Cited by Boron-Promoted Co-Catalyzed N-Methylation of Secondary Aromatic Amines with CO2 and H2

Ionic liquid-based advanced porous organic hyper-crosslinked polymers (ILHCPs) for CO2 capture and conversion DOI

Ruina Zhang, Guokai Cui, Xin’gai Wang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151102 - 151102

Published: April 15, 2024

Language: Английский

Citations

A Cu-Salen-based conjugated microporous polymer catalyst for N-formylation of CO₂ under mild conditions DOI

Shuai Gu,

J.-Y. Shou,

Anqi Chen

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

CMP@Cu-salen with uniformly dispersed active sites and abundant pore structure achieves excellent catalytic performance for N -formylation of amines CO 2 under mild conditions.

Language: Английский

Citations

Copper-PMHS System-Enabled Reductive Cyclization of o-Aminobenzamides with CO₂ as a Single-Carbon Synthon DOI

Jiang Nan, Lu Zhang,

Rui Cao

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

Chemical utilization of carbon dioxide (CO2) has emerged as a sustainable access for synthesizing high-value chemicals. Continuously designing the more practical reaction systems is large importance. Herein, an unprecedented and powerful copper-PMHS reductive system o-aminobenzamides with CO2 disclosed. Synthetically, diverse range quinazolinones (>70 examples) are rapidly assembled excellent functional group tolerance in good yields. Moreover, building other types heterocycles such benzothiazoles benzimidazoles also allowable. Mechanistically, differing from reported carbonylation cases, this finding represents scarce example single-carbon atom synthon PMHS system.

Language: Английский

Citations

Three-Component Synthesis of Oxazolidinones via Phosphine-Catalyzed Fixation of Carbon Dioxide and Mechanistic Investigation in Mass Spectrometry DOI

Wangyu Li,

Shiwen Zhou,

He Tang

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 2, 2025

A phosphine-catalyzed three-component cyclization reaction between anilines, carbon dioxide, and chloroalkanes was developed for the synthesis of oxazolidinones. This strategy not only proceeds under ambient CO2 pressure metal-free condition but also shows a broad substrate scope, including aromatic amines, aliphatic chiral amino acid esters, bioactive molecules, providing an efficient environmentally benign route to synthesize pharmaceutically relevant N-aryl-oxazolidinones. Mechanistic investigations utilizing mass spectrometry (MS) indicate involvement multiple phosphine intermediates in this process, thereby elucidating underlying mechanism. Moreover, relationships these Tolman cone angles or solvent effect phosphines were examined through spectrometry.

Language: Английский

Citations

Phosphonium-Salt-Catalyzed N-Methylation and N-Formylation of Amines with CO₂ DOI

Changyue Ren,

Anke Spannenberg,

Thomas Werner

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(29), P. 10969 - 10977

Published: July 8, 2024

The use of CO2 as a C1 building block is great relevance and focus current research. Herein we report the synthesis air-stable internal phosphonium salts their application catalysts in N-methylation N-formylation amines utilizing CO2. A series were prepared tested for these valuable transformations. Under optimized reaction condition, was achieved at 23 °C, 1 bar pressure under solvent-free conditions using equimolar amounts n-hexylsilane reducing agent. modification led to selectivity switch, realized 70 °C acetonitrile same catalyst reductant. In total, 22 converted corresponding N-methylated products up 99% yield. Moreover, 25 examples conversion N-formylated 96% yield are reported. Both reactions can be performed large scale. also applied late-stage functionalization pharmaceutical sertraline. NMR studies control experiments revealed two different pathways intermediates N-formylation.

Language: Английский

Citations

Recent advances in N-formylation reaction for the chemical recycling of carbon dioxide DOI

Qiang Yuan,

Xiao Cai,

Weiping Ding

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The homogeneous and heterogeneous catalyst systems applied in N -formylation reaction of amines CO 2 from both are summarized.

Language: Английский

Citations

Boron-Promoted Co-Catalyzed N-Methylation of Secondary Aromatic Amines with CO2 and H2 DOI

Qin Shi, Zhen Li, Lin He

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(10), P. 3233 - 3233

Published: Jan. 1, 2024

Language: Английский

Citations