Self-coupling of electron acceptor units in conjugated microporous polymers strengthening local donor-acceptor interaction for improving photocatalytic activity DOI

Lin-Fu Xie,

Jianping Chen, Ling Niu

et al.

Applied Catalysis A General, Journal Year: 2024, Volume and Issue: 685, P. 119888 - 119888

Published: July 17, 2024

Language: Английский

Donor–acceptor covalent organic frameworks-confined ultrafine bimetallic Pt-based nanoclusters for enhanced photocatalytic H2 generation DOI
Yu Liu, Yawen Shi, Hua Wang

et al.

Nano Research, Journal Year: 2024, Volume and Issue: 17(7), P. 5835 - 5844

Published: March 7, 2024

Language: Английский

Citations

12
Rational Design of Covalent Organic Frameworks as Photocatalysts for Water Splitting DOI
Zhen Li,

Chengcheng Liu,

Qiwen Deng

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 1, 2024

Abstract Photocatalytic water splitting for hydrogen production represents a crucial approach obtaining green energy through artificial solar utilization, offering sustainable method generation that helps mitigate shortages and protect the environment. Among numerous photocatalytic materials, covalent organic frameworks (COFs) have garnered significant attention intensive study from researchers due to their distinctive benefits, such as porosity, pre‐design capability, tunability at atomic level. Significant advancements are made in development of enhancement performance, comprehension mechanisms. In this review, recent COF‐based spotlighted, both half‐reactions overall reactions, with particular emphasis on rational design COF structures regulate materials' optical electrical properties, well fundamental processes photocatalysis. Drawing current research field, existing challenges, potential opportunities also discussed future development.

Language: Английский

Citations

11
Near-Flat D–A-Typed Triphenylamine-COF toward Efficient Charge Migration and Enhanced Oxygen Activation for Boosting Photoredox Reactions DOI

Ren Ma,

Yujing Zhang, Feiyang Yu

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 3046 - 3060

Published: Feb. 5, 2025

Language: Английский

Citations

1
Selective oxidation of β-keto ester modulated by the d-band centers in D-A conjugated microporous metallaphotoredox catalysts containing M−salen (M Zn, Cu and Co) and triazine monomers DOI

Lin-Fu Xie,

Wan-Hong Huang,

Jianping Chen

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 399 - 412

Published: March 26, 2024

Language: Английский

Citations

5
sp2 Carbon‐Conjugated Covalent Organic Frameworks (sp2c‐COFs): Synthesis and Application in Photocatalytic Water Splitting DOI Open Access

Shiqiong Peng,

Renjie Wang,

Yao Yang

et al.

Macromolecular Rapid Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 9, 2025

Abstract Preparation of irreversible sp 2 carbon‐conjugated covalent organic frameworks (sp c‐COFs) with specific porosity, easy structural functionalization, high chemical stability, and unique π‐electron conjugation structure (especially the combination π–π stacking interactions system), can remove barrier electron transfer provide a advantage for photocatalytic water splitting. Herein, based on three kinds reactions (Aldol condensation reaction, Knoevenagel Horner‐Wadsworth‐Emmons reaction) guided by precise modulation ligand topology, this review summarizes synthesis c‐COFs their applications in photoelectrocatalytic splitting (hydrogen evolution oxygen reactions). Furthermore, challenges possible research directions are also provided.

Language: Английский

Citations

0
Regulating the Built-In Electric field in Covalent Organic Frameworks for Enhanced CO2 Photoreduction: Asymmetry Linkage Structures DOI
Qian Zhang, Xiao Zhao, Shuaiqi Gao

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 6739 - 6748

Published: April 10, 2025

Language: Английский

Citations

0
Computational Modeling of Reticular Materials: The Past, the Present, and the Future DOI Creative Commons
Wim Temmerman,

Ruben Goeminne,

Kuber Singh Rawat

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

Abstract Reticular materials rely on a unique building concept where inorganic and organic units are stitched together giving access to an almost limitless number of structured ordered porous materials. Given the versatility chemical elements, underlying nets, topologies, reticular provide platform design for timely technological applications. have now found their way in important societal applications, like carbon capture address climate change, water harvesting extract atmospheric moisture arid environments, clean energy Combining predictions from computational chemistry with advanced experimental characterization synthesis procedures unlocks strategy synthesize new desired properties functions. Within this review, current status modeling is addressed supplemented topical examples highlighting necessity molecular This review as templated study starting structure realistic material towards prediction functions At end, authors perspective past, present future formulate open challenges inspire model method developments.

Language: Английский

Citations

2
Self-coupling of electron acceptor units in conjugated microporous polymers strengthening local donor-acceptor interaction for improving photocatalytic activity DOI

Lin-Fu Xie,

Jianping Chen, Ling Niu

et al.

Applied Catalysis A General, Journal Year: 2024, Volume and Issue: 685, P. 119888 - 119888

Published: July 17, 2024

Language: Английский

Citations

1