Protons Selectively Regulate the Asymmetric Activation of the C─H Bonds of Methanol Molecules
Kun Jia,
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Peng Jia
No information about this author
ChemistrySelect,
Journal Year:
2025,
Volume and Issue:
10(7)
Published: Feb. 1, 2025
Abstract
The
activation
of
C─H
bonds
under
mild
conditions
is
a
crucial
step
in
the
conversion
organic
molecules.
However,
simultaneous
methanol
can
result
excessive
oxidation,
thereby
diminishing
selectivity
for
formaldehyde
production.
We
achieved
selective
by
adjusting
proton
concentration
an
anhydrous
solution,
which
significantly
enhanced
dehydrogenation
rate
methanol.
Additionally,
we
constructed
related
molecular
models
to
identify
sites
asymmetric
providing
new
insights
further
studies
on
bond
activation.
Language: Английский
Photocatalytic Upgrading of Plastic Waste into High-Value-Added Chemicals and Fuels: Advances and Perspectives
ACS Sustainable Chemistry & Engineering,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 13, 2025
Language: Английский
Electrochemical Commodity Polymer Up‐ and Re‐Cycling: Toward Sustainable and Circular Plastic Treatment
Macromolecular Rapid Communications,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 18, 2025
Abstract
The
demand
for
commodity
plastics
reaches
unprecedented
dimensions.
In
contrast
to
the
well‐developed
plethora
of
methods
polymer
synthesis,
sustainable
strategies
end‐of‐life
management
continue
be
scarce.
While
mechanical
re‐cycling
often
results
in
downgraded
materials,
chemical
or
up‐cycling
offers
tremendous
potential
an
efficient
and
green
approach,
thereby
addressing
precarious
treatment
post‐use
within
a
circular
carbon
economy.
Recently,
electrochemistry
surfaced
as
uniquely
powerful
tool
via
functionalization
degradation
obtaining
either
novel
polymers
with
valorized
properties
high‐value
recycled
small
molecules,
respectively.
discussing
recent
progress
that
domain,
future
perspectives
electrochemical
modifications
until
January
2025
are
outlined
herein.
Language: Английский