Despite
great
success
in
design
and
preparation
of
phase
change
microcapsules,
the
balance
anti-leakage,
high
thermal
conductivity,
multi-source
energy
exploitation
are
still
difficult
to
be
achieved
simultaneously,
which
remains
long-standing
bottleneck
for
efficient
safe
harvesting.
In
this
work,
a
multifunctional
double-shell
PANI
microcapsule
(MC)
encapsulating
material
(PCM)
was
designed
fabricated
via
an
emulsion
photopolymerization
strategy.
Thanks
outstanding
anti-permeability,
photo-thermal
property
PANI,
as-prepared
achieves
three
synergetic
effects
simultaneously:
low
leakage
rate,
solar
exploitation.
The
encapsulated
PCM
has
almost
unchanged
Tm
Tc,
negligible
(≤0.2
wt%)
normalized
melting
solidified
enthalpies
after
100
heating/cooling
cycles.
presence
polyaniline
shell
improves
conductivity
efficiency
providing
promising
strategy
extend
single
source
energy.
addition
heat
storage,
microcapsules
also
possess
anticorrosion
property,
is
particularly
attractive
coating
applications.
Accordingly,
resulted
could
act
as
candidate
with
all-in-one
features
temperature
regulated
properties,
durability
anti-corrosion
would
stimulate
wide
application
energy-saving
anticorrosive
smart
coatings.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(37), P. 24966 - 24976
Published: Jan. 1, 2024
A
PCMs-enhanced
thermostat
capable
of
dynamically
adjusting
its
thermal
regulation
performance
along
with
the
ambient
temperature
is
developed,
showing
great
potential
for
all-day
temperature-adaptive
management
in
energy-saving
buildings.
Journal of Materials Research and Technology,
Journal Year:
2024,
Volume and Issue:
32, P. 4019 - 4027
Published: Sept. 1, 2024
The
development
of
advanced
composite
solid-solid
phase
change
materials
(SSPCMs)
is
urgent
to
explore
for
improving
solar
energy
harvesting
and
storage.
Herein,
novel
SSPCMs
with
synergetic
cross-linking
structure
were
fabricated
through
polymerization
using
GO
TiO2
constructed
on
the
polyurethane
framework
skeleton.
enhanced
polymer
played
a
role
as
skeletal
encapsulate
PEG
in
molecular
chains,
provided
highly
thermal
conductive
pathways
SSPCMs.
nanoparticles
performed
extended
surface
further
improvement
conductivity.
exhibited
remarkably
improved
conductivity
high
0.7
W/(m‧K)
fast
response
rate.
good
light
adsorption
property
absorbance
efficiency
by
94.4%.
And
photo-thermal
conversion
reached
93.5%.
Meanwhile,
excellent
anti-leakage
performance
shape
stability
under
temperature.
Consequently,
as-prepared
possessed
potential
applications
storage
utilization
systems.
Phase
change
materials
(PCMs)
are
used
in
the
field
of
thermal
management
because
their
ability
to
absorb
and
release
energy
through
latent
heat.
However,
rigidity
leakage
issues
PCMs
limit
application
electronic
devices.
In
this
paper,
we
prepared
flexible
phase
composites
with
excellent
capabilities
by
mixing
microparticles
addition-cure
liquid
silicone
rubber
(ALSR).
The
have
superior
mechanical
properties,
cycling
capacity,
temperature
response
rate,
enthalpy
can
reach
156.1
J/g
a
conductivity
0.84
W·m–1·K–1.
avoid
rapid
warming
solid–liquid
transition
PCMs,
which
be
applied
heat
dissipation
laptop.
To
sum
up,
properties
broad
prospects
area
Despite
great
success
in
design
and
preparation
of
phase
change
microcapsules,
the
balance
anti-leakage,
high
thermal
conductivity,
multi-source
energy
exploitation
are
still
difficult
to
be
achieved
simultaneously,
which
remains
long-standing
bottleneck
for
efficient
safe
harvesting.
In
this
work,
a
multifunctional
double-shell
PANI
microcapsule
(MC)
encapsulating
material
(PCM)
was
designed
fabricated
via
an
emulsion
photopolymerization
strategy.
Thanks
outstanding
anti-permeability,
photo-thermal
property
PANI,
as-prepared
achieves
three
synergetic
effects
simultaneously:
low
leakage
rate,
solar
exploitation.
The
encapsulated
PCM
has
almost
unchanged
Tm
Tc,
negligible
(≤0.2
wt%)
normalized
melting
solidified
enthalpies
after
100
heating/cooling
cycles.
presence
polyaniline
shell
improves
conductivity
efficiency
providing
promising
strategy
extend
single
source
energy.
addition
heat
storage,
microcapsules
also
possess
anticorrosion
property,
is
particularly
attractive
coating
applications.
Accordingly,
resulted
could
act
as
candidate
with
all-in-one
features
temperature
regulated
properties,
durability
anti-corrosion
would
stimulate
wide
application
energy-saving
anticorrosive
smart
coatings.