Sustainable Waterborne Polyurethane Adhesive With Superstrong Adhesion Performance and Excellent Weatherability from Biomass Lignin and CO2‐Based Polyols DOI Open Access
Rui Li, Lifeng Li, Wenlian Qiu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Abstract Utilizing biomass and CO 2 to synthesize biodegradable reusable polymeric materials is critical for addressing the dual challenges of petrochemical resource depletion environmental pollution. Among emerging alternatives, ‐based polyols (PPC) exhibit exceptional promise in replacing petroleum‐based polyols; while, lignin stands as most abundant aromatic resource. However, integrating these feedstocks produce high‐performance with combined biodegradability, recyclability, reusability remains technically demanding. In this work, a lignin‐based waterborne polyurethane adhesive (LWPU) developed using PPC low‐molecular‐weight (AOH), achieving high solid content (53.2%) outstanding overall properties. The incorporation strengthens hydrogen‐bonding networks increases crosslinking density, thereby enhancing cohesive energy density. optimized LWPU demonstrates robust adhesion on diverse substrates, lap shear strengths reaching 14.7 MPa (wood), 10.6 (steel), 9.0 (aluminum). Notably, it maintains structural integrity under extreme thermal variations (–30 °C 100 °C), high‐humidity (95% ± 5% RH), prolonged ultraviolet (UV) irradiation conditions. Further, lignin‐reinforced dynamic covalent hydrogen bonds impart recyclability adhesives. This methodology establishes sustainable pathway designing bio‐adhesives that synergistically utilize CO₂‐derived feedstocks.

Language: Английский

Multi-Material 3D Printing of Biobased Epoxy Resins DOI Open Access
Matteo Bergoglio, Elisabeth Rossegger, Sandra Schlögl

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(11), P. 1510 - 1510

Published: May 27, 2024

Additive manufacturing (AM) has revolutionised the industry, offering versatile capabilities for creating complex geometries directly from a digital design. Among various 3D printing methods polymers, vat photopolymerisation combines photochemistry and printing. Despite fact that single-epoxy been explored, fabrication of multi-material bioderived epoxy thermosets remains unexplored. This study introduces feasibility potential by means dual-vat Digital Light Processing (DLP) technology, focusing on resins such as ELO (epoxidized linseed oil) DGEVA (vanillin alcohol diglycidyl ether). By integrating different materials with mechanical properties into one sample, this approach enhances sustainability offers versatility applications. Through experimental characterisation, including thermal analysis, demonstrates ability to produce structures composed tailored shapes change demand. The findings underscore promising technology DLP applied sustainable monomers, allowing material production structure fabrication.

Language: Английский

Citations

6

Eco-friendly and novel tannin-based wood adhesive enhanced with cellulose nanofibrils grafted by hyperbranched polyamides DOI
Jinda Peng,

Jiuli Lei,

Fuqi Feng

et al.

Industrial Crops and Products, Journal Year: 2024, Volume and Issue: 222, P. 119576 - 119576

Published: Sept. 7, 2024

Language: Английский

Citations

4

Ballistic Performance of Raffia Fiber Fabric Reinforcing Epoxy Composites as Standalone Targets DOI Open Access
Douglas Santos Silva,

Raí Felipe Pereira Junio,

Marcelo Henrique Prado da Silva

et al.

Journal of Composites Science, Journal Year: 2024, Volume and Issue: 8(9), P. 370 - 370

Published: Sept. 20, 2024

Reliable ballistic armor systems are crucial to ensure the safety of humans and vehicles. Typically, these constructed from various materials like fiber-reinforced polymer composites, which utilized for a favorable weight protection ratio. In particular, there has been quest eco-friendly that offer both strong mechanical properties sustainable advantages. The present work conducted analysis epoxy matrix composites using raffia (Raphia vinifera) fibers Amazon region as reinforcement. experiments investigated limit residual velocities with 10, 20, 30 vol% raffia. experimental density was lower than epoxy. Fractured surfaces were examined by scanning electron microscopy (SEM) reveal failure mechanism. results showed 10 fiber fabric had highest energy absorption (168.91 J) velocity (201.43 m/s). ones displayed higher level physical integrity. SEM micrographs demonstrated mechanisms associated delamination breakage. There small variation in between reinforced raffia, 826.66, 829.75, 820.44 m/s, respectively.

Language: Английский

Citations

4

Formaldehyde-Free, High-Bonding Performance, Fully Lignin-Based Adhesive Cross-Linked by Glutaraldehyde DOI

Sai Hu,

Xiaoqian Chen, Shuzhen Ni

et al.

ACS Applied Polymer Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

The traditional phenolic resin is prepared by the reaction of petroleum-based phenol and carcinogenic formaldehyde, which causes serious harm. As a renewable compound with abundant reserves in nature, lignin as potential sustainable substitute for phenol-formaldehyde lignin-phenol-formaldehyde adhesives have attracted increasing attention production plywood. However, how to exploit environmentally friendly fully lignin-based remains challenge. Here, formaldehyde-free adhesive was synthesized using facile strategy cross-linking glutaraldehyde. structural characterization confirmed that successfully reacted aldehydes promoted nucleophilic addition during synthesis glutaraldehyde cross-linked adhesives. plywood exhibited excellent adhesion performance, dry bonding strength reached 2.66 0.93 MPa, respectively, indicating comparable competitiveness compared formaldehyde adhesive. work demonstrates synthesize enables its utilization promising alternatives

Language: Английский

Citations

0

Advancements in Biomass-Derived Adhesives: Enhancing Overall Properties for Versatile Applications DOI Creative Commons
Asmare Tezera Admase, Zenamarkos Bantie Sendekie,

Tesfa Nega Gesese

et al.

IntechOpen eBooks, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 3, 2025

The increasing demand for sustainable materials has propelled research into biomass-derived adhesives as eco-friendly alternatives to traditional synthetic options. This chapter investigates the enhancement of physicochemical and thermomechanical properties bio-based adhesives, highlighting their applications across diverse industries, including medical devices, construction, automotive, wood wood-based panels, packaging. Bio-adhesives, sourced from renewable such lignin, tannins, proteins, offer advantages like biodegradability non-toxicity. However, challenges low water resistance, bonding strength, thermal stability persist. Recent advancements, incorporation nanofillers cross-linking agents, have shown promise in overcoming these limitations, significantly improving adhesive performance. In applications, bio-adhesives must be biocompatible biodegradable facilitate wound healing without harmful effects. construction automotive sectors, they provide solutions lightweight materials, enhancing structural integrity under various environmental conditions. packaging industry is also benefiting derived proteins whey casein, which improve barrier while remaining renewable. Despite potential, commercialization faces higher production costs variable Ongoing aims address issues through modifications development standardized testing methods. underscores transformative potential emphasizing role promoting sustainability meeting rigorous demands applications. Ultimately, can contribute a more future material science.

Language: Английский

Citations

0

Simultaneously Enhanced Bonding Strength, Water Resistance and Flame Retardancy of Urea-Formaldehyde Adhesive Using Polymerized Polyborosiloxane for Plywood DOI
Jiahao Shen, Teng Huang,

Zhiqian Lin

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0

Room-Temperature Curing of Cellulose Adhesive via Freeze–Thaw-Induced In Situ Cross-Linking for Bonding Wood or Bamboo DOI

Chunyan Yin,

Hongxing Yang,

Jiajian Wang

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 24, 2025

Language: Английский

Citations

0

Developing Eco-Friendly, High-Performance Soy Protein Plywood Adhesive via Core–Shell Hybridization and Borate Chemistry DOI Open Access
Yi Zhang,

Longxiang Sun,

Xinyu Li

et al.

Materials, Journal Year: 2025, Volume and Issue: 18(5), P. 1144 - 1144

Published: March 4, 2025

Developing eco-friendly, high-performance adhesives is crucial for sustainable industrial applications but remains a significant challenge. Herein, synergistic strategy combining core-shell hybridization and borate chemistry was employed to fabricate multifunctional soy protein (SPI) adhesive with excellent adhesion. Specifically, reactive hybrid (POSS-U) synthesized via free-radical polymerization using octavinyl-POSS as the core urushiol (U) shell. Sodium (SB) then added crosslinker, along POSS-U SPI, prepare SPI/POSS-U/SB adhesive. The exhibited 100% increase in dry shear strength (2.46 MPa) wet of 0.74 MPa, meeting indoor application standards. Due thermal shielding char formation POSS SB, peak heat release rate modified reduced by 25.4%, revealing flame retardancy. Additionally, remained mold-free 144 h due antifungal properties boron. This work provides an innovative approach enhancing protein-based contributes advancement composite materials.

Language: Английский

Citations

0

Construction and performance analysis of dual-particle-sized TiO 2 /polydimethylsiloxane (PDMS) photocatalytic and superhydrophobic wood coating DOI

Zhangqian Kong,

Xingzhou Yao,

Linjun Zhong

et al.

Wood Material Science and Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 12

Published: March 6, 2025

Language: Английский

Citations

0

Self‐Bonded Wood Composites with Efficient Heat Dissipation Enabled by In‐Situ Grown Co/Zn Bimetallic MOFs DOI Open Access
Haoran Ye, Yuxuan Cao, Xin Jin

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Most electronic product packaging materials are made of plastic, a petroleum‐based material with limited heat dissipation capabilities, restricting its suitability for heat‐intensive products. Wood‐based composites have gained widespread usage due to their environmental friendliness and cost‐effectiveness. However, the low thermal conductivity restricts application in requiring efficient dissipation. Here, high‐strength wood‐based composite excellent antibacterial property (WBC/ZIF‐67/8) is constructed through self‐bonding technology. The WBC/ZIF‐67/8 demonstrates exceptional mechanical properties tensile flexural strengths 66.87 86.33 MPa, respectively. Importantly, it exhibits 1.01 W mK −1 , significantly surpassing that densified wood. This superior performance attributed core‐shell structure formed situ growth ZIF‐67/8 crystals on wood fibers. Although fibers themselves exhibit relatively conductivity, this enables effective conduction diffusion at interface between high Simultaneously, introduction enhanced anti‐mildew composite. These improvements capability pave way durable sustainable packaging.

Language: Английский

Citations

0