Sustainable cost-effective chemically modified banana leaf powder for methyl blue dye removal: kinetics, isotherm, thermodynamics and artificial intelligence-based analysis DOI Creative Commons

Simona Barna,

Mst. Nusrat Jahan,

Sasbir Rahman Sium

et al.

Discover Chemistry., Journal Year: 2024, Volume and Issue: 1(1)

Published: Nov. 4, 2024

This study investigates cellulose-based adsorbents that are naturally occurring and have a unique, abundant supply for adsorbing organic dye. The effectiveness of chemically modified banana leaf powder (CMBLP) as biodegradable environmentally friendly adsorbent extracting methyl blue (MB) dye from aqueous solutions was studied. Point-zero charge (pHpzc) analysis, scanning electron microscopy (SEM), X-ray energy dispersion (EDS), Fourier transform infrared spectroscopy (FTIR) were used to characterize the CMBLP. At pH 6.0, 100 mg/L dye, 50 min contact time, 300 K temperature, maximum removal values obtained. Under ideal circumstances, CMBLP displays 77.13215% rate. Langmuir Freundlich models, along with pseudo-first- pseudo-second-order kinetics equations, investigate equilibrium isotherm acquired experimental data fit (R2 = 0.9986 0.9984) 0.9996) better. Utilizing model, adsorption capacity (qmax) has been identified be 118.24 mg/g. temperature K, also able adsorb amount (MB). thermal properties validate spontaneous exothermic nature process. majority statistical artificial intelligence-based model (like KNN, SVM, ANN LSTM) superiority MB onto support our findings.

Language: Английский

Remarkable photodegradation breakdown cost, antimicrobial activity, photocatalytic efficiency, and recycling of SnO2 quantum dots throughout industrial hazardous pollutants treatment DOI
Roba M.S. Attar, Kholood Alkhamis,

Hatun H. Alsharief

et al.

Ceramics International, Journal Year: 2024, Volume and Issue: 50(19), P. 36194 - 36209

Published: July 4, 2024

Language: Английский

Citations

9
Synergistic enhancement of photocatalytic activity in ZnS/P-doped-MoS2 composite for hydrogen generation simultaneously oxidation of benzyl alcohol through water splitting and dye degradation DOI

Pinki Sehrawat,

S.K. Mehta, Sushil Kumar Kansal

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 80, P. 573 - 585

Published: July 17, 2024

Language: Английский

Citations

6
Optimization of trypan blue and brilliant green dyes photocatalytic degradation and adsorption of lead(II) and chromium (VI) heavy metal ions by copper sulfide nanoparticles DOI Creative Commons
Fartisincha P. Andrew, Tshephiso R. Papo, Peter A. Ajibade

et al.

Environmental Advances, Journal Year: 2024, Volume and Issue: 17, P. 100575 - 100575

Published: Aug. 9, 2024

The use of nanoparticles for to remove organic pollutants and heavy metals is a rapidly expanding field in environmental sciences. However, process optimization practical, real-world applications still underexplored. In this work, copper sulfide prepared from single-source precursor were characterized using SEM, TEM, EDX, FTIR, UV-visible spectroscopy. demonstrated high photocatalytic degradation efficiency trypan blue (TB) brilliant green (BG) dyes. as-prepared efficiently removed lead(II) (Pb2+) chromium(VI) (Cr6+) ions. Response surface methodology (RSM) with Box-Behnken design (BBD) was employed optimize reaction time, pH, nanoparticle dosage. optimal conditions TB pH 10.91, 77.46 minutes, 4.999 g/L, while BG, they 3, 70 5 g/L. For Pb2+ removal, 7.06, 100.38 0.94 Cr6+ 3.03, 168.20 0.98 Under these conditions, CuS achieved up 99.35% TB, 100% removal Pb2+, 98.54% Cr6+. ANOVA confirmed the models' significance, regression coefficients (R²: 0.9852 0.9846 0.9980 0.9901 Cr6+). photocatalyst remained stable over three reuse cycles, minimal reduction (8.88% 19.01% BG). This study demonstrates effectiveness remediation highlights practicality RSM as efficient materials dyes metal-laden wastewater.

Language: Английский

Citations

6
Spectrophotometric determination for green hydrophobic deep eutectic solvent-based microextraction of brilliant blue FCF (E133) from beverages DOI

Mahmut Olgun,

Sezen Sivrikaya Özak, Aslıhan Dalmaz

et al.

Journal of Chromatography A, Journal Year: 2024, Volume and Issue: unknown, P. 465374 - 465374

Published: Sept. 1, 2024

Language: Английский

Citations

6
Green-Activated Charcoal-Anchored Iron Oxide-Driven Microbial Electro-Fenton System for Sustainable Mitigation of Refractory Contaminants DOI
Rishabh Raj, Anil Dhanda, Sovik Das

et al.

ACS ES&T Water, Journal Year: 2024, Volume and Issue: 4(9), P. 4129 - 4139

Published: Aug. 1, 2024

The contamination of natural water bodies with dyes and other refractory compounds is a menacing issue in developing nations. Despite stringent laws, industrial effluent not managed efficiently, as it incurs additional cost. Hence, the present research focuses on sustainable mitigation contaminants using self-driven bioelectro-Fenton (BEF) system. iron-activated charcoal (Gt-Fe/AC) cathode-cum-Fenton catalyst used this investigation was synthesized waste green tea extract biogenic agent. catalyst-driven BEF system (Gt-Fe/AC-MFC) achieved maximum power density 111.7 ± 3.1 mW/m2 operating voltage 108 3 mV, while parallelly degrading 20 mg/L Coomassie Brilliant Blue (CBB) dye almost entirely 300 min at neutral pH. Additionally, high removal Congo red (96.8 1.2%) methylparaben (90.9 0.6%) attained under similar conditions. Moreover, Fe-AC-catalyzed performed fairly well treating spiked real wastewater exhibited remarkable stability, only 3% decrease CBB efficiency after 10 continuous cycles 0.11% drop cathodic current per cycle. can be oxidative technology to tackle resource-constricted regions.

Language: Английский

Citations

5
Zn0.96Bi0.02M0.02O (M = V or Cu) semiconductor: high-spin ferromagnetic order and fast removal of toxic organic chemicals under solar lighting DOI
Sahr A. Alsherari

Journal of Materials Science Materials in Electronics, Journal Year: 2025, Volume and Issue: 36(4)

Published: Feb. 1, 2025

Language: Английский

Citations

0
Nanosensor for the detection of bromothymol blue dye and its removal from wastewater by sustainable methods DOI Creative Commons

Nashra Sheraz,

Afzal Shah, Syed Sakhawat Shah

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(6), P. 4203 - 4219

Published: Jan. 1, 2025

This study introduces the environmentally friendly synthesis of Ag 2 O, TiO , and Ni-doped SnO nanoparticles their application in detecting removing bromothymol blue dye from wastewater.

Language: Английский

Citations

0
Green Synthesis of Copper Oxide Nanoparticles using Euphorbia heterophylla Leaf Extract for Deactivation of Pathogenic Bacteria and Photocatalytic Degradation of Industrial Dyes DOI Creative Commons

G. Kalaiyan,

Niraj S. Topare, Surajudeen Sikiru

et al.

Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 104797 - 104797

Published: April 1, 2025

Language: Английский

Citations

0
Preparation and Application of Sodium–Lanthanum Molybdate for the Photocatalytic Degradation of Coomassie Brilliant Blue G-250 Dye DOI Creative Commons

C. Lima,

Joyce Araújo Borges, Italo A. L. Santos

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: 10(16), P. 16006 - 16014

Published: April 17, 2025

This study reports on the synthesis, characterization, and application of sodium-lanthanum molybdate [NaLa(MoO4)2] as a photocatalyst in degradation process Coomassie Brilliant Blue G-250 (CBB-250), an environmentally toxic recalcitrant dye derived from triphenylmethane. The highlighted ceramic material was produced by coprecipitation, its properties were studied using range physicochemical techniques including compositional, crystallographic, morphological analyses. Among most relevant information, X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy confirmed formation NaLa (MoO4)2 crystals with tetragonal arrangement. Additionally, scanning electron microscope (SEM) images provide evidence production overlapping plate-like microstructures. nitrogen adsorption isotherms demonstrated that obtained exhibits mesoporous organization, surface area pore diameter equivalent to 45.7 m2 g-1 6.54 nm, respectively. Photocatalytic tests, performed under ultraviolet light irradiation for 120 min, indicated NaLa(MoO4)2 has high oxidative reactivity, achieving >95% CBB-250 present system. reaction velocity constants, estimated accordance Langmuir-Hinshelwood equation, substantiate enhances kinetics (13.7 × 10-3 min-1) throughout photochemical treatment. In growing scientific interest effective strategies removal emerging pollutants contamination matrices, represents promising avenue development innovative technologies this field.

Language: Английский

Citations

0
Electrochemical Sensor for Levosulpiride Detection and Its Adsorptive Removal from Wastewater DOI Creative Commons
Mohsin Javed, Afzal Shah, Iltaf Shah

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: April 23, 2025

There is increasing apprehension regarding the harmful impacts of synthetic drugs, particularly antipsychotic levosulpiride. Consequently, it both an environmental and a social responsibility to create effective sensors materials for early detection removal this drug before consumption contaminated water. The goal achieved by development highly sensitive selective sensing platform, while objective polyacrylamide hydrogel. present study introduces novel combination advanced green chemistry concepts electrode modifier (functionalized MWCNTs) adsorbent (polyacrylamide hydrogel). Unlike conventional methods, where molecules slowly diffuse surface, our technique sensor preparation directly immobilizes these on electrode, leading robust electrochemical signals establishing platform with significantly reduced limit (0.7 nM). Furthermore, traditional adsorption processes may take hours or even days, unique levosulpiride demonstrates in just 45 min, as confirmed experimental findings. Results revealed that occurred accordance Langmuir model, kinetics adhered pseudo-second order kinetics. Thermodynamic parameters such negative ΔG positive ΔS spontaneous nature entropy-driven process adsorption.

Language: Английский

Citations

0