Cited by Unraveling the Synergistic Role of Sm<sup><b>3+</b></sup> Doped NiFe‐LDH as High‐Performance Electrocatalysts for Improved Anion Exchange Membrane and Water Splitting Applications

Enhanced hydrogen storage performance of g-C3N4/CoMn2O4 nanocomposites DOI

Gokuladeepan Periyasamy,

Ajaijawahar Kaliyaperumal,

Rameshbabu Ramachandran

et al.

Journal of Materials Science Materials in Electronics, Journal Year: 2024, Volume and Issue: 35(6)

Published: Feb. 1, 2024

Language: Английский

Citations

γ-FeOOH Nanosheet with Enormous Cationic Defect: Efficient and Durable Bifunctional Electrocatalyst Suitable for an Industrial-Scale AEM Electrolyzer DOI

Dimple K. Bora,

Debasish Ghosh,

Animesh Jana

et al.

ACS Applied Engineering Materials, Journal Year: 2024, Volume and Issue: 2(4), P. 975 - 987

Published: April 16, 2024

Anion exchange membrane (AEM)-based electrolysis of alkaline water using a transition metal electrocatalyst is supposed to be the effective route for next-generation pure green hydrogen production, but development suitable challenging. Herein, we report simple and scalable protocol grow highly aligned ultrathin iron(III) oxyhydroxide (lepidocrocite, γ-FeOOH) nanosheet on nickel foam (γ-FeOOH-NS-NF) at room temperature (RT) through controlled simultaneous oxidation hydrolysis in presence hydrazine. During synthesis, hydrazine plays crucial multiple roles, one which generation enormous Fe vacancies (VFe). The synthesized γ-FeOOH-NS-NF showed superior bifunctional splitting activity because its thin sheet microstructure cationic defect. Particularly high current density, it an exceptionally low overpotential 320 η1000 Tafel slope 29 OER, 309 mV 65 dec–1 HER aqueous 1 M KOH solution. For overall splitting, 10 mA cm–2 density was observed potential 1.6 V. It 98% Faradaic efficiency excellent stability continuous operation over 100 h 500 density. More importantly, electrode assembly (MEA) having both anode cathode prototype anion (AEM) electrolyzer (4 cm2) outstanding performance stability. experimental results evidenced that grown NF generated VFe are primarily responsible efficient splitting. Thus, robust synthetic technique, direct usability AEM electrolyzer, correspondingly make as industrial-scale production.

Language: Английский

Citations

Evaluating the water splitting promotion effects of birnessite Mn3+/4+ platelets of α-Mn3O4 coated with Ag@Ag2WO4 nanosphericals DOI

Mohamed Mokhtar Mohamed,

S. M. Syam,

M. Khaіry

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 61, P. 1028 - 1042

Published: March 7, 2024

Language: Английский

Citations

Modulating electronic structure of self-supported nickel-vanadium layered double hydroxide to accelerate hydrogen evolution reaction DOI

Lingjiang Kou, Yong Wang, Jiajia Song

et al.

Scripta Materialia, Journal Year: 2024, Volume and Issue: 252, P. 116242 - 116242

Published: June 22, 2024

Language: Английский

Citations

Ultra-fast synthesis of transition metal-MXene nanocomposite electrocatalyst for energy-saving seawater hydrogen production: Experiment and theory DOI

Ruhollah Sharifi, Abolghasem Dolati, Abdolvahab Seif

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 93, P. 1377 - 1392

Published: Nov. 11, 2024

Language: Английский

Citations

Empowering the Water Oxidation Activity of the Bimetallic Metal–Organic Framework by Annexing Gold Nanoparticles over the Catalytic Surface DOI

Anup Kuchipudi, Ankit Das, Krishnendu Bera

et al.

Inorganic Chemistry, Journal Year: 2023, Volume and Issue: 62(51), P. 21265 - 21276

Published: Dec. 11, 2023

Electrocatalytic water splitting to an anodic oxygen evolution reaction (OER) and a cathodic hydrogen (HER) is believed be the most important application for sustainable generation. Being four-electron, four-proton transfer process, OER plays main obstacle same. Therefore, designing effective electrocatalyst minimize activation energy barrier research topic of prime importance. The metal–organic framework (MOF) with highly porous network considered appropriate candidate in alkaline conditions. Apart from several MOFs, bimetallic one has advantageous electrocatalytic performance due synergistic electronic interaction between two metal ions. However, MOFs have their low conductive nature, therefore, they possess charge kinetics at interface. Surface functionalization via various nanoparticles (NPs) strategy nullifying issue. In this work, we designed CoNi-based MOF that was surface-functionalized by Au NPs (Au@CoNi-Bpy-BTC) under Au@CoNi-Bpy-BTC required overpotential just 330 mV, which 56 mV lower as compared pristine MOF. Impedance analysis confirms improved conductivity interface, where possesses Rct value than CoNi-Bpy-BTC materials. Moreover, Au-decorated shows 8.5 times increase TOF noble toward surface developing electrocatalysts energy-related fields. Overall, report displays exceptional correlation decorated over surface, can regulate activity, confirmed experimental analysis.

Language: Английский

Citations

A novel polymetallic molybdate and it derived metal sulfide electrocatalyst for water splitting DOI

Siru Chen, Junyan Chen,

Junlong Xu

et al.

Fuel, Journal Year: 2024, Volume and Issue: 380, P. 133272 - 133272

Published: Sept. 24, 2024

Language: Английский

Citations

Unraveling the Synergistic Role of Sm³⁺ Doped NiFe‐LDH as High‐Performance Electrocatalysts for Improved Anion Exchange Membrane and Water Splitting Applications DOI

Sreenivasan Nagappan,

Hemalatha Gurusamy,

Harpriya Minhas

et al.

Small Methods, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 17, 2024

Effective first-row transition metal-based electrocatalysts are crucial for large-scale hydrogen energy generation and anion exchange membrane (AEM) devices in water splitting. The present work describes that SmNi

Language: Английский

Citations