Supramolecular Polymerization of Pseudo[2]rotaxanes Formation of per‐Imidazole Pillar[5]arene‐based Host–Guest Complexations and Halogen Bonding Interactions DOI
Zheng‐Xiang Li,

C.‐W. F. CHENG,

Kaixuan Wang

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(42)

Published: Nov. 1, 2024

Abstract In this study, we reported the construction of 3D supramolecular polymeric networks using per ‐imidazole pillar[5]arene ( DIMP5 ) as a host and 1,4‐diiodotetrafluorobenzene L halogen bond donor in chloroform. The polymerization process was characterized by 1 H NMR, 19 F NMR spectroscopy, X‐ray single crystal analysis. C─I⋯N distance (2.78 Å) angle (177°) clearly indicated formation bonds structure. Meanwhile, introducing adiponitrile G guest, pseudo[2]rotaxanes also prepared, which driven ‐based host–guest complexations bonding interactions.

Language: Английский

Recent advance development in pillar[5]arene-based nanomaterials for cancer therapy DOI
Yu Dai, Wenqiang Yu,

Yu‐Shan Cheng

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

In this review, we summarize five different types of pillar[5]arene-based nanomaterials and their applications in chemotherapy, photodynamic therapy, photothermal multimodal synergistic therapy for tumors.

Language: Английский

Citations

0
Pillar[n]arene‐Based Supramolecular Nanodrug Delivery Systems for Cancer Therapy DOI Open Access
Shubin Wei,

Xinyi Cui,

Tingting Li

et al.

ChemMedChem, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 20, 2025

Abstract Macrocyclic supramolecular materials play an important role in encapsulating anticancer drugs to improve the efficiency and reduce toxicity normal tissues through host‐guest interactions. Among them, pillar[n]arenes, as emerging class of macrocyclic compounds, have attracted increasing attention drug delivery drug‐controlled release due their high biocompatibility, excellent chemistry, simplicity modification. In this review, we summarize research progress pillar[n]arene‐based nanodrug systems (SNDs) recent years field tumor therapy, including release, imaging diagnostics therapeutic modalities. Furthermore, opportunities major limitations SNDs for therapy are discussed.

Language: Английский

Citations

0
A pillar[5]arene-based supramolecular fluorescent probe for selective GSH detection and GSH-activated mitochondrial targeting cell imaging DOI

Kai-Li Chang,

Jing Zhang, Haidong Bian

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142272 - 142272

Published: April 1, 2025

Language: Английский

Citations

0
Supramolecular Polymerization of Pseudo[2]rotaxanes Formation of per‐Imidazole Pillar[5]arene‐based Host–Guest Complexations and Halogen Bonding Interactions DOI
Zheng‐Xiang Li,

C.‐W. F. CHENG,

Kaixuan Wang

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(42)

Published: Nov. 1, 2024

Abstract In this study, we reported the construction of 3D supramolecular polymeric networks using per ‐imidazole pillar[5]arene ( DIMP5 ) as a host and 1,4‐diiodotetrafluorobenzene L halogen bond donor in chloroform. The polymerization process was characterized by 1 H NMR, 19 F NMR spectroscopy, X‐ray single crystal analysis. C─I⋯N distance (2.78 Å) angle (177°) clearly indicated formation bonds structure. Meanwhile, introducing adiponitrile G guest, pseudo[2]rotaxanes also prepared, which driven ‐based host–guest complexations bonding interactions.

Language: Английский

Citations

0