Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 353, P. 128310 - 128310
Published: June 6, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 353, P. 128310 - 128310
Published: June 6, 2024
Language: Английский
Processes, Journal Year: 2024, Volume and Issue: 12(1), P. 148 - 148
Published: Jan. 8, 2024
Batch experiments were conducted to test orange waste (OW), an agricultural solid byproduct from the juice manufacturing industry, as adsorbent for binary solutions of Cd2+-Cr3+ and Zn2+-Cr3+. Fourier transform infrared spectroscopy (FTIR) point zero charge (pHpzc) used identify functional groups on OW surface involved in biosorption. The biosorption equilibrium data both binary-metal obtained fitted various isotherm models. extended Sips non-modified Redlich-Peterson models gave best fit experimental data. According model, maximum capacity was 0.573 mmol·g−1 Cd2+, 0.453 Zn2+, 1.96 Cr3+. sorption dropped 0.061 Cd2+ 0.101 mmol·g1 Zn2+ their systems with Cr3+ higher initial metal concentrations solution. However, chromium only slightly affected by presence or Zn2+. For systems, a second ion solution always conduces reduction other decreased more than vice versa. Conclusively, effective removal ions aqueous can still be achieved
Language: Английский
Citations
5Groundwater for Sustainable Development, Journal Year: 2024, Volume and Issue: 25, P. 101139 - 101139
Published: March 3, 2024
Language: Английский
Citations
5Results in Chemistry, Journal Year: 2024, Volume and Issue: 8, P. 101582 - 101582
Published: June 1, 2024
Water treatment has emerged as a global priority in recent years due to its direct impact on human health. To address this concern, the utilization of cost-effective, readily available, and efficient materials is imperative overcoming associated challenges. In study, cellulose derived from Luffa cylindrica (LC) underwent oxidation using (2,2,6,6-tetramethylpiperidine-1-yl)oxyl (TEMPO) subsequently functionalized with amine groups poly(ethylenimine) (PEI). The resulting material was then composited polyvinyl alcohol (PVA) nanofiber. modified membrane employed for adsorption hexavalent chromium wastewater various pH, contact time, temperature, concentration, composite dose. findings revealed that process pH-dependent high optimal removal (93 %) observed at pH 2, (94 dose, (90.3 time. Kinetics were studied by applying pseudo-first-order, pseudo-second-order, Elovich, Intraparticle diffusion models. And data suggested adheres pseudo-second-order model (R2 = 0.9948). Moreover, isotherm examined Langmuir, Freundlich, Tempkin, D-P equation results exhibited satisfactory fit Langmuir 0.99193) maximum removable capacity (52.91).
Language: Английский
Citations
5Next Materials, Journal Year: 2023, Volume and Issue: 3, P. 100046 - 100046
Published: Dec. 19, 2023
In the present study, graphene oxide decorated with silver nanoparticles (GO@AgNPs) was synthesized for effective removal of metformin from water. The prepared GO@AgNPs characterized by using Fourier transform Infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric-differential thermal analyses (TGA-DTA), scanning electron microscopy (SEM) coupled dispersive (EDX) and transmission (TEM). Response surface methodology via Box-Behnken design adopted optimizing variables adsorption on GO@AgNPs. Under optimized conditions (contact time = 50 min; pH 6.5; adsorbent dose 0.015 g; initial concentration mg/L) capacity efficiency were 131.7 ±.0.30 mg/g 99.34% ±.0.33, respectively. data obtained at 305, 310, 315 320 K assessed non-linear isotherm kinetic models. Freundlich model fits best to measured data. pseudo second order equation well study impact temperature demonstrated that sorption process endothermic (∆H° 31.335 kJ/mol; Ea 32.009 kJ/mol) spontaneous in nature (∆G° −11.162, −11.876, −12.537 −13.268 kJ/mol K, respectively). Moreover, value sticking probability (S* 0.00082) illustrated high adsorption/desorption shows there no loss capacities upto 6 cycles which effectiveness as a potential remediation aqueous system.
Language: Английский
Citations
11Gels, Journal Year: 2024, Volume and Issue: 10(4), P. 259 - 259
Published: April 11, 2024
The removal of toxic heavy metal ions from wastewater is great significance in the protection environment and human health. Poly(gamma-glutamic acid) (PGA) a non-toxic, biodegradable, highly water-soluble polymer possessing carboxyl imino functional groups. Herein, water-insoluble PGA-based hydrogels were prepared, characterized, investigated as adsorbents. prepared recyclable exhibited good adsorption effects on including Cu2+, Cr6+, Zn2+. parameters temperature, solution pH, initial concentration ions, contact time capacity hydrogel for Cu2+ investigated. was spontaneous exothermic process. process followed pseudo-first-order kinetic model Langmuir isotherm model, implying physical monolayer adsorption. mechanisms investigation that adsorbed via electrostatic interactions with anionic carboxylate groups PGA addition to coordination –NH Importantly, reusability capability remained high after five consecutive cycles. properties make it potential candidate material ion treatment.
Language: Английский
Citations
4Elsevier eBooks, Journal Year: 2025, Volume and Issue: unknown, P. 153 - 194
Published: Jan. 1, 2025
Language: Английский
Citations
0Desalination and Water Treatment, Journal Year: 2025, Volume and Issue: unknown, P. 101021 - 101021
Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Radioanalytical and Nuclear Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 5, 2025
Language: Английский
Citations
0Clean Technologies and Environmental Policy, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 13, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132202 - 132202
Published: Feb. 1, 2025
Language: Английский
Citations
0