Journal of Sulfur Chemistry,
Journal Year:
2024,
Volume and Issue:
45(4), P. 477 - 489
Published: June 2, 2024
Three
novel
organotellurium
(IV)
derivatives
of
diphenyldithiocarbamate,
C4H8Te[(CS2)
N(C6H5)2]2
(1),
(C2H5)2Te[(CS2)
(2),
and
C4H7(CH3)Te[(CS2)
(3)
have
been
synthesized
by
the
reaction
sodium
salt
diphenyl
dithiocarbamate
with
C4H8TeI2,
(C2H5)2TeI2,
C4H7(CH3)TeI2
respectively.
The
compounds
1–3
were
characterized
elemental
analysis,
IR,
1H
NMR,
13C{1H}
NMR
spectroscopic
studies.
antimicrobial
efficacy
was
examined
against
selected
bacterial
fungal
strains
using
broth
microdilution
disc
diffusion
methods.
Penicillin
amphotericin
B
used
as
a
positive
control
for
highest
activity
shown
compound
3
while
strain
1
showed
MIC
value
6.25
µg/ml.
However,
all
high
to
moderate
activity.
The Journal of Organic Chemistry,
Journal Year:
2023,
Volume and Issue:
88(24), P. 17511 - 17520
Published: Nov. 29, 2023
Despite
the
widespread
applications
of
sulfoximines,
green
and
efficient
access
to
functionalized
sulfoximines
remains
a
challenge.
By
employing
an
electrochemical
strategy,
we
describe
approach
for
construction
N-aroylsulfoximines,
which
features
broad
substrate
scope,
mild
reaction
conditions,
safety
on
gram
scale,
no
need
external
oxidant
transition
metal
catalysts.
Journal of Sulfur Chemistry,
Journal Year:
2024,
Volume and Issue:
45(4), P. 477 - 489
Published: June 2, 2024
Three
novel
organotellurium
(IV)
derivatives
of
diphenyldithiocarbamate,
C4H8Te[(CS2)
N(C6H5)2]2
(1),
(C2H5)2Te[(CS2)
(2),
and
C4H7(CH3)Te[(CS2)
(3)
have
been
synthesized
by
the
reaction
sodium
salt
diphenyl
dithiocarbamate
with
C4H8TeI2,
(C2H5)2TeI2,
C4H7(CH3)TeI2
respectively.
The
compounds
1–3
were
characterized
elemental
analysis,
IR,
1H
NMR,
13C{1H}
NMR
spectroscopic
studies.
antimicrobial
efficacy
was
examined
against
selected
bacterial
fungal
strains
using
broth
microdilution
disc
diffusion
methods.
Penicillin
amphotericin
B
used
as
a
positive
control
for
highest
activity
shown
compound
3
while
strain
1
showed
MIC
value
6.25
µg/ml.
However,
all
high
to
moderate
activity.