Modulating the Supramolecular Assembly of α‐Cyclodextrin and Anderson‐type Polyoxometalate through Covalent Modifications DOI
Chunyan Liu,

Yun‐Jing Mu,

Wu‐Ji Chen

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 11, 2024

A series of unprecedented supramolecular complexes covalently modified Anderson-type polyoxometalates (POMs) and α-cyclodextrins (α-CDs) have been obtained characterized in solid state by single-crystal X-ray diffraction, aqueous solution using various techniques including

Language: Английский

Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications DOI
Zhengfen Liu, Xiaobo Li,

Weijun Dai

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 526, P. 216350 - 216350

Published: Nov. 29, 2024

Language: Английский

Citations

37
Naphthalenediimide-Based Hybrid Material with Eu-Substituted Polyoxometalate: Photochromism, Near-Infrared Photothermal Conversion, and C-3 Functionalization of Indoles DOI

Silang Chen,

Qi Yang, Xiang Shen

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 7, 2025

Designing and developing novel photochromic materials with additional functions such as photothermal conversion photocatalysis are challenging but meaningful objectives. Crystalline naphthalenediimide (NDI)-based hybrids an attractive class of multifunctional fast-response photoinduced electron transfer charge separation properties. They promising photocatalysts. Herein, a hybrid material, EuPMo11O39(L)1.5(H2O)2]·DMA (EuMo-NDI) (L = N,N'-di(1-oxido-4-pyridyl)-1,4,5,8-naphthalenediimide), was prepared solvothermal method, integrating photoactive NDI derivative Eu-substituted polyoxometalate. EuMo-NDI exhibits 0D structure sensitive behavior under UV-vis light irradiation due to between its components. The colored sample demonstrated efficient near-infrared the strong absorption photogenerated radical anion NDI•- mixed valence heteropoly blue in region. Meanwhile, is easily excited presence donors form species, which can activate inert O2 superoxide O2•-. exhibited high photocatalytic activity for C-3 thiocyanation indoles mild conditions using white driving force. This work provides effective avenue design photocatalysts platforms.

Language: Английский

Citations

2
Polyoxometalate-based materials in therapeutic and biomedical applications: current status and perspective DOI

Milad Moghadasi,

Mohammad Abbasi, Mohammad Ebrahim Mousavi

et al.

Dalton Transactions, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Recent advances in polyoxometalate (POM)-based materials with biomedical applications indicate significant potential the therapeutic field. The scientific community aims to advance these enhance bioorthogonal chemistry of POMs.

Language: Английский

Citations

0
The effect of ionic versus covalent functionalization of polyoxometalate hybrid materials with coordinating subunits on their stability and interaction with DNA DOI
Daria Nowicka, Dawid Marcinkowski, Nahir Vadra

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(28), P. 11678 - 11688

Published: Jan. 1, 2024

The nature of the polyoxometalate (POM) and coordinating subunit (CSU) modulate stability POM-CSU hybrid DNA binding.

Language: Английский

Citations

2
Polyoxometalate-based peroxidase-mimicking sensors for colorimetric detection and discrimination of phenolic pollutants DOI
Yuan‐Yuan Ma,

Zhao-Bin Li,

Xing-Pu Zhao

et al.

Microchemical Journal, Journal Year: 2024, Volume and Issue: 205, P. 111297 - 111297

Published: July 26, 2024

Language: Английский

Citations

2
Enhancing flame retardancy and smoke suppression of wood via in-situ synthesis of amine-phosphotungstic acid nanoparticles with tunable shapes DOI

Zhongwei Wang,

Yan Qing, Zhu Liu

et al.

Construction and Building Materials, Journal Year: 2024, Volume and Issue: 456, P. 139226 - 139226

Published: Nov. 22, 2024

Language: Английский

Citations

2
Copper-bonded polyoxomolybdates-based framework as a heterogeneous catalyst for the cascade click reaction and bromination DOI

Shiqi Fu,

Gang Liu, Sen Liu

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 562, P. 114185 - 114185

Published: May 9, 2024

Language: Английский

Citations

1
Using Coordination Chemistry to Control “Click” Reactions: The Selective Formation of Asymmetrically Ligated Polyoxometalates DOI
Stanislav K. Petrovskii, Marco Moors, D. Fuhrmann

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(29), P. 13785 - 13792

Published: July 4, 2024

The Cu(I)-catalyzed azide-alkyne cycloaddition reaction between (NBu

Language: Английский

Citations

1
Cluster-Cation Pairs Mediated Assembly of Subnanometer Polyoxometalates Superstructures DOI
Zhong Li, Haoyang Li, Yan Lin

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(42), P. 28874 - 28884

Published: Oct. 10, 2024

Superstructures assembled by subnanometer polyoxometalate (POM) clusters are interesting for their attractive structures and excellent properties. However, the complex interactions between cations make it challenging to control assembly of POM at scale. Here, 20 cluster-assembled superstructures built two types MP

Language: Английский

Citations

1
Monomeric, Oligomeric, Polymeric, and Supramolecular Cyclodextrins as Catalysts for Green Chemistry DOI Creative Commons
Makoto Komiyama

Research, Journal Year: 2024, Volume and Issue: 7

Published: Jan. 1, 2024

This review comprehensively covers recent developments of cyclodextrin-mediated chemical transformations for green chemistry. These cyclic oligomers glucose are nontoxic, eco-friendly, and recyclable to accomplish eminent functions in water. Their most important feature is form inclusion complexes with reactants, intermediates, and/or catalysts. As a result, their cavities serve as sterically restricted apolar reaction fields promote the efficiency selectivity reactions. Furthermore, unstable reagents intermediates protected from undesired side The scope applications has been further widened through covalent or noncovalent modifications. Combinations them metal catalysis especially successful. In terms these effects, various reactions achieved high yield so that valuable chemicals synthesized multiple components one-pot cyclodextrin units orderly assembled polymers show cooperation advanced properties. Recently, cyclodextrin-based metal–organic frameworks polyoxometalate–cyclodextrin have fabricated employed unique applications. Cyclodextrins fulfill many requirements chemistry should make enormous contributions this growing field.

Language: Английский

Citations

1