Dimensional effect of oxide-derived Cu elelctrocatalysts to reduce CO2 into multicarbon compounds DOI
Minfang Wu, Chang Zhu, Jianing Mao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156006 - 156006

Published: Sept. 1, 2024

Language: Английский

CO2 electrolysis to multi-carbon products in strong acid at ampere-current levels on La-Cu spheres with channels DOI Creative Commons
Jiaqi Feng, Limin Wu, Xinning Song

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: June 6, 2024

Abstract Achieving satisfactory multi-carbon (C 2+ ) products selectivity and current density under acidic condition is a key issue for practical application of electrochemical CO 2 reduction reaction (CO RR), but challenging. Herein, we demonstrate that combining microenvironment modulation by porous channel structure intrinsic catalytic activity enhancement via doping effect could promote efficient RR toward C in electrolyte (pH ≤ 1). The La-doped Cu hollow sphere with channels exhibits Faradaic efficiency (FE) 86.2% partial −775.8 mA cm −2 . single-pass conversion can reach 52.8% at −900 Moreover, the catalyst still maintains high FE 81.3% −1 A plays crucial role accumulating K + OH - species near surface within channels, which effectively suppresses undesired hydrogen evolution promotes C–C coupling. Additionally, La enhances generation *CO intermediate, also facilitates formation.

Language: Английский

Citations

56
Reaction Environment Regulation for Electrocatalytic CO2 Reduction in Acids DOI
Min Zeng,

Wensheng Fang,

Yiren Cen

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(26)

Published: April 19, 2024

The electrocatalytic CO

Language: Английский

Citations

51
Recent Advances and Challenges in Efficient Selective Photocatalytic CO2 Methanation DOI

Piyan Wang,

Fengyi Yang, Jiafu Qu

et al.

Small, Journal Year: 2024, Volume and Issue: 20(32)

Published: March 15, 2024

Abstract Solar‐driven carbon dioxide (CO 2 ) methanation holds significant research value in the context of emission reduction and energy crisis. However, this eight‐electron catalytic reaction presents substantial challenges activity selectivity. In regard, researchers have conducted extensive exploration achieved developments. This review provides an overview recent advances efficient selective photocatalytic CO methanation. It begins by discussing fundamental principles detail, analyzing strategies for improving efficiency conversion to CH 4 comprehensively. Subsequently, it outlines applications advanced characterization methods Finally, highlights prospects opportunities area, aiming inspire into high‐value shed light on mechanisms.

Language: Английский

Citations

18
Cu promoted electron-rich Bi sites in Metal–Organic layers for Industrial-current-level acidic electroreduction CO2 to liquid Fuel DOI
Yating Wang, Wei Chen, Yuhang Li

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 686, P. 1168 - 1174

Published: Feb. 4, 2025

Language: Английский

Citations

2
Robust and efficient electroreduction of CO2 to CO in a modified zero-gap electrochemical cell DOI Creative Commons

Siyu Zhong,

Peng‐Fei Sui, Peter Holtappels

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161119 - 161119

Published: Feb. 1, 2025

Language: Английский

Citations

2
Advances in CO2 Electroreduction over Hollow Fiber Gas Diffusion Electrodes DOI

Yuanlin Gao,

Xiaoyue Tu,

Xiangjian Liu

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: unknown

Published: April 2, 2024

Abstract CO 2 electroreduction (CO RR) to high‐value chemicals by renewable energy is a promising route for achieving carbon cycling. Traditional two‐dimensional planar electrodes applied in RR are faced with problems of high mass transfer resistance, carbonate precipitation, flooding, and complicated structures, seriously limiting their efficiency application. Three‐dimensional hollow fiber gas diffusion (HFGDEs) candidates due rich specific surface area, low simplified component, no flooding trouble, which beneficial current density as well efficiency. In this review, we provide inspirations positive paradigms the rational design HFGDE toward following part: 1. The mechanism RR. 2. classification typical metal‐based catalysts. 3. preparation process HFGDEs. 4. Recent advanced studies 5. Challenges at stage future development HFGDEs towards accelerating application industrial reduction electrolyzers.

Language: Английский

Citations

8
Polymeric ionic liquid promotes acidic electrocatalytic CO2 conversion to multicarbon products with ampere level current on Cu DOI Creative Commons

Zhonghao Tan,

Jianling Zhang,

Yisen Yang

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Feb. 21, 2025

The acidic electroreduction of CO2 into multicarbon (C2+) products is much attractive for the improved carbon utilization than alkaline or neutral electroreduction. How to improve efficiency C2+ generation by CO2, important, especially at high current density and in electrolyte with low K+ concentration. Herein, we propose a strategy capping Cu surface polymeric ionic liquid (PIL) adlayer boosting electrocatalytic conversion densities (ampere-level) In relatively concentration (1.0 M), Faradaic (FE) reaches 82.2% under 1.0 A·cm−2 environment (pH=1.8). Particularly, when as 1.5 A·cm−2, FE still keeps 75.8%. Experimental theoretical studies reveal that presence PIL on catalyst can well inhibit H+ diffusion surface, enrich more facilitate C-C coupling reaction. Acidic reduction promising way utilization, which selectivity activity need improvement. Here, authors report boost ampere level density.

Language: Английский

Citations

1
Halide-modulated Hollow-Fiber Cu penetration electrode boosts Ampere-Level CO2 electroreduction to multicarbon products DOI
Chang Zhu, Gangfeng Wu, Jianing Mao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 485, P. 150040 - 150040

Published: Feb. 27, 2024

Language: Английский

Citations

6
Industrial‐Level Modulation of Catalyst‐Electrolyte Microenvironment for Electrocatalytic CO2 Reduction: Challenges and Advancements DOI
Weiyi Liu,

Zunhang Lv,

Changli Wang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 9, 2024

Abstract CO 2 reduction reaction (CO RR), as a promising strategy for storing renewable energy and promoting carbon resource recycling, is critical industrial development. Previous reports have extensively explored catalyst‐electrolyte microenvironmental modulation to elucidate coupling mechanisms enhance catalytic conversion multicarbon products. Currently, most reviews mainly focus on the impact of microenvironment in low‐current systems mechanism exploration performance optimization, yet few them can integrate macroscopic applications with microscopic investigations explore relevance between development optimization. To address gap, this review focuses summarizing challenges advancements high‐current devices. By introducing models different scales sequentially, connection device clarified. Then, various invalidation effective solutions are summarized intuitively expound stability. Meanwhile, an intuitive measure rationality modulation, evaluation methods should be refined, which also covered further detail below. Finally, more valuable challenging prospects discussed guiding transformation RR.

Language: Английский

Citations

6
Cobalt(II) tetraphenylporphyrin trapped in the pores of Cu2O to enhance the C2+ selectivity towards acidic CO2 electroreduction DOI

Yuda Wang,

Qingqing Cheng, Hui Zhang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 492, P. 152254 - 152254

Published: May 14, 2024

Language: Английский

Citations

5