Synthesis of B-Substituted Anthracenyl and Pyrenyl Derivatives of ortho-Carborane

Inorganics, Journal Year: 2025, Volume and Issue: 13(5), P. 138 - 138

Published: April 27, 2025

Isomeric B-substituted anthracenyl and pyrenyl derivatives of ortho-carborane containing polycyclic aromatic substituents both in the position carborane cage most distant from carbon atoms (position 9) neighboring 3) were synthesized by Pd-catalyzed cross-coupling corresponding iodo with aryl zinc bromides. The derivative two at positions cage, 9,12-di(pyren-1′-yl)-ortho-carborane, was obtained a similar way starting 9,12-diiodo-ortho-carborane. solid-state structures pyrene-containing 3-pyren-1′-yl-ortho-carborane, 9-pyren-1′-yl-ortho-carborane, 9,12-di(pyren-1′-yl)-ortho-carborane determined single-crystal X-ray diffraction.

Language: Английский

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Luminescent o-Carboranyl-Containing Molecules: A Promising Platform for Stimuli-Responsive Smart Materials

Dyes and Pigments, Journal Year: 2024, Volume and Issue: 232, P. 112484 - 112484

Published: Oct. 11, 2024

Language: Английский

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Synthesis and properties of tetraphenylethene cationic cyclophanes based on o-carborane skeleton

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: 35(12), P. 110074 - 110074

Published: June 1, 2024

Language: Английский

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Heteroatom-contained carbon-rich macrocycles and carbon nanobelts: Synthesis, molecular architectures, characteristics and applications

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 518, P. 216063 - 216063

Published: July 17, 2024

Language: Английский

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The synthesis and application of o-carborane-based macrocyclic arenes

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(36), P. 15316 - 15323

Published: Jan. 1, 2024

Two

Language: Английский

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