Controlling Electron Delocalization in Vanadium‐Based Hybrid Bronzes through Molecular Templation DOI Open Access
Suchen Wan,

Nicole Musielak,

Allen G. Oliver

et al.

Angewandte Chemie, Journal Year: 2023, Volume and Issue: 135(51)

Published: Nov. 2, 2023

Abstract We show that the conductivity of hybrid vanadium bronzes—mixed‐valence organic–inorganic oxides—can be tuned over six orders magnitude through judicious choice molecular component. By systematically varying steric profile, charge density, and propensity to hydrogen bond across a series eight diammonium‐based molecules, we engender multiple distinct motifs V−O connectivity within two‐dimensional oxide layers family bulk crystalline materials. A combination single‐crystal powder X‐ray diffraction analysis, variable‐temperature electrical transport measurements, range spectroscopic methods, including UV/Visible diffuse reflectance, photoelectron, electron paramagnetic resonance are employed probe how layer topology correlates with localization. Specifically, alkylammonium molecules yield hybrids featuring more corrugated contain tetrahedra as well higher ratio corner‐sharing edge‐sharing polyhedra exhibit highly localized electronic behavior, while alkyl bipyridinium regular polyhedral substantially delocalized behavior. This work allows for development design principles based on structure–property relationships brings capabilities bronzes technologically relevant levels.

Language: Английский

Hybrid bilayered vanadium oxide electrodes with large and tunable interlayer distances in lithium-ion batteries DOI
Xinle Zhang, Ryan Andris, Timofey Averianov

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 674, P. 612 - 623

Published: June 24, 2024

Language: Английский

Citations

5
Interlayer pillaring influences the octahedral tilting and electrochemical capacity of tungsten oxides DOI Creative Commons
Ran Ding, Michael A. Spencer, Noah P. Holzapfel

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Pillaring tungsten oxides with alkylammonium cations increases the interlayer spacing but decreases band gap, leading to low electrochemical capacity.

Language: Английский

Citations

0
Mechanism of Charge Transport in Mixed-Valence 2D Layered Hybrid Organic–Inorganic Bronze Materials DOI

Suchona Akter,

Mohammad R. Momeni

The Journal of Physical Chemistry C, Journal Year: 2025, Volume and Issue: unknown

Published: May 13, 2025

Language: Английский

Citations

0
Mixed-Metal Alloying in Hybrid Bronzes DOI
Anton F. Walte, Raúl Torres-Cadena, W. Lakna N. Dayaratne

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(34), P. 23699 - 23703

Published: Aug. 19, 2024

We show that substitutional alloying during the aqueous self-assembly of layered organic-templated metal oxides produces single-phase mixed-metal hybrids. Single-crystal X-ray diffraction, bulk elemental analyses, and vibrational electronic spectroscopies corroborate a solid solution Mo W atoms at lattice sites within two-dimensional oxide layers. Mild postsynthetic reduction then introduces relatively delocalized electrons to afford hybrid bronzes. To our knowledge, this represents first demonstration in rare example solid-solution formation low temperature. approach yields congeners with optical band gaps over 130 meV smaller than those single-metal analogs, while achieving activation energies (Ea) conduction as 78.4(2) meV. Further, substitution appears tune collective phenomena by suppressing non-Arrhenius behavior observed for Mo-based This work considerably expands nascent bronze platform help address energy-related challenges fundamental solid-state physical questions.

Language: Английский

Citations

3
Controlling Electron Delocalization in Vanadium‐Based Hybrid Bronzes through Molecular Templation DOI
Suchen Wan,

Nicole Musielak,

Allen G. Oliver

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(51)

Published: Nov. 2, 2023

We show that the conductivity of hybrid vanadium bronzes-mixed-valence organic-inorganic oxides-can be tuned over six orders magnitude through judicious choice molecular component. By systematically varying steric profile, charge density, and propensity to hydrogen bond across a series eight diammonium-based molecules, we engender multiple distinct motifs V-O connectivity within two-dimensional oxide layers family bulk crystalline materials. A combination single-crystal powder X-ray diffraction analysis, variable-temperature electrical transport measurements, range spectroscopic methods, including UV/Visible diffuse reflectance, photoelectron, electron paramagnetic resonance are employed probe how layer topology correlates with localization. Specifically, alkylammonium molecules yield hybrids featuring more corrugated contain tetrahedra as well higher ratio corner-sharing edge-sharing polyhedra exhibit highly localized electronic behavior, while alkyl bipyridinium regular polyhedral substantially delocalized behavior. This work allows for development design principles based on structure-property relationships brings capabilities bronzes technologically relevant levels.

Language: Английский

Citations

6
An Insightful Study on the Reduction and Extraction of Neptunium Assisted by Molybdenum DOI
Huaixin Hao, Yaoyang Liu,

Hong Thi Cao

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(44), P. 17909 - 17917

Published: Jan. 1, 2024

Mo dramatically boosts the extraction of Np( v ) by TRPO through catalytic reduction effect in both aqueous phase and organic phase.

Language: Английский

Citations

1
Hybrid Bilayered Vanadium Oxide Electrodes with Large and Tunable Interlayer Distance in Lithium-Ion Batteries DOI
Xinle Zhang, Ryan Andris, Timofey Averianov

et al.

Published: Jan. 1, 2024

Download This Paper Open PDF in Browser Add to My Library Share: Permalink Using these links will ensure access this page indefinitely Copy URL DOI

Language: Английский

Citations

0
Real-time observation of crystals growth under optical microscopy: A self-assembly process of organic-inorganic intercalation composites driven by electrostatic interaction DOI

Zhaokang Zheng,

Zhen Liu, Yujie Ma

et al.

Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 41, P. 102334 - 102334

Published: Oct. 1, 2024

Language: Английский

Citations

0
Controlling Electron Delocalization in Vanadium‐Based Hybrid Bronzes through Molecular Templation DOI Open Access
Suchen Wan,

Nicole Musielak,

Allen G. Oliver

et al.

Angewandte Chemie, Journal Year: 2023, Volume and Issue: 135(51)

Published: Nov. 2, 2023

Abstract We show that the conductivity of hybrid vanadium bronzes—mixed‐valence organic–inorganic oxides—can be tuned over six orders magnitude through judicious choice molecular component. By systematically varying steric profile, charge density, and propensity to hydrogen bond across a series eight diammonium‐based molecules, we engender multiple distinct motifs V−O connectivity within two‐dimensional oxide layers family bulk crystalline materials. A combination single‐crystal powder X‐ray diffraction analysis, variable‐temperature electrical transport measurements, range spectroscopic methods, including UV/Visible diffuse reflectance, photoelectron, electron paramagnetic resonance are employed probe how layer topology correlates with localization. Specifically, alkylammonium molecules yield hybrids featuring more corrugated contain tetrahedra as well higher ratio corner‐sharing edge‐sharing polyhedra exhibit highly localized electronic behavior, while alkyl bipyridinium regular polyhedral substantially delocalized behavior. This work allows for development design principles based on structure–property relationships brings capabilities bronzes technologically relevant levels.

Language: Английский

Citations

0