Current Green Chemistry,
Journal Year:
2024,
Volume and Issue:
12(2), P. 85 - 116
Published: Sept. 26, 2024
In
the
realm
of
synthetic
organic
chemistry,
environmentally
friendly
manipulation
small
molecules
has
gained
prominence.
One
particularly
promising
approach
is
electrochemical
synthesis,
which
offers
a
green
and
sustainable
alternative
to
using
hazardous
toxic
redox
reagents.
By
harnessing
electric
current
from
renewable
sources
like
sunlight
or
wind,
synthesis
emerges
as
viable
replacement
for
conventional
methods.
This
review
article
provides
comprehensive
exploration
method,
delving
into
its
background
applications
in
synthesizing
transforming
various
molecules,
including
sulfoximines,
isoxazolines,
benzimidazoles,
more.
aims
shed
light
on
potential
greener
more
way
conducting
transformations.
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(10), P. 5824 - 5831
Published: Jan. 1, 2024
An
electrochemical
oxidation-induced
amination
of
simple
alkylarenes
with
sulfoximines
as
a
nitrogen
source
and
5,6-dimethyl-1
H
-benzo[
d
]imidazole
catalyst
was
developed.
Chinese Journal of Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 16, 2025
Comprehensive
Summary
The
N–H
methylsulfoxidation
of
sulfoximines
using
DMSO
as
a
methylsulfinyl
source,
induced
by
electrochemistry,
has
been
developed.
This
method
is
the
first
example
an
electrochemical
reaction
in
which
serves
source.
Unlike
previous
reactions
involving
substrate,
exclusively
proceed
via
radical
mechanisms,
this
follows
S‐cation
pathway.
A
wide
range
N
‐methylsulfinyl
were
successfully
obtained.
Organic Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 15, 2025
The
integration
of
trifluoroacetyl
(CF3CO)
groups
into
organic
skeletons
is
a
key
research
topic
in
synthetic
chemistry
given
their
significant
potential
to
boost
biological
activity.
Despite
recent
developments
strategies
for
incorporating
moiety
via
radical
intermediates,
the
practical
utilization
inexpensive
and
readily
available
trifluoroacetic
acids
as
sources
has
not
yet
been
developed.
Herein,
an
electrochemical
strategy
employed
achieve
deoxygenative
transformation
directly
with
assistance
PPh3.
obtained
radicals
are
then
coupled
sulfoximine
species,
thus
enabling
synthesis
N-trifluoroacetylated
sulfoximines.
Additionally,
other
fluorinated
alkyl
carboxylic
acids,
including
perfluoro-,
difluoro-,
trifluoromethylcarboxylic
can
also
be
efficiently
utilized
under
these
conditions,
leading
corresponding
acylated
Moreover,
trifluoroacetylation
drug-based
molecules
easy
execution
scale-up
experiments
highlight
applicability
this
protocol.
Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(24), P. 4647 - 4653
Published: Nov. 6, 2023
Abstract
Herein,
an
electrochemical
oxidative
approach
for
the
synthesis
of
N‐sulfenyl
and
N‐phosphinyl
sulfoximines
has
been
established
from
readily
available
NH‐sulfoximines
with
thiophenols
diarylphosphine
oxides.
Utilizing
synergistic
effect
halide
salt
oxidation,
desired
products
are
obtained
at
room
temperature
in
absence
any
acidic/basic/metallic
additives.
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
22(29), P. 5907 - 5912
Published: Jan. 1, 2024
An
electrochemically
promoted
oxidative
dehydrogenation
cross-coupling
reaction
between
aldehyde
hydrazones
and
thiophenols
is
demonstrated
for
the
first
time,
which
results
in
a
variety
of
thioetherified
products
moderate
to
excellent
yields.
Chemistry - An Asian Journal,
Journal Year:
2024,
Volume and Issue:
19(23)
Published: Aug. 24, 2024
Abstract
A
zinc‐catalyzed
C(sp
2
)−
N
dehydrative
cross‐coupling
between
carboxylic
acids
and
NH
‐sulfoximines
to
afford
‐aroylated
sulfoximines
under
mild
reaction
conditions
is
described.
Various
were
coupled
with
readily
available
provide
the
corresponding
in
good
excellent
yields.
