1-Aryl-3-nitro- and 3-Bromo-3-nitroprop-2-en-1-ones: Synthesis and Structural Features DOI Creative Commons
I. S. Adyukov, Василий В. Пелипко, Р. И. Байчурин

et al.

Russian Journal of General Chemistry, Journal Year: 2024, Volume and Issue: 94(3), P. 497 - 507

Published: March 1, 2024

Abstract A method for producing a number of ( E )-1-aryl-3-nitroprop-2-en-1-ones based on synthetic condensation–dehydration strategy has been optimized. New Z )-1-aryl-3-bromo-3-nitroprop-2-en-1-ones have synthesised from using halogenation-dehydrohalogenation to )-1-aryl-3-nitroprop-2-en-1-ones. The fine structure nitro- and bromonitroenketones it’s features were determined by 1 H– H NOESY NMR X-ray diffraction analysis.

Language: Английский

Diastereoselective Synthesis of 2-(Pyrrolidin-2-ylidene)-1H-indene-1,3-diones via 1,3-Dipolar Cycloaddition of H-Bond-Assisted Azomethine Ylides with Chalcones DOI
Issa Yavari,

Seyed Alireza Hadian

Synthesis, Journal Year: 2025, Volume and Issue: unknown

Published: April 22, 2025

Abstract The diastereoselective synthesis of NH-unprotected pyrrolidin-2-ylidene derivatives was accomplished via 1,3-dipolar cycloaddition H-bond-assisted azomethine ylides with chalcones. This process resulted in the formation three stereogenic centers, exhibiting excellent diastereoselectivity. effectiveness this approach illustrated through a gram-scale experiment, and structure final product confirmed by single-crystal X-ray analysis.

Language: Английский

Citations

0
Organocatalysis in 1,3-Dipolar Cycloaddition Reactions (A Review) DOI

Yulia A. Pronina,

L. A. Teglyai,

A. I. Ponyaev

et al.

Russian Journal of General Chemistry, Journal Year: 2024, Volume and Issue: 94(1), P. 1 - 44

Published: Jan. 1, 2024

Language: Английский

Citations

2
Bromonitroalkenes as efficient intermediates in organic synthesis DOI
Azim Ziyaei Halimehjani,

Hoonam Tahvildari

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(24), P. 4801 - 4838

Published: Jan. 1, 2024

Bromonitroalkenes are useful molecules in synthetic organic chemistry. They mainly prepared from nitroalkenes

Language: Английский

Citations

2
Diastereoselective Synthesis of NH-Unprotected Spiropyrrolidines via the Huisgen Reaction of Acenaphthoquinone-Derived Azomethine Ylides with β-Nitrostyrenes DOI
Issa Yavari,

Kiyana Ghafouri

Synthesis, Journal Year: 2024, Volume and Issue: 56(15), P. 2403 - 2409

Published: April 4, 2024

Abstract 4′-Nitro-2H-spiro[acenaphthylene-1,2′-pyrrolidine]-2-one derivatives are prepared via [3+2] cycloaddition reactions of azomethine ylides, generated in situ from acenaphthoquinone and primary amines, with β-nitrostyrenes the presence ( i Pr)2NEt methanol. Evidence for structures products was obtained single-crystal X-ray analysis. The important feature this diastereoselective synthesis NH-unprotected spiropyrrolidines is formation four contiguous stereogenic centers, one which quaternary, high selectivity.

Language: Английский

Citations

1
1-Aryl-3-nitro- and 3-Bromo-3-nitroprop-2-en-1-ones: Synthesis and Structural Features DOI Creative Commons
I. S. Adyukov, Василий В. Пелипко, Р. И. Байчурин

et al.

Russian Journal of General Chemistry, Journal Year: 2024, Volume and Issue: 94(3), P. 497 - 507

Published: March 1, 2024

Abstract A method for producing a number of ( E )-1-aryl-3-nitroprop-2-en-1-ones based on synthetic condensation–dehydration strategy has been optimized. New Z )-1-aryl-3-bromo-3-nitroprop-2-en-1-ones have synthesised from using halogenation-dehydrohalogenation to )-1-aryl-3-nitroprop-2-en-1-ones. The fine structure nitro- and bromonitroenketones it’s features were determined by 1 H– H NOESY NMR X-ray diffraction analysis.

Language: Английский

Citations

1