Gold supported on Bi2MoO6 based on oxygen vacancy structure: Enhanced adsorption activation for efficient photocatalytic selective oxidation of benzyl alcohol DOI

Tinglan Wang,

Xueyi Duan,

Kaiyi Sun

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1006, P. 176334 - 176334

Published: Sept. 3, 2024

Language: Английский

Constructing a Polyoxometalate-Based Metal–Organic Framework for Photocatalytic Oxidation of Thioethers to Sulfoxides Utilizing In Situ-Generated Superoxide Radicals DOI
Xueling Liu, Si Chen,

Junjie Xu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Developing new photocatalysts for the selective oxidation of thioethers to high-value-added sulfoxides under low-oxygen mild conditions is a promising but challenging strategy. Here, polyoxometalate-based metal–organic framework (POMOF), CoBW12–TPT, was successfully synthesized, wherein continuous π···π stacking interactions and direct coordination bonds not only strengthen framework's stability also accelerate electron transfer. A series experiments theoretical studies, including control experiments, kinetic electrochemical spectroscopic analyses, paramagnetic resonance, revealed synergistic catalytic effect among Co(II) metal centers, BW12O405–, photosensitizer TPT. CoBW12–TPT applied in photocatalytic sulfoxides. Under irradiation, photoinduced transfer POMOF leads generation superoxide radicals from O2, which controls sulfoxide compounds desulfurization reaction shows good activity. In particular, it can be construction some drug molecules such as Modafinil Albendazole Oxide.

Language: Английский

Citations

3
Dy/Ho-encapsulated tartaric acid-functionalized tungstoantimonates: heterogeneous catalysts for isoindolinones synthesis DOI
Guo‐Ping Yang, Haoqi Liu,

Jincao Chen

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(78), P. 10934 - 10937

Published: Jan. 1, 2024

Two novel rare earth-substituted tungstoantimonates [H

Language: Английский

Citations

1
Pd-incorporated polyoxometalate catalysts for electrochemical CO2 reduction DOI Creative Commons

Kimitake Kawakami,

Tomohiro Yabe, Fumiaki Amano

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(36), P. 14829 - 14836

Published: Jan. 1, 2024

We investigated the electrochemical CO 2 RR performance of a Pd-incorporated polyoxometalate ([H SiW 10 O 36 Pd (OAc) ] 4− ) possessing various countercations on carbon electrode and found that Ba 2+ salt exhibited selective production over 12 h.

Language: Английский

Citations

0
Gold supported on Bi2MoO6 based on oxygen vacancy structure: Enhanced adsorption activation for efficient photocatalytic selective oxidation of benzyl alcohol DOI

Tinglan Wang,

Xueyi Duan,

Kaiyi Sun

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1006, P. 176334 - 176334

Published: Sept. 3, 2024

Language: Английский

Citations

0