Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Language: Английский
Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179306 - 179306
Published: Feb. 1, 2025
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125177 - 125177
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Molecular Modeling, Journal Year: 2025, Volume and Issue: 31(3)
Published: Feb. 25, 2025
Language: Английский
Citations
0Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown
Published: March 6, 2025
Electrochemical treatment of urea wastewater purification significantly aids in environmental protection, but it remains a considerable challenge designing high performance anode oxidation electrocatalysts. Herein, we report La-induced three-dimensional ordered macroporous (3DOM) NiO heterostructure to improve Ni sites electron density for electrooxidation by activating the La-O-Ni bridge. This material demonstrated exceptional membrane electrode assembly (MEA) device, characterized low cell voltage (1.49 V @ 80 °C) and 280 h stability test at 1 A cm-2 current (25 displayed promising efficiency purification. Permeation experiments revealed crucial role 3DOM morphological facilitating mass transfer processes. valence nickel mechanism (HNM) on bridge during catalysis was proposed, based various situ characterizations theoretical calculations. Experimentally, Raman UV-vis spectra that active species Niδ+ (δ≥3) promote kinetics, while ATR-IR proved strong adsorption C=O with enhancement N-H bonds cleavage, supporting HNM. work enables us underscore critical importance architectures contributions
Language: Английский
Citations
0Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Language: Английский
Citations
0