Chinese Journal of Polymer Science, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 25, 2024
Language: Английский
Chinese Journal of Polymer Science, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 25, 2024
Language: Английский
Chemical Science, Journal Year: 2024, Volume and Issue: 15(27), P. 10281 - 10307
Published: Jan. 1, 2024
Delving into the tools empowering polymer chemists to design polymers for roles as solid electrolytes, multifunctional binders and active electrode materials in cutting-edge solid-state batteries wearable devices.
Language: Английский
Citations
9Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown
Published: May 31, 2024
Improving composite cathode function is key to the success of solid-state battery. Maximizing attainable capacity and retention requires integrating suitable polymeric binders that retain a sufficiently high ionic conductivity long-term chemo-mechanical stability active material-solid-electrolyte-carbon mixture. Herein, we report block copolymer networks composed lithium borate polycarbonates poly(ethylene oxide) improved (200 mAh g
Language: Английский
Citations
4ChemElectroChem, Journal Year: 2024, Volume and Issue: 11(15)
Published: July 12, 2024
Abstract Rechargeable polymer‐based solid‐state batteries with metallic lithium anodes and LiNi x Mn y Co 1− − O 2 (NMC)‐based cathodes promise safer high‐energy‐density storage solutions than existing lithium‐ion batteries, but have shown challenging to realize. The failure mechanisms that been suggested for these battery cells mostly related the use of a anode formation dendrites during cycling. Here, we approach issue using solid polymer electrolytes (SPEs) vs. NMC by employing range materials based on poly(ϵ‐caprolactone‐ co ‐trimethylene carbonate) (PCL‐PTMC) different salts under various cycling conditions. It is seen although ionic conductivity electrolyte can be improved exchanging salt, it does not immediately correlate better performance. However, increasing temperature improve ion transport kinetics lowers polarization cell full capacity achieved at an upper voltage cut‐off appropriate electrolyte. For electrolytes, limit demonstrated 4.4 V Li + /Li, NMC‐111 thereby possible provided limited below this limit.
Language: Английский
Citations
3Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 16, 2025
Abstract Polyester thermoplastic elastomers are promising sustainable materials but their mechanical properties need improvement, in particular, attempts to increase strength often result compromised elasticity. Strong and tough known require complex polymer formulations together with control over cross‐linking or crystallinity, both of which challenge recycling. Here, the introduction transient strain‐stiffening approaches into fully amorphous structures show strengthening toughening while conserving recyclability. The new block polyester prepared by controlled polymerization methods using commercial monomers. polymers comprise a central poly(ɛ‐caprolactone‐ co ‐ɛ‐decalactone) flanked poly(cyclohexene oxide‐ alt ‐phthalate) blocks. Elastomer thermomechanical tuned varying ratios ɛ‐caprolactone ɛ‐decalactone within mid‐block access excellent properties. best feature 30–50 wt.% polycaprolactone exhibit tensile strengths up 40 MPa, elongations at break above 2000%, elastic recovery (>90%). These strain‐induced crystallization outperform current elastomers, entering region property space. They have service temperature ranges from −60 140 °C high stability (≥300 °C), wide thermal (re)processing windows. also resistance creep, humidity resistance,
Language: Английский
Citations
0Smart Molecules, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 1, 2024
Abstract Aliphatic polyesters and polycarbonates are among the promising sustainable polymers, which exhibit unique degradability chain‐chain interactions owing to their heterofunctionality. However, monocomponent aliphatic usually suffer from inferior properties functionalities. By contrast, precisely modulated block copolymers composed of give rise materials with tailored performance. An efficient approach synthesize is ring‐opening (co)polymerization heterocycle monomers. Herein, this review presents monomer for formation sequence‐controlled polycarbonates. Available synthetic strategies, different monomers, combinations catalyst systems summarized.
Language: Английский
Citations
1Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown
Published: May 31, 2024
Abstract Improving composite cathode function is key to the success of solid‐state battery. Maximizing attainable capacity and retention requires integrating suitable polymeric binders that retain a sufficiently high ionic conductivity long‐term chemo‐mechanical stability active material‐solid‐electrolyte‐carbon mixture. Herein, we report block copolymer networks composed lithium borate polycarbonates poly(ethylene oxide) improved (200 mAh g −1 at 1.75 mA cm −2 ) (94 % over 300 cycles) all‐solid‐state cathodes with nickel‐rich LiNi 0.8 Co 0.1 Mn O 2 material, Li 6 PS 5 Cl solid electrolyte, carbon. Tetrahedral B(OR) (OH) − anions immobilized on polycarbonate segments provide hydrogen‐bonding chain crosslinking selective Li‐counterion conductivity, parameterized by Li‐ion transference numbers close unity ( t Li+ ~0.94). With 90 wt content flexible low glass transition temperature backbone, single‐ion conductors achieved conductivities 0.2 mS 30 °C. The work should inform future binder design for improving processability composites towards commercializing batteries, allow use in other cell configurations, such as lithium‐sulphur designs.
Language: Английский
Citations
0Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(32), P. 20947 - 20957
Published: Jan. 1, 2024
We demonstrate the post-synthetic conversion of polyethylene into functional polymer electrolytes for lithium-ion batteries. To avoid end-of-life contributing to waste, we further upcycle them useful organic acids.
Language: Английский
Citations
0Chinese Journal of Polymer Science, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 25, 2024
Language: Английский
Citations
0