Bis(dialkylaminethiocarbonyl)disulfides Act as Electron Acceptors for EDA Complexes for the Synthesis of Dithiocarbamate Derivatives under Visible Light

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

This study proposes a green and efficient atom- step-economical method for converting hazardous CS2 to dithiocarbamate derivatives under visible light irradiation catalyst-free conditions. By the construction of novel C-S C-N bonds, series β-dicarbonyl compounds amines are incorporated into products. Under light, amine first form bis(dialkylaminethiocarbonyl)disulfides, which then react with K2CO3-activated electron donor-acceptor (EDA) complexes subsequently generate target confirms time that bis(dialkylaminethiocarbonyl)disulfides can act as acceptors an EDA complex compounds, coupled product light.

Language: Английский

Synthesis of 1,3-thiazolidine-2-thiones using CS2 and epoxy amines

Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 152, P. 155361 - 155361

Published: Nov. 1, 2024

Language: Английский