Straightforward α-allylation of carbonyl compounds with alkenes via α-carbonyl radical intermediates DOI
Sien Liu,

Yanjing Liao,

Hongyi Li

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(9), P. 2502 - 2511

Published: Jan. 1, 2024

We report that the direct oxidative cross-coupling of carbonyl compounds with simple alkenes is realized to synthesize α-allylated by identifying bisphosphine ligand BINAP enables copper catalyst integrate two different catalytic cycles in a one-pot system.

Language: Английский

Transition metals-catalyzed amination of biomass feedstocks for sustainable construction of N-heterocycles DOI
Qiong Yan, Xu Wu, Hao Jiang

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 502, P. 215622 - 215622

Published: Dec. 26, 2023

Language: Английский

Citations

77
A new era of LMCT: leveraging ligand-to-metal charge transfer excited states for photochemical reactions DOI Creative Commons
Ann M. May, Jillian L. Dempsey

Chemical Science, Journal Year: 2024, Volume and Issue: 15(18), P. 6661 - 6678

Published: Jan. 1, 2024

Ligand-to-metal charge transfer (LMCT) excited states showcase promise in enabling photochemical reactions. This article details design principles to enable low energy LMCT and notable examples that drive reactions from these states.

Language: Английский

Citations

48
Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop DOI Creative Commons
Sebastian B. Beil, Sylvestre Bonnet, Carla Casadevall

et al.

JACS Au, Journal Year: 2024, Volume and Issue: 4(8), P. 2746 - 2766

Published: Aug. 8, 2024

Photocatalysis is a versatile and rapidly developing field with applications spanning artificial photosynthesis, photo-biocatalysis, photoredox catalysis in solution or supramolecular structures, utilization of abundant metals organocatalysts, sustainable synthesis, plastic degradation. In this Perspective, we summarize conclusions from an interdisciplinary workshop young principal investigators held at the Lorentz Center Leiden March 2023. We explore how diverse fields within photocatalysis can benefit one another. delve into intricate interplay between these subdisciplines, by highlighting unique challenges opportunities presented each multidisciplinary approach drive innovation lead to solutions for future. Advanced collaboration knowledge exchange across domains further enhance potential photocatalysis. Artificial photosynthesis has become promising technology solar fuel generation, instance, via water splitting CO

Language: Английский

Citations

19
Emerging Trends in Copper-Promoted Radical-Involved C–O Bond Formations DOI

Peng‐Zi Wang,

Jia‐Rong Chen, Wen‐Jing Xiao

et al.

Journal of the American Chemical Society, Journal Year: 2023, Volume and Issue: 145(32), P. 17527 - 17550

Published: Aug. 2, 2023

The C–O bond is ubiquitous in biologically active molecules, pharmaceutical agents, and functional materials, thereby making it an important group. Consequently, the development of bond-forming reactions using catalytic strategies has become increasingly research topic organic synthesis because more conventional methods involving strong base acid have many limitations. In contrast to ionic-pathway-based methods, copper-promoted radical-mediated formation experiencing a surge interest owing renaissance free-radical chemistry photoredox catalysis. This Perspective highlights appraises state-of-the-art techniques this burgeoning field. contents are organized according different reaction types working models.

Language: Английский

Citations

40
A review on WO3-based composite photocatalysts: synthesis, catalytic mechanism and diversified applications DOI
Xue Zhang, Ziqi Zhang, Yandong Sun

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: 43(8), P. 3441 - 3459

Published: May 18, 2024

Language: Английский

Citations

16
Decarboxylative halogenation of aliphatic carboxylic acids catalyzed by iron salts under visible light DOI
Jiahui Qian, Yu Zhang, Weining Zhao

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(20), P. 2764 - 2767

Published: Jan. 1, 2024

A general method of visible light-induced decarboxylative halogenation aliphatic carboxylic acids catalyzed by iron is developed.

Language: Английский

Citations

14
Visible-Light-Induced Excited-State Copper Catalysis: Recent Advances and Perspectives DOI
Nian Li, Bo Li, Kathiravan Murugesan

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(16), P. 11974 - 11989

Published: July 26, 2024

Photoactive copper complexes have gained significant attention due to their photocatalytic activities. Different homogeneous Cu(I) complexes, Cu(II) and heterogeneous copper-based photocatalysts been investigated utilized in a broad spectrum of organic transformations. These applications span radical additions, C–C bond C–heteroatom cross-couplings, aerobic oxidative reactions, kinetic resolutions. This review summarizes the advancements this dynamic field visible-light-induced, excited-state copper-catalyzed reactions over recent years. It is organized according type excited species involved provides perspective on current future developments.

Language: Английский

Citations

9
Oxidative Substitution of Organocopper(II) by a Carbon-Centered Radical DOI

Yuecheng Weng,

Yuxuan Jin,

Jian Wu

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(33), P. 23555 - 23565

Published: Aug. 8, 2024

Copper-catalyzed coupling reactions of alkyl halides are believed to prominently involve copper(II) species and radicals as pivotal intermediates, with their exact interaction mechanism being the subject considerable debate. In this study, a visible light-responsive fluoroalkylcopper(III) complex, [(terpy)Cu(CF3)2(CH2CO2tBu)] Trans-1, was designed explore mechanism. Upon exposure blue LED irradiation, Trans-1 undergoes copper–carbon bond homolysis, generating Cu(II) carbon-centered radicals, where radical then recombines intermediate, resulting in formation Cis-1, Cis isomer Trans-1. Beyond this, well-defined fluoroalkylcopper(II) intermediate ligated sterically hindered ligand isolated underwent full characterization electronic structure studies. The collective experimental, computational, spectroscopic findings work strongly suggest that organocopper(II) engages via an "oxidative substitution" mechanism, which is likely operational pathway for copper-catalyzed C–H trifluoromethylation reactions.

Language: Английский

Citations

9
Towards a more Sustainable Photocatalysis using Copper and Iron DOI Creative Commons
Youssef Abderrazak, Oliver Reiser

Current Opinion in Green and Sustainable Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 100998 - 100998

Published: Jan. 1, 2025

Language: Английский

Citations

1
Selective Arene Photonitration via Iron-Complex β-Homolysis DOI Creative Commons
Shuyang Liu, Ziyu Gan, Min Jiang

et al.

JACS Au, Journal Year: 2024, Volume and Issue: 4(12), P. 4899 - 4909

Published: Nov. 21, 2024

Nitroaromatics, as an important member and source of nitrogen-containing aromatics, is bringing enormous economic benefits in fields pharmaceuticals, dyes, pesticides, functional materials, fertilizers, explosives. Nonetheless, the notoriously polluting nitration industry, which suffers from excessive discharge fumes waste acids, poor group tolerance, tremendous purification difficulty, renders mild, efficient, environmentally friendly a formidable challenge. Herein, we develop visible-light-driven biocompatible arene C–H strategy with good efficiency regioselectivity, marvelous substrate applicability wide application scale-up synthesis, total late-stage functionalization. A nitryl radical delivered through unusual β-homolysis photoexcited ferric-nitrate complex proposed to be key nitrification reagent this system.

Language: Английский

Citations

7