Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer DOI

Sheng-Ping Liu,

Lan Yang,

Yan‐Hong He

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A photoinduced FeCl 3 /HCl synergistic catalytic method enables C(sp )–S bond formation via reductive cross-coupling of activated/inert )–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).

Language: Английский

Synthesis of Diverse 4‐Pyrrolin‐2‐ones by Electrochemically Induced Dehydrogenative Regioselective Cyclization of 3‐Aza‐1,5‐dienes and 1,3‐Dicarbonyl Compounds DOI
Xing Ji,

Run He,

Lou Shi

et al.

European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(11)

Published: Jan. 20, 2024

Abstract A practical and mild electrochemical dehydrogenative regioselective cyclization method has been established for the synthesis of 4‐pyrrolin‐2‐ones using 3‐aza‐1,5‐dienes 1,3‐dicarbonyl compounds as substrates. This protocol is catalyst‐free, metal‐free, does not require oxidizing agents. It exhibits wide substrate compatibility can be easily scaled up to gram scale.

Language: Английский

Citations

9
Electrochemical Sulfonylation/Cyclization of N-Alkenylacrylamides with Sodium Sulfinates or Sulfonyl Hydrazides DOI
Zhixian Yang,

Lu-Cai Ding,

Gui-Hong Yang

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(15), P. 10660 - 10677

Published: July 18, 2024

Two general protocols for the regioselective electrochemically enabled sulfonylation cyclization of

Language: Английский

Citations

8
Advances and perspectives on photochemical/electrochemical synthesis of nitrogen, sulfur, and phosphorus heteroatom containing compounds from biomass-based feedstocks DOI

Hanjing Tian,

Anping Wang, Pan Hu

et al.

Industrial Crops and Products, Journal Year: 2024, Volume and Issue: 222, P. 119738 - 119738

Published: Sept. 27, 2024

Language: Английский

Citations

4
General Electron-Donor-Acceptor Complex Mediated Thioesterification Reaction via Site-Selective C-H Functionalization using Aryl Sulfonium Salts DOI

Roshan I. Patel,

Barakha Saxena,

Anuj Sharma

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(19), P. 10265 - 10274

Published: Jan. 1, 2024

We herein describe a versatile electron–donor–acceptor (EDA) mediated thioesterification reaction using aryl sulfonium salt (acceptor) with potassium thioacid salts (donor) under visible light irradiation.

Language: Английский

Citations

3
Synthesis of thioesters using an electrochemical three-component reaction involving elemental sulfur DOI

Gongbo Liu,

Shuoyu Xu,

Yangyang Yue

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(48), P. 6154 - 6157

Published: Jan. 1, 2024

An electrochemical three-component reaction involving elemental sulfur is disclosed for achieving a metal-free, oxidant-free synthesis of thioesters in high atom-economical, step-economical and chemoselective manner.

Language: Английский

Citations

1
Palladium‐Catalyzed Carbonylative Transformation for the Synthesis of Tetracyclic Indoline Thioesters DOI
Ming Li,

Guo-Xiao Zhao,

Shan-Mei Xu

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(15), P. 3367 - 3371

Published: June 14, 2024

Abstract Palladium‐catalyzed thioesterification of (aza)indole‐tethered aryl iodides, Mo(CO) 6 , and sulfonyl chlorides is reported. A series C2 thioester‐group substituted indoline‐fused ring compounds are constructed by an intramolecular Heck cyclization carbonylation chemistry involving N ‐(2‐iodobenzoyl)indole. The salient features this three‐component cascade sequence include the use solid as carbon monoxide source good functional group tolerance.

Language: Английский

Citations

1
Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer DOI

Sheng-Ping Liu,

Lan Yang,

Yan‐Hong He

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A photoinduced FeCl 3 /HCl synergistic catalytic method enables C(sp )–S bond formation via reductive cross-coupling of activated/inert )–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).

Language: Английский

Citations

1