Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157974 - 157974
Published: Nov. 1, 2024
Language: Английский
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(26)
Published: Feb. 27, 2024
Abstract Quasi‐solid aqueous zinc ion batteries (AZIBs) based on flexible hydrogel electrolytes are promising substitutions of lithium‐ion owing to their intrinsic safety, low cost, eco‐friendliness and wearability. However, it remains a challenge lower the freezing point without sacrificing fundamental advantages such as conductivity mechanical properties. Herein, an all‐around electrolyte is constructed through convenient energy dissipation strategy via rapid reversible intramolecular/intermolecular ligand exchanges between Zn 2+ alterdentate ligands. The as‐obtained exhibits excellent properties, fatigue resistance, high Zn‐ion (38.2 mS cm −1 ), good adhesion (19.1 kPa), ultra‐low (−97 °C). Due ligands help improve solvation structure guide uniform deposition, Zn||Zn symmetric cells show stable plating/stripping behavior long‐term cycle stability. Zn||V 2 O 5 full exhibit large capacity 230.6 mAh g retention 75.2% after 1000 cycles. Furthermore, AZIBs operate stably even under extreme conditions including temperature (−40 °C) bending angle (180°). mechanically damage‐resistant can also be utilized in strain sensors. This work offers facile for developing deformation‐resistant, dendrite‐free, environmentally adaptable AZIBs.
Language: Английский
Citations
58
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(37)
Published: March 7, 2024
Abstract Concurrently achieving mechanical robustness, low hysteresis, and high transparency are essential for ionogels to enhance their reliability satisfy the requirements in soft electronics. Fabricating comprising these characteristics presents a considerable challenge. Herein, inspired by structure of neural networks, new strategy situ formation dense urea moieties aggregated domains is proposed achieve topology‐tailoring polyurea ionogels. Initially, leveraging pronounced disparity reactivity isocyanate (─NCO) groups between isophorone diisocyanate (IPDI) NCO‐terminated prepolymer (PPGTD), IPDI preferentially reacts with deblocked trifunctional latent curing agents, resulting domains. Thereafter, interconnected via PPGTD establish polymer networks which ionic liquid uniformly dispersed, forming like Attributed this unique design strategy, ionogel demonstrates remarkable properties, including strength (0.6–2.4 MPa), excellent toughness (0.9–4.3 MJ m −3 ), hysteresis (6.6–11.6%), (>92%), along enhanced fatigue puncture resistance. Furthermore, exhibit outstanding versatility, enabling strain sensors, flexible electroluminescence devices, nanogenerators. This contributes unparalleled combinatory catering diverse demands iontronics.
Language: Английский
Citations
28
TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 174, P. 117662 - 117662
Published: March 23, 2024
Language: Английский
Citations
28
Applied Materials Today, Journal Year: 2024, Volume and Issue: 38, P. 102256 - 102256
Published: May 23, 2024
Language: Английский
Citations
26
Advanced Healthcare Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 17, 2024
Abstract The rapid advancements in artificial intelligence, micro‐nano manufacturing, and flexible electronics technology have unleashed unprecedented innovation opportunities for applying sensors healthcare, wearable devices, human–computer interaction. human body's tactile perception involves physical parameters such as pressure, temperature, humidity, all of which play an essential role maintaining health. Inspired by the sensory function skin, many bionic been developed to simulate skin's various stimuli are widely applied health monitoring. Given urgent requirements sensing performance integration field devices monitoring, here is a timely overview recent advances multi‐functional It covers fundamental components categorizes them based on different response mechanisms, including resistive, capacitive, voltage, other types. Specifically, application these area monitoring highlighted. Based this, extended dual/triple‐mode integrating temperature presented. Finally, challenges discussed.
Language: Английский
Citations
18
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(44)
Published: Sept. 12, 2024
Abstract Practical applications of existing self‐healing ionogels are often hindered by the trade‐off between their mechanical robustness, ionic conductivity, and temperature requirements for ability. Herein, this challenge is addressed drawing inspiration from sea cucumber. A polyurethane containing multiple hydrogen‐bond donors acceptors synthesized used to fabricate room‐temperature with excellent properties, high puncture resistance, impact resistance. The hard segments polyurethane, driven hydrogen bonds, coalesce into phase regions, which can efficiently dissipate energy through reversible disruption reformation bonds. Consequently, resulting exhibit record‐high tensile strength toughness compared other ionogels. Furthermore, inherent reversibility bonds within regions allows spontaneously self‐heal damaged properties conductivity times at room temperature. To underscore application potential, these employed as electrolytes in fabrication electrochromic devices, stable performance, repeatable healing ability, satisfactory This study presents a novel strategy exceptional capability.
Language: Английский
Citations
17
Advanced Science, Journal Year: 2023, Volume and Issue: 11(3)
Published: Nov. 23, 2023
Abstract As stretchable conductive materials, ionogels have gained increasing attention. However, it still remains crucial to integrate multiple functions including mechanically robust, room temperature self‐healing capacity, facile processing, and recyclability into an ionogel‐based device with high potential for applications such as soft robots, electronic skins, wearable electronics. Herein, inspired by the structure of spider silk, a multilevel hydrogen bonding strategy effectively produce multi‐functional is proposed combination desirable properties. The are synthesized based on N ‐isopropylacrylamide (NIPAM), N, ‐dimethylacrylamide (DMA), ionic liquids (ILs) 1‐ethyl‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMI][TFSI]). synergistic interactions between PNIPAM chains, PDMA ILs endow improved mechanical strength along fast ability at ambient conditions. Furthermore, show great capability continuous fabrication fibers using melt‐spinning process. ionogel exhibit spider‐silk‐like features hysteresis behavior, indicating their excellent energy dissipation performance. Moreover, interwoven network strain thermal sensing performance can accurately sense location objects. In addition, processability different shapes 3D printing. This work provides new design superior diverse applications.
Language: Английский
Citations
41
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154083 - 154083
Published: July 17, 2024
Language: Английский
Citations
16
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 490, P. 151850 - 151850
Published: May 1, 2024
Language: Английский
Citations
12
Composites Communications, Journal Year: 2024, Volume and Issue: 50, P. 102017 - 102017
Published: July 24, 2024
Language: Английский
Citations
11