Ionic liquid functionalized bimetallic UiO-66-Br with multiple active sites for efficient catalytic oxidative carboxylation of olefins and CO2 DOI
Yuanyuan Cui, Jianmin Sun

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131352 - 131352

Published: Dec. 1, 2024

Language: Английский

Evaluating metal-free quaternized boronate esters as efficient catalysts for the fixation of CO2 with epoxides to form cyclic carbonates under suitable conditions DOI
Eyyup Yasar, Emine Aytar, Ahmet Kılıç

et al.

Reaction Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 9(11), P. 2938 - 2953

Published: Jan. 1, 2024

The conversion of CO 2 into high value-added chemicals is receiving increasing attention from the scientific community, commercial enterprises, and policymakers due to environmental problems like global warming.

Language: Английский

Citations

10
The efficient and reusable imidazolium-organoboron catalysts for green CO2 insertion reactions in solvent-free under atmospheric and high-pressure conditions DOI
Emine Aytar, Eyyup Yasar, Ahmet Kılıç

et al.

Fuel, Journal Year: 2024, Volume and Issue: 378, P. 132867 - 132867

Published: Aug. 24, 2024

Language: Английский

Citations

9
Catalytic Strategies for the Cycloaddition of CO2 to Epoxides in Aqueous Media to Enhance the Activity and Recyclability of Molecular Organocatalysts DOI Creative Commons

Niracha Tangyen,

Wuttichai Natongchai,

Valerio D’Elia

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(10), P. 2307 - 2307

Published: May 14, 2024

The cycloaddition of CO2 to epoxides afford versatile and useful cyclic carbonate compounds is a highly investigated method for the nonreductive upcycling CO2. One main focuses current research in this area discovery readily available, sustainable, inexpensive catalysts, catalytic methodologies that allow their seamless solvent-free recycling. Water, often regarded as an undesirable pollutant process, progressively emerging helpful reaction component. On one hand, it serves hydrogen bond donor (HBD) enhance performance ionic compounds; on other aqueous media development diverse protocols can boost or ease recycling molecular catalysts. An overview advances use biphasic systems provided work along with recommendations possible future developments.

Language: Английский

Citations

8
Greener preparation of a flexible material based on macaw palm oil derivatives and CO2 DOI
Rafael Turra Alarcon, Caroline Gaglieri, Gilbert Bannach

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(6), P. 3261 - 3270

Published: Jan. 1, 2024

The polymerization procedure reduces the aminolysis drawback found in conventional synthesis for renewable polyhydroxyurethanes. polymer is from two macaw palm oil derivatives and presents flexible, luminescent, waterproofing features.

Language: Английский

Citations

6
CO2 fixation: cycloaddition of CO2 to epoxides by practical metal-free recyclable catalysts DOI

Wuttichai Natongchai,

Daniel Crespy, Valerio D’Elia

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 25, 2024

Recent works on practical and recyclable catalysts for the cycloaddition of CO 2 to epoxides are reviewed with an eye use inexpensive, readily-available, non-toxic materials future emerging designs.

Language: Английский

Citations

6
2D Co-Based Metal–Organic Framework Nanosheets for the One-Pot Synthesis of Cyclic Carbonates from Olefins and CO2 DOI

Xiaofei Chen,

Shujun Liu, Chongxiong Duan

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2024, Volume and Issue: 63(13), P. 5629 - 5636

Published: March 22, 2024

One-pot catalysis of olefins and CO2 provides an economical energy-efficient way for the fixation production cyclic carbonates. In this work, a two-dimensional Co-1,4-benzenedicarboxylate MOF (2D CoBDC) was synthesized via facile solvothermal reflux method further examined in one-pot synthesis The results activity evaluations detailed kinetics showed that 2D CoBDC exhibited enhanced catalytic performance (92% styrene conversion 85% carbonate yield) under cocatalyst-free conditions 100 °C, 1 bar, 12 h, compared with 3D counterpart. from effectiveness factors Thiele modulus revealed full utilization negligible mass transfer limitations catalyst. A recycle experiment confirmed excellent reusability little loss after at least 5 runs. Finally, possible mechanism reaction catalyzed by proposed.

Language: Английский

Citations

4
Dissociation role on the catalytic activity of organic halides in CO2 conversion to cyclic carbonates: Experimental and computational study DOI Creative Commons
Elisa Hernández, Pablo Navarro, Paolo P. Pescarmona

et al.

Journal of CO2 Utilization, Journal Year: 2024, Volume and Issue: 88, P. 102929 - 102929

Published: Sept. 12, 2024

Language: Английский

Citations

4
Robust Tertiary Amine Suspended HCIPs for Catalytic Conversion of CO2 into Cyclic Carbonates under Mild Conditions DOI

Yanbin Zeng,

Rui Wang,

Zijun Luo

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 10, 2025

A series of tertiary amine suspended hyper-cross-linked ionic polymers (HCIPs), characterized by a rich mesoporous structure, high liquid (IL) density, and good CO2 adsorption capability, were readily prepared via postsynthetic method. The self-polymerization 1,3,5-tris(bromomethyl) benzene (TBB) or its copolymerization with 4,4'-bis(bromomethyl) biphenyl (BBP) in varying ratios, followed grafting N,N,N',N'-tetramethyl-1,3-propanediamine (TMPDA), yielded the target TMPDA-HCIPs. These HCIPs constitute one limited categories heterogeneous water-tolerant catalyst types ever developed for cycloaddition reaction between epoxides. Specifically, chloropropylene carbonate (CPC) was produced 99.9% yield 99% selectivity at 80 °C 1 bar pressure presence 22 mol % water relative to epoxide substrate. Furthermore, when simulated flue gas served as source, same ratio enhanced CPC from 81.9% 91.5% under MPa pressure, only slightly decreasing 94.1%. Additionally, could be easily recovered maintained catalytic performance after six cycles. In conclusion, this study presents robust efficient synthesis cyclic carbonates mild conditions, potentially reducing costs purifying real that contains vapor.

Language: Английский

Citations

0
Preparation of Magnetic Nano-Catalyst Containing Schiff Base Unit and Its Application in the Chemical Fixation of CO2 into Cyclic Carbonates DOI Creative Commons
Na Young Kang,

Yindi Fan,

Dan Li

et al.

Magnetochemistry, Journal Year: 2024, Volume and Issue: 10(5), P. 33 - 33

Published: April 26, 2024

The development of a catalyst for the conversion CO2 and epoxides to corresponding cyclic carbonates is still very attractive topic. Magnetic nano-catalysts are widely used in various organic reactions due their magnetic separation recycling properties. Here, nano-catalyst containing Schiff base unit was designed, synthesized as heterogeneous catalyze form without solvents co-catalysts. characterized using Fourier transform infrared (FTIR), X-ray diffraction (XRD), thermogravimetric (TG), VSM, SEM, TEM BET. results show that has high activity solvent-free cycloaddition reaction with epoxide under mild conditions, easily separated from mixture driven by external force. recovered maintains performance after five cycles.

Language: Английский

Citations

2
Photo-driven CO2 conversion into cyclic carbonates DOI
Yijun Feng, Jianfeng Yao

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 356, P. 130027 - 130027

Published: Oct. 6, 2024

Language: Английский

Citations

2