Cited by Dual-functional tartaric acid additive realizing high-quality perovskite film through chemical passivation and crystallization regulation

Optimized Crystallization via Ionic Liquid Engineering for Air‐Fabricated Perovskite Solar Cells with Efficiency of 25.11% DOI

Shiying Tang,

Yunsheng Gou,

Deng Chen

et al.

Solar RRL, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

The premature reaction of PbI 2 with organic cations in perovskite (PVK) precursor solutions often leads to compromised film quality. To mitigate this, the ionic liquid (IL) pyridinium trifluoromethanesulfonate is introduced into solution. strong interaction between and promotes formation nucleation clusters, effectively lowering barrier regulating crystallization perovskite, resulting high‐quality, homogeneous PVK films. In situ characterization shows that prenucleation strategy yields films an average grain size exceeding 1 μm. hydrophobicity trifluoromethyl group modulates humidity, facilitating moist environments. This contrast typical negative effects moisture, which can induce defects structures. As a result, IL‐modified solar cells (PSCs) achieved remarkable power conversion efficiency (PCE) 25.11% under ambient conditions. These PSCs retained 80.43% their initial PCE after 820 h continuous maximum point (MPP) tracking. Furthermore, 1000 exposure air 30%–50% relative humidity (RH) at room temperature, devices maintained 87% efficiency, demonstrating excellent stability for long‐term PSC applications.

Language: Английский

Citations

Unleashing the power of chelation: a universal π-conjugated ligand for enhanced crystallization and defect passivation in perovskite photovoltaics DOI

Yangdi Chen,

Wenfeng Zhang, Jun Qu

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

Thiourea derivative induced crystallization for enhanced efficiency and stability of perovskite solar cells over 25% DOI

You Liu,

Hanzhong Xu,

Shulei Ji

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

Ambipolar Interfacial Molecule for Enhancing Performances of Perovskite Solar Cells with Versatile Architectures Under Various Illumination Environments DOI

Min Jun Choi,

Seok Woo Lee,

Hongjae Shim

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 21, 2025

Abstract Perovskite solar cells (PSCs) are of significant interest for researchers as the next‐generation energy harvesters. However, PSCs suffer from traps that densely distributed at interfaces, which deteriorate device's performance. To address this issue, a new small molecule (DTAQTPPO) capable trap passivation on perovskite layer surface while possessing ambipolar charge extraction properties is designed, endow DTAQTPPO with dual functionality both interface defect passivator and efficient hole/electron extractor in n‐i‐p p‐i‐n architectures. These beneficial effects improve power conversion efficiencies (PCEs) to 23.03% 23.55% under 1 sun 37.18% 36.29% 1000 lux light‐emitting diode (LED) indoor illuminations architectures, respectively, after incorporating DTAQTPPO. In addition, enhance PV using an anti‐solvent‐free PCE 23.24% 35.47% LED illumination, respectively. results suggest can be widely used multifunctional interlayer versatile device architectures various light illumination conditions generality different perovskites processes.

Language: Английский

Citations

Dual-functional tartaric acid additive realizing high-quality perovskite film through chemical passivation and crystallization regulation DOI

Yanyan Wang, Xiaoguo Li,

Chongyuan Li

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 1, 2025

Language: Английский

Citations