Zif-L(Co) Derived Cobalt Doped In2o3 Hollow Nanofibers with High Surface Activity for Efficient Formaldehyde Gas Sensing DOI
Lei Zhu, Jianan Wang, Jianwei Liu

et al.

Published: Jan. 1, 2023

Gas sensors based on semiconductor metal oxides are identified as a highly promising candidate for toxic gas detection, yet they still suffer from high operating temperature due to low surface activity at temperature. To address this issue, we present an elaborate design the homogeneous functionalization of ZIF-L(Co) derived cobalt (Co) catalysts into hollow In2O3 frameworks, aiming activate redox capacity and catalytic efficacy sensor HCHO gas. Benefiting Co doping boosts generates abundant oxygen vacancies, optimized 1 wt% Co-doped HNFs exhibits response 40.4 toward 100 ppm moderately 180 ℃, which is 4 times higher than that pristine HNFs. Moreover, has virtues selectivity excellent long-term stability sensing. This study highlights important influence catalyst modulation active sites oxides-based sensors, inspiring development cost-effective indoor hazardous monitoring.

Language: Английский

Atomic-level coordination structures meet graphitic carbon nitride (g-C3N4) for photocatalysis: Energy conversion and environmental remediation DOI

Haiwei Su,

Haibo Yin, Rong Wang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 123683 - 123683

Published: Jan. 1, 2024

Language: Английский

Citations

42
Tandem microplastic degradation and hydrogen production by hierarchical carbon nitride-supported single-atom iron catalysts DOI Creative Commons
Jingkai Lin,

Kunsheng Hu,

Yantao Wang

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Oct. 10, 2024

Abstract Microplastic pollution, an emerging environmental issue, poses significant threats to aquatic ecosystems and human health. In tackling microplastic pollution advancing green hydrogen production, this study reveals a tandem catalytic degradation-hydrogen evolution reaction (MPD-HER) process using hierarchical porous carbon nitride-supported single-atom iron catalysts (FeSA-hCN). Through hydrothermal-assisted Fenton-like reactions, we accomplish near-total ultrahigh-molecular-weight-polyethylene degradation into C 3 -C 20 organics with 64% selectivity of carboxylic acid under neutral pH, leap beyond current capabilities in efficiency, selectivity, eco-friendliness, stability over six cycles. The system demonstrates versatility by degrading various daily-use plastics across different settings. mixture FeSA-hCN plastic products further achieves 42 μmol h ‒1 illumination, outperforming most existing photoreforming methods. This MPD-HER not only provides scalable economically feasible strategy combat but also contributes the economy, far-reaching implications for global sustainability initiatives.

Language: Английский

Citations

16
Multidimensional engineering of single-atom cobalt catalysts for ultrafast Fenton-like reactions DOI

Zhong‐Shuai Zhu,

Yantao Wang, Pengtang Wang

et al.

Nature Water, Journal Year: 2025, Volume and Issue: 3(2), P. 211 - 221

Published: Jan. 22, 2025

Language: Английский

Citations

6
Carbonaceous materials in structural dimensions for advanced oxidation processes DOI
Yunpeng Wang, Ya Liu, Huayang Zhang

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Catalytic active sites and mechanisms of various dimensional carbonaceous materials in activation oxidants towards advanced oxidant processes for wastewater/water treatment were reviewed.

Language: Английский

Citations

2
Electronic Structure and Functions of Carbon Nitride in Frontier Green Catalysis DOI
Jingkai Lin,

Wenjie Tian,

Huayang Zhang

et al.

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(16), P. 2303 - 2315

Published: Aug. 6, 2024

ConspectusGraphitic carbon nitride-based materials have emerged as promising photocatalysts for a variety of energy and environmental applications owing to their "earth-abundant" nature, structural versatility, tunable electronic optical properties, chemical stability. Optimizing nitride's physicochemical properties encompasses approaches, including the regulation inherent defects, morphology control, heterostructure construction, heteroatom metal-atom doping. These strategies are pivotal in ultimately enhancing photocatalytic activities. Previous reviews with extensive examples mainly focused on synthesis, modification, application photocatalysis. However, there has been lack straightforward in-depth discussion understand characteristics functions various engineered nitrides well precise tailoring explain regularity specificity improved performance targeted systems. In past ten years, our group conducted investigations studies demonstrate close yet intricate relationship between structure nitride reactivity. Understanding nitride, different engineering strategies, is essential improvement processes from fundamental study practical applications.To this end, Account, we first delve into nature highlighting structures, band structure, density states, molecular orbitals, center, its functions, such charge distribution, internal electric field, external force. Subsequently, based recent research group, present detailed strategic modifications consequential impacts particularly intrinsic characteristics, performance. categorized follows: (i) component changing, which involves intralayer interface heterojunctions homojunctions, modulate band-edge potentials reactivity photoinduced electrons holes toward surface redox reactions; (ii) dimensional tuning, engineers influence electron transfer direction; (iii) defect introduces symmetry break framework, promote redistribution altering structure; (iv) anchoring single-atom metals facilitate orbital hybridization enhancement through unique metal-N coordination configurations. Finally, propose an appraisal prospects challenges manipulation characterization nitride. The integration

Language: Английский

Citations

12
Microenvironment Engineering of Heterogeneous Catalysts for Liquid-Phase Environmental Catalysis DOI

Zhong‐Shuai Zhu,

Shuang Zhong, Cheng Cheng

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(20), P. 11348 - 11434

Published: Oct. 9, 2024

Environmental catalysis has emerged as a scientific frontier in mitigating water pollution and advancing circular chemistry reaction microenvironment significantly influences the catalytic performance efficiency. This review delves into engineering within liquid-phase environmental catalysis, categorizing microenvironments four scales: atom/molecule-level modulation, nano/microscale-confined structures, interface surface regulation, external field effects. Each category is analyzed for its unique characteristics merits, emphasizing potential to enhance efficiency selectivity. Following this overview, we introduced recent advancements advanced material system design promote (e.g., purification, transformation value-added products, green synthesis), leveraging state-of-the-art technologies. These discussions showcase was applied different reactions fine-tune regimes improve from both thermodynamics kinetics perspectives. Lastly, discussed challenges future directions engineering. underscores of intelligent materials drive development more effective sustainable solutions decontamination.

Language: Английский

Citations

11
In situ single iron atom doping on Bi2WO6 monolayers triggers efficient photo-fenton reaction DOI Creative Commons
Wei Liu, Peifang Wang, Juan Chen

et al.

Environmental Science and Ecotechnology, Journal Year: 2024, Volume and Issue: 20, P. 100414 - 100414

Published: March 21, 2024

Developing an efficient photocatalytic system for hydrogen peroxide (H

Language: Английский

Citations

10
Atomically dispersed Co-Mn dual sites anchored in photoresponsive carbon nitride mediated peroxymonosulfate activation for elimination of petroleum hydrocarbon in water DOI
Qi Guo, Xue-fang Yu, Kaisheng Zhang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 343, P. 123581 - 123581

Published: Nov. 28, 2023

Language: Английский

Citations

22
Macroporous Carbon-Nitride-Supported Transition-Metal Single-Atom Catalysts for Photocatalytic Hydrogen Production from Ammonia Splitting DOI
Jingkai Lin, Yantao Wang, Wenjie Tian

et al.

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(17), P. 11711 - 11722

Published: Aug. 21, 2023

Ammonia (NH3) splitting to hydrogen (H2) is a promising route for on-site production of green energy; however, the application limited due high-cost noble-metal-based catalysts and high operating temperature endothermic nature. Herein, we develop series macroporous carbon nitride-supported single-atom transition metal (TMs-MCN, TMs: Co, Mn, Fe, Ni, Cu) catalyst panels solar light-driven photocatalytic gaseous NH3 splitting. Under ambient reaction conditions, optimized Ni-MCN shows an H2 rate 35.6 μmol g–1 h–1, much superior that MCN other TMs-MCN. Such enhanced photoactivity attributed presence Ni–N4 sites, which improve optical properties, accelerate charge carrier separation/transfer, boost kinetics catalysts. Density functional theory calculations further reveal sites can effectively modify electronic structure nitride. Compared with site possesses moderate binding strength lowest energy barrier facilitate formation key intermediates *NH + *H. These findings provide valuable guidelines rational design toward energy- cost-effective production.

Language: Английский

Citations

20
ZIF-L(Co) derived cobalt doped In2O3 hollow nanofibers with high surface activity for efficient formaldehyde gas sensing DOI
Lei Zhu, Jianan Wang, Jianwei Liu

et al.

Sensors and Actuators B Chemical, Journal Year: 2023, Volume and Issue: 403, P. 135129 - 135129

Published: Dec. 12, 2023

Language: Английский

Citations

20