EcoEnergy,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 12, 2024
Abstract
The
electrochemical
synthesis
for
value‐added
chemicals
and
fuels
via
carbon
dioxide
reduction
reaction
(CO
2
RR)
offers
an
effective
route
to
close
the
anthropogenic
cycle
store
renewable
energy.
Currently,
copper‐based
catalyst
is
still
only
choice
generating
various
CO
RR
species
beyond
two
electron
products.
However,
wide
range
of
products
generated
on
copper
leads
low
selectivity,
their
concentrations
in
electrolytes
pose
great
costs
downstream
purification
process
significantly
challenge
scalability
this
technology.
To
make
technology
economically
viable,
enhancing
product
selectivity
crucial.
In
review,
we
identify
primary
discuss
latest
insights
into
mechanisms
controlling
selectivity.
Then,
examined
factors
that
affect
Emphasizing
these
design,
highlight
importance
advanced
technologies
expand
our
knowledge
prospects
future
RR.
Energy & Environmental Science,
Journal Year:
2024,
Volume and Issue:
17(16), P. 5795 - 5818
Published: Jan. 1, 2024
Recent
developments
in
heteroatom-doped
Cu-based
catalysts
for
CO
2
electroreduction
into
C
2+
products
are
highlighted.
The
design
strategies
doped
and
situ
technologies
discussed.
Accounts of Materials Research,
Journal Year:
2024,
Volume and Issue:
5(6), P. 712 - 725
Published: May 15, 2024
ConspectusRare
earth
interface
structure
materials
(RE-ISM)
play
a
crucial
role
in
the
field
of
inorganic
synthesis
and
provide
an
effective
means
achieving
refined
utilization
rare
elements.
By
capitalizing
on
unique
properties
earth,
these
are
designed
for
functional
applications
at
interfaces.
Given
escalating
energy
environmental
concerns,
there
is
urgent
need
to
expedite
development
efficient
pathways
clean
storage
conversion.
Electrocatalytic
conversion
energetic
small
molecule
way
with
as
carrier.
However,
catalysts
often
constrained
by
limitations
catalyst
system
lack
clarity
regarding
reaction
processes.
It
provides
new
opportunities
design
catalytic
developing
RE-ISM
analyzing
dynamic
evolution
process
across
time
space
dimensions.In
this
Account,
we
mainly
focus
research
progress
synthesis,
application,
mechanism
order
effectively
high-performance
materials.
classified
into
three
categories
based
size
substrate,
following
guidance
provided
phase
diagram.
includes
atomic
interfaces,
cluster
heterstructures.
strategically
designing
diverse
structures,
it
feasible
synthesize
material
systems
that
tailored
toward
multitude
applications.
The
synthesized
employed
electrocatalytic
molecules,
offering
novel
prospects
electrode
redox
both
negative
positive
grades
involves
structural
molecules
through
electron
transfer.
facilitating
such
reactions.
Achieving
construction
necessitates
in-depth
analysis
mechanisms
employing
situ
spectroscopy
technology.
transformation
morphology,
structure,
was
analyzed
from
perspective
resolution,
spatial
spectral
resolution.
We
elucidate
correlation
between
interaction
intrinsic
cognitive
foundation
analysis.
This
theoretical
support
RE-ISM.
In
summary,
expect
will
ideas
insights
further
promote
rapid
high
performance
Chemical Society Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
This
review
discusses
the
behavior
of
low-concentration
carbon
dioxide
(LCC)
in
multiphase
flows
and
interfaces,
covering
diffusion,
adsorption,
catalytic
mechanisms,
applications
CO
2
capture,
storage,
conversion,
challenges,
prospect.
Energy Materials,
Journal Year:
2025,
Volume and Issue:
5(5)
Published: Feb. 25, 2025
Recent
research
on
the
electrocatalytic
CO2
reduction
reaction
(eCO2RR)
has
garnered
significant
attention
given
its
capability
to
address
environmental
issues
associated
with
emissions
while
harnessing
clean
energy
produce
high-value-added
products.
Compared
C1
products,
C2+
products
provide
greater
densities
and
are
highly
sought
after
as
chemical
feedstocks.
However,
formation
of
C-C
bond
is
challenging
due
competition
H-H
C-H
bonds.
Therefore,
elevate
selectivity
yield
fuels,
it
essential
develop
more
advanced
electrocatalysts
optimize
design
electrochemical
cell
configurations.
Of
materials
investigated
for
CO2RR,
Cu-based
stand
out
their
wide
availability,
affordability,
compatibility.
Moreover,
catalysts
exhibit
promising
capabilities
in
adsorption
activation,
facilitating
compounds
via
coupling.
This
review
examines
recent
both
cells
electroreduction
compounds,
introducing
core
principles
eCO2RR
pathways
involved
generating
A
key
focus
categorization
catalyst
designs,
including
defect
engineering,
surface
modification,
nanostructure
tandem
catalysis.
By
analyzing
studies
catalysts,
we
aim
elucidate
mechanisms
behind
enhanced
compounds.
Additionally,
various
types
electrolytic
discussed.
Lastly,
prospects
limitations
utilizing
highlighted
future
research.
