An unprecedented {Y2⊂Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device DOI

Linping Shi,

Wenliang Li,

Pu-Yue Wang

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(11), P. 3309 - 3315

Published: Jan. 1, 2024

An unprecedented disk-like Y 12 cluster with unique 2 ⊂Y 10 type structure was achieved successfully, which is the largest non-brucite RE and exhibits obvious electroluminescence performance in OLED device.

Language: Английский

Metal Cluster Catalysts for Electrochemical CO2 Reduction DOI
Khac Huy Dinh, Leta Takele Menisa, Hugh Warkentin

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 5731 - 5759

Published: March 24, 2025

Language: Английский

Citations

0
Cost-efficient phosphor materials with defect-induced luminescence based on sodium chloride and potassium chloride DOI
Xue Yang,

Tao Xiong,

Yida Zhou

et al.

Applied Materials Today, Journal Year: 2025, Volume and Issue: 44, P. 102736 - 102736

Published: April 25, 2025

Language: Английский

Citations

0
Programming heterometallic 4f–4f′ helicates under thermodynamic control: the circle is complete DOI Creative Commons
Lotti Egger, Laure Guénée,

Neel Deorukhkar

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(13), P. 6050 - 6062

Published: Jan. 1, 2024

The use of pair interactions and specific site affinities provides 63% the heterotrimetallic HHH -[(L4 3 Zn)LaEu] 8+ helicate in solution where statistics predicts only 25% this isomer under thermodynamic control for a stoichiometric ratio 1 : 1.

Language: Английский

Citations

3
Magnetic Circularly Polarized Luminescence with Heterometallic Molecular Cluster‐Aggregates DOI Creative Commons
Diogo A. Gálico, Muralee Murugesu

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: 12(27)

Published: Aug. 5, 2024

Abstract Magnetic circularly polarized luminescence (MCPL) is a technique based on the differential emission of left and right light induced by magnetic field. This counterpart to widely explored circular dichroism. In this work, first demonstration MCPL presented in heterometallic lanthanide(III) systems using two molecular cluster aggregates, {Eu 1 Tb 19 } 3 17 . The results here indicate potential that holds for obtaining highly tuned magneto‐optical materials various applications, such as anti‐counterfeiting materials. Additionally, findings suggest interactions between ions modulate dissymmetry factor, opening possibility development tunable

Language: Английский

Citations

3
Distortion Engineering: A Strategy to Modulate Molecular Upconversion with Molecular Cluster-Aggregates DOI
Diogo A. Gálico, Alexandros A. Kitos, Rayan Ramdani

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 20, 2024

The rational engineering of molecules is a powerful chemistry tool pivotal importance in the fields molecular magnetism and luminescence. Hence, systems that can be modulated via composition control are expected to present extra versatility regarding tunability their properties. This case with cluster aggregates (MCAs), high nuclearity compounds. Herein, we demonstrate how union both strategies, namely, engineering, employed enhance upconversion MCAs. was achieved by doping

Language: Английский

Citations

3
Heteronuclear lanthanide titanium-oxygen cluster luminescence thermometer with adjustable operating range and sensitivity DOI
Tingting Li,

Jin-Zhe Liu,

Shaojiang Zheng

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 16, 2024

Language: Английский

Citations

3
Anti-thermal quenching in NdIII molecular near-infrared thermometers operating at physiological temperatures DOI Creative Commons
María José Maldonado,

Patricia Farías-Carreño,

Yolimar Gil

et al.

Communications Chemistry, Journal Year: 2025, Volume and Issue: 8(1)

Published: May 3, 2025

Examples of molecular complexes acting as thermometers operating at room temperature in near infrared region are scarce, therefore this work showcases the anti-thermal quenching effect on neodymium(III) working biological windows within physiological range. A mononuclear complex, [Nd(L)(NO3)3] (1Nd), where L is a macrocyclic ligand, was synthesized and used precursor to develop two novel species: dinuclear, [(Nd(L)(NO3))2(µ-BDC)](NO3)2·H2O (2Nd), linked by 1,4-benzenedicarboxylate (BDC), hexameric, [(Nd(L))(µ-BTC)(H2O)]6·35H2O (6Nd), with 1,3,5-benzenetricarboxylate (BTC). Thermometric properties were studied range (292-332 K), utilizing 804 nm laser excitation (first window) monitoring emissions second window (908, 1065, 1340 nm) associated 4F3/2 → 4I9/2, 4I11/2, 4I13/2 transitions, respectively. Among complexes, hexamer 6Nd exhibited exceptional performance, Sr 2.4%K-1 293 K, when luminescence intensity ratio (LIR) Stark components 4I11/2 emission used, positioning it high-performance NdIII-based thermometer. All displayed behavior, surpassing current molecular-based near-infrared region. Theoretical calculations using complete active space self consistent field (CASSCF) Boltzmann population models between Kramers doublets level performed rationalize behavior.

Language: Английский

Citations

0
Hybrid multifunctionalized mesostructured stellate silica nanoparticles loaded with β-diketonate Tb3+/Eu3+ complexes as efficient ratiometric emissive thermometers working in water DOI Creative Commons
Tristan Pelluau, Saad Sene, Lamiaa M. A. Ali

et al.

Nanoscale, Journal Year: 2023, Volume and Issue: 15(35), P. 14409 - 14422

Published: Jan. 1, 2023

Despite the great effort made in recent years on lanthanide-based ratiometric luminescent nanothermometers able to provide temperature measurements water, their design remains challenging. We report synthesis and properties of efficient that are based mesoporous stellate nanoparticles (MSN) ca. 90 nm functionalized with an acetylacetonate (acac) derivative inside pores loaded β-diketonate-Tb3+/Eu3+ complexes work PBS or cells. Encapsulating a [(Tb/Eu)9(acac)16(μ3-OH)8(μ4-O)(μ4-OH)] complex (Tb/Eu ratio = 19/1 9/1) led hybrid multifunctionalized exhibiting Tb3+ Eu3+ characteristic temperature-dependent luminescence high rate Tb3+-to-Eu3+ energy transfer. According theoretical calculations, modifications photoluminescence increase pairwise transfer by about 10 times can be rationalized as change coordination number Ln3+ sites from 7 8 accompanied symmetry evolution Cs C4v slight shortening intramolecular Ln3+-Ln3+ distances upon effect encapsulation. These operate 20-70 °C range excellent photothermal stability, cyclability repeatability (>95%), displaying maximum relative thermal sensitivity 1.4% °C-1 (at 42.7 °C) water. Furthermore, they cells 8.6% 40 °C), keeping mind adjusting calibration for each system is necessary ensure accurate measurements.

Language: Английский

Citations

9
Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry DOI Creative Commons
Gautier Félix≠, Saad Sene, Alena N. Kulakova

et al.

RSC Advances, Journal Year: 2023, Volume and Issue: 13(37), P. 26302 - 26312

Published: Jan. 1, 2023

Mixed-lanthanide silsesquioxane cages: to combine a slow relaxation of the magnetization and luminescent thermometry.

Language: Английский

Citations

9
A review on designing and synthesis of lanthanide based macrocyclic complexes and their potential applications DOI

Krishna Atal,

Urmila Phageria,

Sushama Kumari

et al.

Inorganica Chimica Acta, Journal Year: 2023, Volume and Issue: 561, P. 121857 - 121857

Published: Nov. 19, 2023

Language: Английский

Citations

8