Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 5, 2024
Abstract
Industrial
production
of
H
2
O
requires
lots
energy
and
causes
environmental
pollution.
Moreover,
in
subsequent
applications,
much
economic
loss
could
be
produced
during
the
transportation
process
its
dilution
process.
Therefore,
it
is
highly
desirable
for
situ
application
.
In
recent
years,
catalytic
synthesis
,
e.
g.,
direct
synthesis,
electrocatalytic
photocatalytic
has
attracted
more
attention
because
continuous
low‐concentration
by
can
directly
used
oxidation
organic
compounds,
effectively
avoiding
shortcomings
current
industrial
route.
Here,
we
briefly
reviewed
latest
processes
via
various
routes.
On
this
basis,
summarized
discussed
typical
conversion
reactions,
including
ammoximation
ketones,
alcohols,
C−H
bonds,
olefins.
Some
coupling
reactions
have
shown
excellent
performance
with
high
selectivity,
cost
been
significantly
reduced.
Finally,
utilization
were
analyzed,
some
strategies
promoting
efficiency
proposed.
Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
30(44)
Published: June 4, 2024
Abstract
Plastic
pollution
constitutes
an
evergrowing
urgent
environmental
problem,
since
overaccumulation
of
plastic
waste,
arising
from
the
immense
increase
production
disposable
products,
overcame
planet's
capacity
to
properly
handle
them.
Chemical
upcycling
polystyrene
a
convenient
method
for
conversion
waste
into
high‐added
value
chemicals,
suggesting
attractive
perspective
in
dealing
with
crisis.
We
demonstrate
herein
novel,
easy‐to‐perform
organocatalytic
photoinduced
aerobic
protocol,
which
proceeds
via
synergistic
indirect
hydrogen
atom
transfer
(HAT)
catalysis
under
LED
390
nm
Kessil
lamps
as
irradiation
source.
The
developed
employs
BrCH
2
CN‐thioxanthone
photocatalytic
system
and
was
successfully
applied
variety
everyday‐life
leading
isolation
benzoic
acid
after
simple
base‐acid
work
up
yields
varying
23–49
%,
while
large‐scale
experiment
performed,
that
step
is
susceptible
industrial
application.
Applied Organometallic Chemistry,
Journal Year:
2025,
Volume and Issue:
39(5)
Published: April 15, 2025
ABSTRACT
A
novel
mononuclear
Cr(III)
coordination
compound,
[Cr(HL)(N
3
)
2
],
was
synthesized
by
the
reaction
of
CrCl
·6H
O
and
NaN
with
Schiff
base
ligand
(H
L‐Cl).
The
]
were
characterized
spectroscopic
methods.
Single‐crystal
X‐ray
analysis
also
accomplished
to
confirm
structure
compound.
According
results
analysis,
this
compound
crystallizes
in
triclinic
system
P‐1
space
group
CrN
6
environment
around
ion
can
be
described
as
a
distorted
octahedral
geometry.
catalytic
activity
investigated
oxidation
benzyl
alcohol
presence
hydrogen
peroxide.
effects
various
parameters
investigated,
such
amount
catalyst,
concentration
oxidant,
temperature
solvent.
show
that
has
high
stability
could
selectively
convert
into
benzaldehyde.
electrochemical
behaviors
cyclic
voltammetry.
European Journal of Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
27(13)
Published: Feb. 10, 2024
Abstract
The
epoxidation
of
alkenes
has
altered
and
reshaped
the
way
scientists
think
in
modern
organic
synthesis.
Herein,
a
novel,
sustainable
eco‐friendly
protocol
for
is
reported,
utilizing
hydrogen
peroxide
as
green
oxidant
and,
first
time,
hydroxamic
acid
derivatives
organocatalyst.
presented
methodology
very
effective,
leading
to
good
high
yields
oxidation
variety
olefins,
while
various
functional
groups
are
well
tolerated.
Mechanistic
studies
direct
infusion
resolution
mass
spectrometry
(DI‐HRMS)
provide
strong
evidence
mechanism
organocatalytic
oxidation.
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(8), P. 4880 - 4887
Published: Jan. 1, 2024
Irradiation
of
a
solution
an
unsaturated
benzyl
alcohol
in
DMSO
under
oxygen
leads
to
ketone
formation.
Side-oxidations
are
minimized,
thanks
the
protective
role
solvent
against
singlet
oxygen.
No
catalyst
or
additives
required.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(30), P. 12126 - 12137
Published: Jan. 1, 2024
Se(
iv
)
seleninic
acid
is
the
active
catalyst
in
aniline
oxidation
by
H
2
O
due
to
its
favorable
peroxide
activation
kinetics.
The
slow
formation
of
vi
selenonic
and
poorer
performance
hinder
catalytic
role.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(38), P. 15745 - 15750
Published: Jan. 1, 2024
The
powerful
PPNCl
catalyst
can
be
converted
into
a
recyclable
and
more
soluble
polymeric
version
through
post-polymerisation
modification
of
triphenylphosphine-decorated
copolymer.
Dalton Transactions,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
The
need
for
effective
alternative
energy
sources
and
"green"
industrial
processes
is
a
more
crucial
societal
topic
than
ever.
In
this
context,
mastering
oxygen
reduction
reactions
(ORRs)
key
step
to
develop
fuel
cells
or
propose
alternatives
energy-intensive
setups
such
as
the
anthraquinone
process
hydrogen
peroxide
production.
Achieving
goal
using
bio-inspired
metal
complexes
based
on
abundant
non-toxic
elements
could
provide
an
environmentally
friendly
option.
Given
prevalence
of
Cu-containing
active
sites
capable
reductive
activation
dioxygen
in
nature,
development
Cu-based
catalysts
ORR
thus
appears
be
relevant
approach.
We
herein
report
preparation,
full
characterization
(TD)DFT
investigation
new
dinuclear
mixed-valent
copper
complex
6
exhibiting
Cu
