Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 6, 2024
Abstract
A
visible‐light‐induced
radical
tandem
difluoroalkylation/cyclization
to
construct
CF
2
‐containing
isoquinolinonedione
skeletons
with
methacryloyl
benzamides
is
developed.
Broad
substrate
scopes
are
compatible
metal‐,
oxidant‐
and
photocatalyst‐free
conditions
under
room
temperature
in
good‐to‐excellent
yields.
Mechanistic
analysis
revealed
that
the
transformation
initiated
by
photoinduced
electron
donor‐acceptor
(EDA)
complexes
formation.
Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 6, 2024
Abstract
A
visible‐light‐induced
radical
tandem
difluoroalkylation/cyclization
to
construct
CF
2
‐containing
isoquinolinonedione
skeletons
with
methacryloyl
benzamides
is
developed.
Broad
substrate
scopes
are
compatible
metal‐,
oxidant‐
and
photocatalyst‐free
conditions
under
room
temperature
in
good‐to‐excellent
yields.
Mechanistic
analysis
revealed
that
the
transformation
initiated
by
photoinduced
electron
donor‐acceptor
(EDA)
complexes
formation.