Chemical Communications, Journal Year: 2024, Volume and Issue: 60(54), P. 6949 - 6952
Published: Jan. 1, 2024
We prepared a C 60 encapsulated porous organic cage as an electrochemical chiral sensor to exhibit efficient recognition ability for DOPA enantiomers.
Language: Английский
International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 71, P. 433 - 464
Published: May 22, 2024
This paper provides an in-depth examination of critical and strategic raw materials (CRMs) their crucial role in the development electrolyzer fuel cell technologies within hydrogen economy. It methodically analyses a range technologies, including alkaline, proton-exchange membrane, solid-oxide, anion-exchange proton-conducting ceramic systems. Each technology is examined for its specific CRM dependencies, operational characteristics, challenges associated with availability sustainability. The study further extends to storage separation focusing on employed high-pressure cylinders, metal hydrides, processes, implications. A key aspect this exploration supply demand dynamics CRMs, offering comprehensive view that encompasses both present sttate future projections. aim uncover potential risks, understand strategies, identify bottlenecks involved addressing current needs demands as well supply. approach essential planning sustainable sector, emphasizing importance CRMs achieving expanded capacity leading up 2050.
Language: Английский
Citations
29
Talanta, Journal Year: 2025, Volume and Issue: 286, P. 127518 - 127518
Published: Jan. 2, 2025
Language: Английский
Citations
2
Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(22), P. 10403 - 10413
Published: May 18, 2024
Development of a simple, cost-efficient, and portable UO22+ sensory probe with high selectivity sensitivity is highly desirable in the context monitoring radioactive contaminants. Herein, we report luminescent Co-based metal–organic framework (MOF), {[Me2NH2]0.5[Co(DATRz)0.5(NH2BDC)]·xG}n (1), equipped abundant amino functionalities for selective detection uranyl cations. The ionic structure consists two types channels decorated plentiful Lewis basic moieties, which trigger stronger acid–base interaction diffused cationic units thus can selectively quench fluorescence intensity presence other interfering ions. Furthermore, limit sensing was achieved to be as low 0.13 μM (30.94 ppb) rapid responsiveness multiple recyclabilities, demonstrating its excellent efficacy. Density functional theory (DFT) calculations further unraveled preferred binding sites ions tubular channel MOF structure. Orbital hybridization between NH2BDC/DATRz together significantly large electron-accepting ability identified responsible luminescence quenching. More importantly, prepared 1@PVDF {poly(vinylidene difluoride)} mixed-matrix membrane (MMM) displayed good activity comparable 1, great significance their practical employment MOF-based luminosensors real-world application.
Language: Английский
Citations
9
Journal of Porous Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 9, 2025
Language: Английский
Citations
1
Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 28, 2025
Abstract Constructing highly oriented and ordered macro‐pores on metal‐organic framework (MOF) film can surpass the inherent limitations from micro‐pores, promote multiphase adsorption, expedite electrochemical reaction, but fabrication remains extremely challenging. Here, continuous macro‐micro‐porous MOF films are achieved by combining polystyrene microsphere template induction effect of ZnO nanomembrane prepared atomic layer deposition. In addition to intrinsic fabricated exhibits macro‐porous structures. Compared with particles conventional film, mass diffusion charge transportation in significantly improved, endowing excellent activity. The sensor device made ZIF‐67 toward glucose performance, e.g., high sensitivity, low limit detection, fast response, due rapid molecule enhanced exposure active sites via interconnected channels. This work paves way for application high‐performance biosensor chip therefore may have great potential post‐Moore period.
Language: Английский
Citations
1
Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown
Published: March 2, 2025
The development of new chiral building blocks for constructing complex architectures, such as macrocycles and cages, is both crucial challenging. Although concave-shaped calixarenes have been established versatile the synthesis cage compounds, there are no reports on cages constructed from calix[4]arene derivatives. Herein, we present a straightforward effective method gram-scale member macrocycle enantiomers, namely, phenol[4]arene (PC[4]A). As proof concept, functionalized these enantiomers into tetraformylphenol[4]arene (PC[4]ACHO) derivatives via Duff reaction to construct porous organic (CPOCs) using polyamine synthons. Specifically, employ two fluorescent amine synthons, bis(4-aminophenyl)phenylamine tris(4-aminophenyl)amine, assemble with PC[4]ACHO resulting in [2 + 4] lantern-shaped [6 8] truncated octahedral CPOCs, respectively. These structures unambiguously characterized by single-crystal X-ray diffraction circular dichroism (CD) spectroscopy. Notably, CPOCs exhibit internal diameters approximately 3.1 nm, cavity volume around 5300 Å3, high specific surface areas up 1300 m2 g-1 after desolvation, making them among largest reported. Additionally, investigations their sensing performance demonstrate that PC[4]A-based enable enantioselective recognition amino acids This work strongly suggests PC[4]A can serve an excellent block rational design materials practical applications.
Language: Английский
Citations
1
Chemical Communications, Journal Year: 2023, Volume and Issue: 60(7), P. 779 - 792
Published: Dec. 13, 2023
Advances of macrocycle and cage-based materials for iodine capture, with an emphasis on the structure hosts, complexation mechanism adsorption efficiency, have been summarized.
Language: Английский
Citations
18
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(33)
Published: May 7, 2024
Supramolecular assembly frameworks (SAFs) represent a new category of porous materials, utilizing non-covalent interactions, setting them apart from metal-organic (MOFs) and covalent organic (COFs). This includes but is not restricted to hydrogen-bonded supramolecular frameworks. SAFs stand out for their outstanding porosity, crystallinity, stability, alongside unique dissolution-recrystallization dynamics that enable significant structural functional modifications. Crucially, strategies allow balanced manipulation symmetry, dimensions, facilitating the creation advanced crystalline materials unattainable through conventional or coordination bond synthesis. Despite considerable promise in overcoming several limitations inherent MOFs COFs, particularly terms solution-processability, have received relatively little attention recent literature. Minireview aims shed light on standout SAFs, exploring design principles, synthesis strategies, characterization methods. It emphasizes distinctive features broad spectrum potential applications across various domains, aiming catalyze further development practical application within scientific community.
Language: Английский
Citations
8
Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(21), P. 10380 - 10408
Published: Jan. 1, 2024
Stemming from early seminal notions of molecular recognition and encapsulation, three-dimensional, cavity-containing capsular compounds assemblies have attracted intense interest due to the ability modulate chemical physical properties species encapsulated within these confined spaces compared bulk environments. With such a diverse range covalent motifs non-covalent (supramolecular) interactions available assemble building blocks, an incredibly wide-range capsular-type architectures been developed. Furthermore, synthetic tunability internal environments gives chemists opportunity engineer systems for uses in sensing, sequestration, catalysis transport molecules, just name few. In this tutorial review, overview is provided into design principles, synthesis, characterisation, structural facets coordination cages, porous organic supramolecular capsules, foldamers mechanically interlocked molecules. Using recent examples, advantages limitations each system are explored, highlighting their application various tasks functions.
Language: Английский
Citations
7
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 515, P. 215958 - 215958
Published: May 23, 2024
Language: Английский
Citations
6