Photocatalytic Sulfonylation: Innovations and Applications

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: July 14, 2024

Photosynthesis, converting sustainable solar energy into chemical energy, has emerged as a promising craft to achieve diverse organic transformations due its mild reaction conditions, sustainability, and high efficiency. The synthesis of sulfonated compounds drawn significant attention in the pharmaceuticals, agrochemicals, materials industries unique structure electronic properties sulfonyl groups. Over past decades, many photocatalytic sulfonylation reactions have been developed. In this review, recent advances photocatalyzed reviewed since 2020, with primary focus on discussing design mechanism.

Language: Английский

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Visible-Light-Catalyzed Fast Synthesis of 1,4-Benzoxazepine Derivatives from 2-Alkoxyarylaldehydes and N-Arylglycines

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 3, 2025

A novel photocatalytic method for the synthesis of 1,4-benzoxazepine using 2-alkoxyarylaldehyde as an oxygen source and N-arylglycine a nitrogen has been reported. This is mild, efficient, fast, corresponding reaction can be completed within 2 h at room temperature under atmosphere light-irradiation conditions. Mechanistic studies have confirmed that this scheme involves decarboxylation cyclization provides convenient pathway preparation various 2-alkyl-N-phenyl-substituted 1,4-benzoxazepine.

Language: Английский

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Photocatalytic synthesis of carbamoylated chroman-4-ones via radical cascade cyclization of 2-(allyloxy)arylaldehydes and oxamic acids

Molecular Catalysis, Journal Year: 2025, Volume and Issue: 582, P. 115168 - 115168

Published: May 2, 2025

Language: Английский

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Homogeneous catalysis and heterogeneous separation: Ionic liquids as recyclable photocatalysts for hydroacylation of olefins

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110579 - 110579

Published: Oct. 1, 2024

Language: Английский

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Versatile Quinazolinone Synthesis: N‐Bromosaccharin‐Catalyzed Divergence in 2,3‐Dihydroquinazolin‐4(1H)‐one and Quinazolin‐4(3H)‐one Formation

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(12)

Published: March 19, 2024

Abstract In this research, we present an innovative and eco‐friendly methodology for the synthesis of a diverse array 2,3‐dihydroquinazolin‐4(1H)‐ones, featuring use catalytic N‐Bromosaccharin (NBSac). This novel approach is not limited to just one product; it extends efficient quinazolin‐4(3H)‐ones by harnessing visible light alongside stoichiometric (NBSac) as multifunctional heterogeneous oxidant. By uniting cyclocondensation oxidation into one‐pot sequential process, direct access achieved. The developed protocol characterized its user‐friendliness, metal‐free operation, wide applicability across substrates, ability recycle catalyst, making appealing sustainable method quinazolinone synthesis.

Language: Английский

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Transition-Metal- and Photocatalyst-Free Photoinduced Formation of Carbon–Pnictogen (–N, –P) Bonds

Synthesis, Journal Year: 2024, Volume and Issue: 56(17), P. 2627 - 2637

Published: April 2, 2024

Abstract Pnictogens, classified within group 15 elements, play a pivotal role in the constitution of diverse array drug molecules, natural products, and functional materials. Recent research has increasingly prioritized exploration mild conditions for synthesizing C–Pnictogen (C–N C–P) bonds, highlighting growing emphasis on efficient sustainable synthetic methodologies. This Short Review explores fundamental mechanisms, addresses constraints, assesses methodologies, underscoring potential photocatalyst- transition-metal-free photochemical reactions advancing sustainability. Divided into two segments, it encompasses recent advancements facilitating C–N C–P bond formation. 1 Introduction 2 Carbon–Nitrogen (C–N) Bond Formation 3 Carbon–Phosphorus (C–P) 4 Summary Outlook

Language: Английский

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Unveiling the Untapped Potential of Bertagnini’s Salts in Microwave-Assisted Synthesis of Quinazolinones

Molecules, Journal Year: 2024, Volume and Issue: 29(9), P. 1986 - 1986

Published: April 26, 2024

Microwave-assisted organic synthesis (MAOS) has emerged as a transformative technique in chemistry, significantly enhancing the speed, efficiency, and selectivity of chemical reactions. In our research, we have employed microwave irradiation to expedite quinazolinones, using water an eco-friendly solvent thereby adhering principles green chemistry. Notably, purification product was achieved without need for column chromatography, thus streamlining process. A key innovation approach is aldehyde bisulfite adducts (Bertagnini's salts) solid surrogates aldehydes. Bertagnini's salts offer several advantages over free aldehydes, including enhanced stability, easier purification, improved reactivity. Green metrics Eco-Scale score calculations confirmed sustainability this approach, indicating reduction waste generation outcomes. This methodology facilitates diverse array compounds, offering substantial contributions field, with potential widespread applications pharmaceutical research beyond.

Language: Английский

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Visible-Light-Induced Remote C(sp³)—H Phosphonylation of Amides

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(6), P. 2057 - 2057

Published: Jan. 1, 2024

Language: Английский

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Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF₃-Enones

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 2, 2024

Condition-controlled switchable and divergent transformations of cost-effective 2-bromo-3,3,3-trifluoropropene (BTP) aldehydes were realized using a decatungstate (TBADT)-photocatalyzed strategy. The hydroacylated products, i.e., β,β-Br,CF

Language: Английский

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