Metal Coordination-Induced Structural Regulation of Twisted Cucurbit[14]uril-Based Supramolecular Assemblies for Mercury Ions Detection on Smart Platform DOI
Wei Zhang,

Mao-Qin Liu,

Xuefeng Zhu

et al.

ACS Sensors, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 15, 2025

The high selectivity and reversibility of metal coordination enable precise modulation the structural morphology supramolecular assemblies, which is essential for development intelligent application functionalized materials. In this study, sheet-like assemblies (Pyr-O@tQ[14]) constructed by twisted cucurbit[14]urils (tQ[14]) pyrene derivatives (Pyr-O) through host-guest interactions, exhibit excellent optical properties, achieves highly sensitive detection Hg2+ fluorescence quenching, with a limit 0.177 μM. A novel smart platform, compatible smartphones, developed to enhance efficiency practicality practical applications. From microscopic perspective, adjusting concentration can change Pyr-O@tQ[14] from lamellar square finally spherical, demonstrating dynamic control assembly structure in response environmental stimuli. This study not only presents efficient quantitative sensing platform but also highlights unique advantages tQ[14] constructing tunable, responsive structures, opening new avenues design synthesis advanced

Language: Английский

Gold nanoparticles-wood nanohybrid as peroxidase-like for simple and selective detection of mercury ion DOI
Yuanfu Zhang, Xue Zhao, Lei Jin

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2025, Volume and Issue: 332, P. 125804 - 125804

Published: Feb. 1, 2025

Language: Английский

Citations

1

Metal Coordination-Induced Structural Regulation of Twisted Cucurbit[14]uril-Based Supramolecular Assemblies for Mercury Ions Detection on Smart Platform DOI
Wei Zhang,

Mao-Qin Liu,

Xuefeng Zhu

et al.

ACS Sensors, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 15, 2025

The high selectivity and reversibility of metal coordination enable precise modulation the structural morphology supramolecular assemblies, which is essential for development intelligent application functionalized materials. In this study, sheet-like assemblies (Pyr-O@tQ[14]) constructed by twisted cucurbit[14]urils (tQ[14]) pyrene derivatives (Pyr-O) through host-guest interactions, exhibit excellent optical properties, achieves highly sensitive detection Hg2+ fluorescence quenching, with a limit 0.177 μM. A novel smart platform, compatible smartphones, developed to enhance efficiency practicality practical applications. From microscopic perspective, adjusting concentration can change Pyr-O@tQ[14] from lamellar square finally spherical, demonstrating dynamic control assembly structure in response environmental stimuli. This study not only presents efficient quantitative sensing platform but also highlights unique advantages tQ[14] constructing tunable, responsive structures, opening new avenues design synthesis advanced

Language: Английский

Citations

0