trans‐Selective Element−Element′ Addition to Alkynes DOI
Shuang Zhao,

Yingman Sun,

Shiqing Li

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(21)

Published: July 18, 2024

Abstract The trans ‐addition of intermetallic σ‐bonds (E−E′; E E’=Si, B, Se, P, Sn, etc.) across alkynes has emerged as an exceptionally atom‐economical means constructing multi‐substituted alkenes, which readily transform into densely functionalized and biologically active compounds. Compared to the widely studied cis ‐E−E’ additions, additions remain a more challenging underdeveloped area. In this article, recent advances in are summarized, encompassing various interelement compounds such Si−Si, B−B, Si−B, P−B, Se−B, B−Sn. We aim provide deeper understanding facilitate further development synthetic methodologies applications vicinally ‐bismetallated alkenes.

Language: Английский

trans‐Selective Element−Element′ Addition to Alkynes DOI
Shuang Zhao,

Yingman Sun,

Shiqing Li

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(21)

Published: July 18, 2024

Abstract The trans ‐addition of intermetallic σ‐bonds (E−E′; E E’=Si, B, Se, P, Sn, etc.) across alkynes has emerged as an exceptionally atom‐economical means constructing multi‐substituted alkenes, which readily transform into densely functionalized and biologically active compounds. Compared to the widely studied cis ‐E−E’ additions, additions remain a more challenging underdeveloped area. In this article, recent advances in are summarized, encompassing various interelement compounds such Si−Si, B−B, Si−B, P−B, Se−B, B−Sn. We aim provide deeper understanding facilitate further development synthetic methodologies applications vicinally ‐bismetallated alkenes.

Language: Английский

Citations

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