The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(21), P. 15864 - 15876
Published: Oct. 22, 2024
A practical and recyclable electro-oxidation of alcohols to aldehydes ketones by using N-hydroxyphthalimide (NHPI) as the catalyst is presented. Through an undivided pool, under constant current conditions, various can be oxidized corresponding or in a high yield. Compared with previous methods, this system has following characteristics: (1) catalyst, electrode, electrolyte, solvent (mainly water) are recyclable; (2) it many advantages such mild reaction easy operation, good tolerance functional groups; (3) smoothly scaled up kilogram-scale production.
Language: Английский