Recent progress in metal-organic frameworks: part I—material preparation DOI
Jiandong Pang, Zhengqing Zhang,

Shitong Zhang

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 31, 2024

Language: Английский

From Guest‐Induced Crystallization to Molecular Imprinting: Calculation‐Guided Discovery of Hydrogen‐Bonded Tetrazole Frameworks for p‐Xylene Separation DOI Open Access
Yi Su, Qiang Gao, Xiaojun Ding

et al.

Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Exploring host-guest interactions to regulate hydrogen-bonding assembly offers a promising approach for developing advanced porous crystal materials (PCMs). However, screening compatible guests with appropriate geometries and that could inhibit the dense packing of building blocks remains primary challenge. This study presents novel guest-induced crystallization (GIC) strategy, guided by thermodynamic calculations, develop hydrogen-bonded organic frameworks (HOFs) using structurally challenging tetrazole units. Thermodynamic principles are established from structure data density functional theory calculation formation energy (ΔE). provides criteria identify available in GIC, enabling successful discovery hidden HOF is kinetically crystallize. Furthermore, potential application p-xylene (PX) separation predicted analyzing ΔE HOFs. A high PX selectivity (PX/m-xylene=6.1, PX/o-xylene=7.2, PX/ethylbenzene=4.1) achieved through selective inclusion C8 aromatic isomers within Significantly, guest-free (HOF-PX-a), bearing PX-templated cavities derived molecular imprinting, shows record-high PX/ethylbenzene (21.7) liquid adsorption. work elucidates underpinning self-assembly rules GIC construction, providing exciting new opportunities predictable PCMs recognition target-specific separations.

Language: Английский

Citations

0
Multivariate synergy for heightening ionic HOF robustness and proton conductivity DOI

Xiang‐Tian Bai,

Li‐Hui Cao,

Xu‐Yong Chen

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Language: Английский

Citations

0
Low Thermal Quenching of an AIE-based Hydrogen-bonded Organic Framework for Phosphor-converted Light-emitting Diodes DOI

Zhihui Sun,

Peipei Yin,

Shiyang He

et al.

Chemical Research in Chinese Universities, Journal Year: 2025, Volume and Issue: unknown

Published: May 9, 2025

Language: Английский

Citations

0
Unravelling the photobehavior of a 2,1,3-benzothiadiazole-based HOF and its molecular units: experimental and theoretical insights into their spectroscopic properties in solution and in the solid state DOI Creative Commons
Mario de la Hoz Tomás, Juan Ángel Organero, Maria Rosaria di Nunzio

et al.

Journal of Materials Chemistry C, Journal Year: 2024, Volume and Issue: 12(25), P. 9112 - 9129

Published: Jan. 1, 2024

Revealing the photobehaviour of a new BTD-based HOF shows occurrence intramolecular charge-transfer and intermolecular proton-transfer photoevents leading to different emission spectra lifetimes when compared molecular units.

Language: Английский

Citations

2
A Hydrogen-Bonded Organic Framework Based on Triphenylamine for Photocatalytic Silane Hydroxylation DOI

G. S. Li,

Kaikai Niu,

Xuan‐Zong Yang

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(35), P. 16533 - 16540

Published: Aug. 21, 2024

Employing hydrogen-bonded organic frameworks (HOFs) as mild photocatalysts for conversions is still considerably challenging. In this work, we synthesized a framework (HOF-16) and achieved the photocatalytic oxidation of silanes to generate silanols. Considering constraints imposed by structure, significant improvement in efficacy singlet oxygen (1O2) generation observed. HOF-16 exhibits remarkable performance when it comes silane hydroxylation, displaying high efficiency, low catalyst loading, good recyclability. This research highlights immense potential HOFs realm photocatalysis.

Language: Английский

Citations

2
Exploring the versatility of hydrogen-bonded organic frameworks: Advances in design, stability, and multifunctional applications DOI

Hina Liaquat,

Muhammad Imran,

Zohaib Saddique

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140221 - 140221

Published: Sept. 1, 2024

Language: Английский

Citations

2
Computational Modeling of Reticular Materials: The Past, the Present, and the Future DOI Creative Commons
Wim Temmerman,

Ruben Goeminne,

Kuber Singh Rawat

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

Abstract Reticular materials rely on a unique building concept where inorganic and organic units are stitched together giving access to an almost limitless number of structured ordered porous materials. Given the versatility chemical elements, underlying nets, topologies, reticular provide platform design for timely technological applications. have now found their way in important societal applications, like carbon capture address climate change, water harvesting extract atmospheric moisture arid environments, clean energy Combining predictions from computational chemistry with advanced experimental characterization synthesis procedures unlocks strategy synthesize new desired properties functions. Within this review, current status modeling is addressed supplemented topical examples highlighting necessity molecular This review as templated study starting structure realistic material towards prediction functions At end, authors perspective past, present future formulate open challenges inspire model method developments.

Language: Английский

Citations

2
Structure features of a supramolecular organic framework self-assembled from a chiral natural compound DOI
Kenika Khotchasanthong, Yupa Pootaeng‐on, Kanok‐on Rayanil

et al.

CrystEngComm, Journal Year: 2024, Volume and Issue: 27(3), P. 297 - 301

Published: Nov. 20, 2024

A fascinating supramolecular-organic framework (SOF) self-assembles from a chiral naturally occurring lanostane compound extracted the Thai plant Miliusa sessilis .

Language: Английский

Citations

1
Recent progress in metal-organic frameworks: part I—material preparation DOI
Jiandong Pang, Zhengqing Zhang,

Shitong Zhang

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 31, 2024

Language: Английский

Citations

1