Direct C–C Bond Cleavage of CH3CN as a Single‐Carbon Synthon：Synthesis of Pyrrolo[1,2‐a]quinoxalines via Electrochemical Oxidation DOI
Fengkai Sun,

Man Miao,

Wenxue Li

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(22), P. 4649 - 4653

Published: Aug. 20, 2024

Abstract A direct electrochemical redox reaction involving radical cross‐coupling cyclization for the synthesis of pyrrolo[1,2‐ a ]quinoxaline derivatives from 1‐(2‐aminophenyl)pyrroles and CH 3 CN has been developed, which includes functionalization C( sp )−H bonds as well construction C−C C−N bonds. Notably, control deuterium‐labelling experiments suggest that in this acts both carbon source via cleavage solvent. The features metal‐ oxidant‐free conditions, various substituted were obtained.

Language: Английский

Carbon-Chain Elongation by Co-Catalyzed Selective C–C Bond Cleavage and Subsequent Silylperoxylation of Alkene Substrates DOI
Jia‐Hao Xie, Terumasa Kato, Keiji Maruoka

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 14754 - 14761

Published: Sept. 20, 2024

Language: Английский

Citations

1
Direct C–C Bond Cleavage of CH3CN as a Single‐Carbon Synthon：Synthesis of Pyrrolo[1,2‐a]quinoxalines via Electrochemical Oxidation DOI
Fengkai Sun,

Man Miao,

Wenxue Li

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(22), P. 4649 - 4653

Published: Aug. 20, 2024

Abstract A direct electrochemical redox reaction involving radical cross‐coupling cyclization for the synthesis of pyrrolo[1,2‐ a ]quinoxaline derivatives from 1‐(2‐aminophenyl)pyrroles and CH 3 CN has been developed, which includes functionalization C( sp )−H bonds as well construction C−C C−N bonds. Notably, control deuterium‐labelling experiments suggest that in this acts both carbon source via cleavage solvent. The features metal‐ oxidant‐free conditions, various substituted were obtained.

Language: Английский

Citations

0