirmed by DFT, it atomic sites adjacent bonded motifs CuFONC act adsorption * C─C coupling process. This work brings prospective on designing novel but coordination electrolytic ‐to‐C pathway.

Language: Английский

Citations

12