Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO₂ reduction

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(15), P. 5311 - 5335

Published: Jan. 1, 2024

The panorama of the latest developments emerging porphyrin-based MOFs for photo(electro)catalytic CO 2 reduction is shown.

Language: Английский

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Emerging metal-organic framework-based photocatalysts for solar-driven fuel production

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 524, P. 216292 - 216292

Published: Nov. 11, 2024

Language: Английский

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Metal Free Innovative Approach for the Removal of Methylene Blue from Simulated Water Sample by Novel Porphyrin Based Photocatalyst

Optical Materials, Journal Year: 2025, Volume and Issue: 160, P. 116757 - 116757

Published: Feb. 3, 2025

Language: Английский

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Manganese‐Based Metal‐Organic Frameworks and Their Derivatives for Electrochemical Water Splitting: Recent Advances and Future Outlook

Chemistry - An Asian Journal, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Metal‐organic frameworks (MOFs) and their derivatives have recently attracted significant interest as promising candidates in water splitting due to well‐defined structural electronic features, three‐dimensional architecture, high surface area, abundance of active sites, remarkable stability, improved capabilities for mass transport diffusion. Mn‐based MOFs been extensively studied demonstrated potential splitting, inspired largely by the natural photosystem‐II. Despite development numerous electrocatalysts, Mn‐MOFs stand out strong synergistic interactions, tunable properties, efficient charge transfer, straightforward synthesis. However, recent reviews on overlooked specific advancements water‐splitting applications. By providing an overview uses materials, this article seeks close that gap. It looks at porosity, structure well how they are used splitting. This study offers a deeper knowledge properties related materials drawing groundbreaking research. The link between structure, property, performance is examined, current subject discussed, difficulties faced addressed, future developments taken into account.

Language: Английский

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Reticular Materials for Photocatalysis

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 27, 2024

Abstract Photocatalysis leverages solar energy to overcome the thermodynamic barrier, enabling efficient chemical reactions under mild conditions. It can greatly reduce reliance on traditional sources and has attracted significant research interest. Reticular materials, including metal‐organic frameworks (MOFs) covalent organic (COFs), represent a class of crystalline materials constructed from molecular building blocks linked by coordination bonds, respectively. function as heterogeneous catalysts, combining well‐defined structures high tailorability akin homogeneous catalysts. In this review, regulation light absorption, charge separation, surface in photocatalytic process through precise molecular‐level design based features reticular is elaborated. Notably, for MOFsmicroenvironment modulation around catalytic sites affects performance delved, with emphasis their unique dynamic flexible microenvironments. For COFs, inherent excitonic effects due fully nature discussed highlight strategies regulate charge‐ and/or energy‐transfer‐mediated photocatalysis. Finally, current challenges future directions field, aiming provide comprehensive understanding how be optimized enhanced photocatalysis discussed.

Language: Английский

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Photocatalytic CO₂ Reduction to Solar Fuels by a Chemically Stable Bimetallic Porphyrin-Based Framework

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 12, 2024

Porphyrin-based photocatalysts have emerged as promising candidates for facilitating carbon dioxide (CO

Language: Английский

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Use of Ce doping to modulate the interfacial electric field and enhance the photocatalytic performance of BiOCl/UiO-66 heterojunctions

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: 13(2), P. 115479 - 115479

Published: Jan. 16, 2025

Language: Английский

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Functionalization of zeolite-encapsulated Cu₅ clusters as visible-light photoactive sub-nanomaterials

RSC Advances, Journal Year: 2025, Volume and Issue: 15(3), P. 2086 - 2098

Published: Jan. 1, 2025

While TiO 2 nanoparticles absorb in the UV of solar spectrum, it is shown that zeolite-encapsulated Cu 5 –TiO visible region via direct photo-induced electron transfers and formation charge-separated states.

Language: Английский

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Core-substituted meso-tetraphenylporphyrin derivatives anchored to anatase nanoparticles with carboxylic acid as new water stable non-planar porphyrin photosensitizers: Mono para-substituted porphyrin vs. the tetra-substituted counterpart

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114039 - 114039

Published: Feb. 1, 2025

Language: Английский

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Revisiting Photocatalytic CO₂ Reduction to Methanol: A Perspective Focusing on Metal‐Organic Frameworks

Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 21, 2025

Abstract Photocatalytic CO 2 reduction to CH 3 OH, particularly with metal‐organic frameworks (MOFs) as photocatalysts, has garnered significant attention due its long‐term potential harness sunlight for converting into a valuable fuel and chemical feedstock. Numerous studies in the literature report successful formation of OH from photocatalytic reduction, sometimes supplemented sacrificial agents, claims substantiated by isotopic labelling measurements. However, this Scientific Perspective, we note that much existing evidence not been obtained under sufficiently rigorous experimental conditions conclusively confirm highly reactive product like chemically stable molecule. This Perspective outlines best practices designed provide robust processes, which could be instrumental clarifying state‐of‐the‐art accelerating development technology toward practical applications.

Language: Английский

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