Hypercoordination in triorganoantimony(III) compounds. Case study of heteroleptic [2,6-(Me2NCH2)2C6H3]2(Ph)Sb DOI

Răzvan Şuteu,

Cristian Silvestru, Anca Silvestru

et al.

Revue Roumaine de Chimie, Journal Year: 2024, Volume and Issue: 69(5-6), P. 241 - 245

Published: May 12, 2024

The triorganoantimony(III) compound [2,6-(Me2NCH2)2C6H3]2(Ph)Sb (1), containing three aryl groups, two of them with pendant arms capable for N→Sb intramolecular interactions, was prepared and structurally investigated, both in solution solid state. 1H the 13C NMR spectra suggested no interaction. molecular structure determined by single-crystal X-ray diffraction revealed a N,C,N-tridentate coordination one 2,6-(Me2NCH2)2C6H3 group, while other displayed only C,N-bidentate behaviour towards antimony. environment about antimony is highly distorted octahedron, can be described as 14Sb6 hypercoordinate species.

Language: Английский

Molecular Bismuth Compounds: Ligand Design and Reactivity DOI
Shigeru Shimada

Structure and bonding, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

0
C–H bond activation at antimony(iii): synthesis and reactivity of Sb(iii)–oxyaryl species DOI Creative Commons

Gabriel Duneş,

Marie Cordier≈, Samia Kahlal

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

We report on the synthesis, structure and reactivity of [{NCN

Language: Английский

Citations

0
Hypercoordination in triorganoantimony(III) compounds. Case study of heteroleptic [2,6-(Me2NCH2)2C6H3]2(Ph)Sb DOI

Răzvan Şuteu,

Cristian Silvestru, Anca Silvestru

et al.

Revue Roumaine de Chimie, Journal Year: 2024, Volume and Issue: 69(5-6), P. 241 - 245

Published: May 12, 2024

The triorganoantimony(III) compound [2,6-(Me2NCH2)2C6H3]2(Ph)Sb (1), containing three aryl groups, two of them with pendant arms capable for N→Sb intramolecular interactions, was prepared and structurally investigated, both in solution solid state. 1H the 13C NMR spectra suggested no interaction. molecular structure determined by single-crystal X-ray diffraction revealed a N,C,N-tridentate coordination one 2,6-(Me2NCH2)2C6H3 group, while other displayed only C,N-bidentate behaviour towards antimony. environment about antimony is highly distorted octahedron, can be described as 14Sb6 hypercoordinate species.

Language: Английский

Citations

0