Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 142, P. 155099 - 155099
Published: May 7, 2024
Language: Английский
Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 142, P. 155099 - 155099
Published: May 7, 2024
Language: Английский
Energy, Journal Year: 2024, Volume and Issue: 292, P. 130474 - 130474
Published: Jan. 27, 2024
Language: Английский
Citations
88Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: 183, P. 514 - 543
Published: Jan. 17, 2024
Language: Английский
Citations
75Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 86, P. 111159 - 111159
Published: March 11, 2024
Language: Английский
Citations
40Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: 183, P. 1258 - 1282
Published: Jan. 19, 2024
Language: Английский
Citations
20The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 9, 2025
In this study, a novel approach that combines photoinduced electron transfer (ET) with hydrogen atom (HAT) has been introduced for the selective β-C(sp3)–H pyridination of carbonyl compounds. This method is notable its absence transition metals and ability to function under benign reaction conditions, resulting in range pyridinated derivatives consistently moderate good yields. The significance technique further underscored by potential late-stage functionalization pharmaceutically significant molecules. Mechanistic investigations confirmed proceeds via radical-mediated pathway.
Language: Английский
Citations
4The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: 90(4), P. 1683 - 1696
Published: Jan. 17, 2025
In the vanguard of sustainable chemistry, pursuit efficient pathways for synthesis alkyl bicyclo[1.1.1]pentane-heteroaryls has captured attention scientific vanguard. We herein report a groundbreaking and eco-conscious multicomponent coupling reaction that paves way alkylation heteroarylation [1.1.1]propellane, process uniquely enabled by photochemical prowess an electron donor–acceptor (EDA) complex. This method is distinguished its minimalist yet powerful approach: devoid transition metals, additives, photosensitizers. Its universality further exemplified seamless compatibility broad spectrum halides heteroarenes under standardized conditions, heralding new era synthetic versatility. The method's practicality underscored capacity late-stage modification pharmaceuticals, offering transformative tool enhancement existing drug molecules. Moreover, facile derivatization synthesized products underscores adaptability potential diverse applications. Our mechanistic studies have elucidated underlying radical-relay pathway, pinpointing pivotal role EDA complex in initiating transformation. discovery not only enriches our fundamental understanding but also opens avenues strategic optimization.
Language: Английский
Citations
4The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 13, 2025
Herein, we report sodium iodide (NaI)-catalyzed decarboxylative C–H alkylation of azauracils with N-hydroxyphthalimide (NHPI) esters facilitated by visible light activation catalytic electron donor–acceptor (EDA) complexes. Control experiments and density functional theory calculations suggest that the coupling reaction proceeds via a transiently assembled EDA complex between NHPI ester NaI in N,N-dimethylacetamide solvent. This synthetic method efficiently applies to primary, secondary, tertiary under mild, photocatalyst-free, redox-neutral conditions, achieving high yields desired alkylated azauracils.
Language: Английский
Citations
2Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 109514 - 109514
Published: Jan. 1, 2024
Language: Английский
Citations
17Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: 35(10), P. 110038 - 110038
Published: May 22, 2024
Language: Английский
Citations
15Journal of Environmental Management, Journal Year: 2024, Volume and Issue: 353, P. 120188 - 120188
Published: Feb. 1, 2024
Language: Английский
Citations
13