Journal of Agricultural and Food Chemistry,
Journal Year:
2024,
Volume and Issue:
72(42), P. 22985 - 23007
Published: Oct. 9, 2024
Efficient
management
of
crop
diseases
and
yield
enhancement
are
essential
for
addressing
the
increasing
food
demands
due
to
global
population
growth.
Metal-organic
frameworks
(MOFs),
which
have
rapidly
evolved
throughout
21st
century,
notable
their
vast
surface
area,
porosity,
adaptability,
establishing
them
as
highly
effective
vehicles
controlled
drug
delivery.
This
review
methodically
categorizes
common
MOFs
employed
in
disease
details
effectiveness
against
various
pathogens.
Additionally,
by
critically
evaluating
existing
research,
it
outlines
strategic
approaches
design
drug-delivery
explains
mechanisms
through
enhance
resistance.
Finally,
this
paper
identifies
current
challenges
MOF
research
suggests
directions
future
research.
Through
in-depth
review,
seeks
enrich
understanding
applications
offers
valuable
insights
researchers
practitioners.
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(29), P. 20333 - 20348
Published: July 10, 2024
Metal-organic
frameworks
(MOFs)
are
porous
materials
with
applications
in
gas
separations
and
catalysis,
but
a
lack
of
water
stability
often
limits
their
practical
use
given
the
ubiquity
water.
Consequently,
it
is
useful
to
predict
whether
MOF
water-stable
before
investing
time
resources
into
synthesis.
Existing
heuristics
for
designing
MOFs
generality
limit
diversity
explored
chemistry
due
narrowly
defined
criteria.
Machine
learning
(ML)
models
offer
promise
improve
predictions
require
data.
In
an
improvement
on
previous
efforts,
we
enlarge
available
training
data
prediction
by
over
400%,
adding
911
labels
assigned
through
semiautomated
manuscript
analysis
curate
new
set
WS24.
The
additional
shown
ML
model
performance
(test
ROC-AUC
>
0.8)
diverse
both
harsher
acidic
conditions.
We
illustrate
how
expanded
can
be
used
previously
developed
activation
combination
genetic
algorithms
quickly
screen
∼10,000
from
space
hundreds
thousands
candidates
multivariate
(upon
activation,
water,
acid).
uncover
metal-
geometry-specific
design
rules
robust
MOFs.
this
work,
which
disseminate
easy-to-use
web
interface,
expected
contribute
toward
accelerated
discovery
novel,
such
as
direct
air
capture
treatment.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(45), P. 18715 - 18750
Published: Jan. 1, 2024
The
construction
of
functional
structures
within
a
single
plane
still
has
lot
challenges.
This
review
article
will
help
us
find
new
groundbreaking
directions
in
lateral
nanoarchitectonics
toward
advanced
material
organization.
Materials Today Catalysis,
Journal Year:
2024,
Volume and Issue:
5, P. 100051 - 100051
Published: May 12, 2024
Ribbon-like
coordination
polymers
(CP)
represents
a
highly
unexplored
innovative
class
of
metal-coordination
network.
Herein,
we
have
developed
scalable
and
chemically
robust
(pH=3-10
stable)
ribbon-like
CP
[{Cu(Pim)(L)(H2O).H2O}]n
(1)
following
complete
environment-friendly
green
synthesis
route.
Considering
the
presence
surface
flanked
labile
coordinated
water
molecules
their
appealing
correlation
with
one-dimensional
structural
characteristics,
such
sort
was
explored
for
first
time
as
excellent
heterogeneous
catalyst
largely
three-component
Hantzsch
condensation
different
classes
dihydropyridine
(DHP).
Moreover,
1
is
employed
to
synthesize
bio-responsive
drug
'Ethidine'
(possessing
high
anti-oxidant
anticarcinogenic
properties)
characterized
Single
Crystal
X-ray
Diffraction
(SCXRD)
analysis.
Several
DHP-based
products
are
also
analysed
through
in-depth
SCXRD
This
report
inaugurates
usage
Cu(II)
based
CPs
environmentally
benign
manner
bioactive
DHPs
Drugs.
Bulletin of the Korean Chemical Society,
Journal Year:
2024,
Volume and Issue:
45(8), P. 675 - 688
Published: June 18, 2024
Abstract
Anthropogenic
carbon
dioxide
(CO
2
)
emissions
pose
a
significant
threat
to
the
delicate
balance
between
human
society
and
natural
environment.
Carbon
capture
sequestration
is
technology
designed
selectively
CO
generated
from
power
plants
industrial
facilities,
preventing
them
entering
atmosphere.
Diamine‐modified
metal–organic
frameworks
(MOFs)
show
promising
capabilities
in
achieving
remarkable
capacities,
highlighting
their
potential
for
effective
applications.
Herein,
using
MOF‐74
type
frameworks,
we
discussed
our
various
methodologies
enhance
adsorption
capacity,
while
also
tackling
issue
of
maintaining
structural
integrity
over
prolonged
periods,
especially
humid
environments.
The
challenges
prospects
by
diamine‐functionalized
hydrophobic
MOFs
are
highlighted.
Separation Science and Technology,
Journal Year:
2025,
Volume and Issue:
unknown, P. 1 - 14
Published: Jan. 14, 2025
This
work
focuses
on
the
effect
of
organic
linker
functionality
adsorption
characteristics
CO2,
CH4,
CO,
and
N2
over
UiO-66,
UiO-66-NH2,
UiO-66-NO2,
UiO-66-COOH,
UiO-66-(COOH)2.
Introducing
polar
complex
functional
groups
such
as
–
NH2,
–NO2,
–COOH,
–(COOH)2
improved
capacity
but
also
reduced
free
volume,
negatively
impacting
adsorption.
In
low-pressure
region,
played
a
dominant
role,
whereas
at
saturation,
pore
volume
Metal-Organic
Frameworks
contributed
more
to
uptake.
For
all
studied
gases,
Type-I
isotherm
was
observed.
The
isotherms
were
modeled
using
virial
equation,
model
parameters
used
calculate
enthalpies
Ideal
Adsorbed
Solution
Theory
predict
selectivity
binary
mixtures.
CO2
showed
that
introducing
larger
caused
sudden
decrease
in
with
increasing
temperature;
this
difference
significant
lower
temperatures
negligible
higher
temperatures.
