Molecules, Journal Year: 2025, Volume and Issue: 30(5), P. 1158 - 1158
Published: March 4, 2025
This article provides a comprehensive review of quantum chemical computational studies on the thermal and photochemical reactions organosilicon compounds, based fundamental concepts such as initial complex formation, HOMO-LUMO interactions, subjacent orbital interactions. Despite silicon's position in group 14 periodic table, alongside carbon, its reactivity patterns exhibit significant deviations from those carbon. delves into behaviors particularly focusing highly coordinated nature silicon. It is poised to serve valuable resource for chemists, offering insights cutting-edge research fostering further innovations synthetic chemistry also theoretical chemistry.
Language: Английский