Manganese(I)-Catalyzed Direct Addition of C(sp3)–H Bonds to Aryl Isocyanates DOI
Hongxin Liu, Zhichao Yu, Bin Li

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(18), P. 13429 - 13437

Published: Sept. 3, 2024

The addition of C-H bonds to isocyanates catalyzed by transition metals is a highly auspicious methodology for providing synthetically and biologically important amides. However, the substrates are limited C(sp

Language: Английский

Selective Functionalization of Alkenes and Alkynes by Dinuclear Manganese Catalysts DOI
Fei Wang,

Guichao Dong,

Suqi Yang

et al.

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 2, 2024

ConspectusAlkenes and alkynes are fundamental building blocks in organic synthesis due to their commercial availability, bench-stability, easy preparation. Selective functionalization of alkenes is a crucial step for the value-added compounds. Precise control over these reactions allows efficient construction complex molecules with new functionalities. In recent decades, second- third-row precious transition metal catalysts (palladium, platinum, rhodium, ruthenium) have been pivotal development metal-catalyzed synthetic methodology. These metals exhibit excellent catalytic activity selectivity, enabling functionalized molecules. However, recovery reuse long challenge this field. years, exploration earth-abundant has interested both academic industrial researchers. The such systems offers promising approach overcome limitations catalysts. For example, manganese third most naturally abundant minimal toxicity biocompatibility. It exhibits good several reactions, including C-H bond functionalization, selective reduction, radical reactions. This Account outlines our progress dinuclear catalysis alkynes. We established elementary manganese(I)-catalysis transmetalation R-B(OH)

Language: Английский

Citations

2
Manganese(I)-Catalyzed C(sp3)–H Bond Functionalization of 8-Methylquinolines DOI
Mark Lautens, Alexa Torelli

Synfacts, Journal Year: 2024, Volume and Issue: 20(07), P. 0716 - 0716

Published: June 14, 2024

Key words manganese catalysis - C–H functionalization Grignard reactions

Language: Английский

Citations

0
Manganese(I)-Catalyzed Direct Addition of C(sp3)–H Bonds to Aryl Isocyanates DOI
Hongxin Liu, Zhichao Yu, Bin Li

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(18), P. 13429 - 13437

Published: Sept. 3, 2024

The addition of C-H bonds to isocyanates catalyzed by transition metals is a highly auspicious methodology for providing synthetically and biologically important amides. However, the substrates are limited C(sp

Language: Английский

Citations

0