A General Pd-Catalyzed C2–H Arylation of Benzoxazoles with Highly Sterically Congested Aryl Chlorides Enabled by a Fittingly Tuned Ligand
Wei-Zhi Song,
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Man Ho Tse,
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Yiu-Kee Lau
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et al.
Organic Letters,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 6, 2024
The
benzoxazole
core,
featuring
a
sterically
congested
2,6-disubstituted
aryl
fragment
at
the
C2
position,
exhibits
exclusive
three-dimensional
structures
that
are
essential
for
particular
applications
in
material
science
and
pharmaceutical
development.
Despite
their
importance,
synthesis
of
these
compounds
has
posed
challenges
with
an
efficient
preparation
strategy
still
lacking.
In
this
study,
we
introduced
new
indolylphosphine
ligand,
Language: Английский
Crystal structure of a phenoxyl radical complex relevant to the metal site of the galactose oxidase enzyme: A facile one-pot synthesis, evidence for hydrogen atom transfer and DNA cleavage via self-activation
Dalton Transactions,
Journal Year:
2023,
Volume and Issue:
53(3), P. 986 - 995
Published: Nov. 28, 2023
Copper
complexes
[Cu(L
Language: Английский