Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 26, 2024
The
fabrication
of
self-driven
systems
with
flexibility
and
tunable
output
for
organic
photoinduction
is
highly
desirable
but
challenging.
In
this
study,
a
3D
cadmium
metal-organic
framework
(Cd-MOF)
synthesized
used
as
filler
ethyl
cellulose
(EC)
to
create
mechanically
durable
flexible
Cd-MOF@EC
composite
films.
Due
its
well-established
platform
periodically
precise
structure
nature,
the
outputs
Cd-MOF-based
TENG
are
much
higher
than
those
ligand-based
TENGs.
Furthermore,
films
different
doping
ratios
Cd-MOF
employed
assemble
Cd-MOF@EC-based
triboelectric
nanogenerators
(TENGs).
results
reveal
that
ratio
10
wt.%
in
provides
highest
output.
Subsequently,
(FCEC-TENG),
working
contact-separation
model,
constructed
harvest
mechanical
energy
from
human
body,
demonstrating
excellent
performance
stability.
harvested
FCEC-TENG
can
directly
illuminate
14
commercial
white
light-emitting
diodes
(LEDs),
providing
visible
light
bromination
reaction,
generating
bromide
good
yield
tolerance.
This
study
presents
an
effective
method
constructing
MOF-based
self-powered
photoinduced
transformation
systems.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 10, 2025
Abstract
Defect‐engineering‐involved
metal‐organic
frameworks
(MOFs)
have
been
highly
valued
in
many
fields
due
to
the
enhanced
porosity
and
abundant
active
sites,
but
how
systematic
modulation
on
deficiency
influencing
fluorescent
sensing
performance
is
still
its
infancy.
Here,
defect‐engineering
of
MOF‐525
used
modulate
exposure
zirconium
(Zr)
clusters
sieving
capability
inner
channels,
enabling
precise
phosphoryl
fluoride
nerve
agents
with
specific
chemical
activity
molecular
dimensions.
Controllable
defects
transformed
localized
emission
porphyrin
into
ligand‐metal
charge
transferring
(LMCT)
gradual
loss
ligand
molecules,
which
interrupted
upon
coordination
agents,
triggering
a
red
turn‐on
fluorescence.
Thus,
defective
60%
effectively
discriminates
(e.g.,
sarin,
soman)
from
similar
substances
tabun,
venomous
agent
X)
synergistic
effect
dimension.
It
exhibits
sensitive
(0.96
n
m
/3.8
ppb),
rapid
(<1
s)
response
toward
target
robust
environmental
interference
acidic,
humid
common
substances.
This
work
enhances
understanding
MOFs
correpsonding
luminescent
behavior,
paving
new
avenue
for
strategy
trace
real
vapor.
ACS Nano,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 9, 2025
Recently,
electrically
conductive
metal–organic
frameworks
(EC-MOFs)
have
emerged
as
a
wealthy
library
of
porous
with
unique
properties,
allowing
their
use
in
diverse
applications
energy
conversion,
including
electrocatalysis.
In
this
review,
the
electron
conduction
mechanisms
EC-MOFs
are
examined,
while
electrical
conductivities
considered.
There
been
various
strategies
to
enhance
MOFs
ligand
modification,
incorporation
conducting
materials,
and
construction
multidimensional
architectures.
With
sufficient
being
established
for
EC-MOFs,
there
extensive
pursuits
electrocatalysis
applications,
such
hydrogen
evolution
reaction,
oxygen
reduction
N2
CO2
reaction.
addition,
computational
modeling
also
exerts
an
important
impact
on
revealing
synthesis–structure–performance
relationships.
Finally,
prospects
current
challenges
discussed
provide
guidelines
designing
promising
framework
materials.
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(47), P. 32206 - 32221
Published: Nov. 14, 2024
Long-range
charge
transport
(LRCT)
in
molecular
wires
is
crucial
for
the
advancement
of
electronics
but
remains
insufficiently
understood
due
to
complex
mechanisms
and
their
dependencies
on
structure.
While
short-range
typically
dominated
by
off-resonant
tunneling,
which
decays
exponentially
with
length,
recent
studies
have
highlighted
certain
structures
that
facilitate
LRCT
minimal
attenuation
over
several
nanometers.
This
Perspective
reviews
latest
progress
understanding
LRCT,
focusing
chemical
designs
enable
this
phenomenon.
Key
strategies
include
π-conjugation,
redox-active
centers,
stabilization
radical
intermediates,
support
through
such
as
coherent
resonant
tunneling
or
incoherent
hopping.
We
discuss
how
effects
structure,
temperature
influence
transport,
highlight
emerging
techniques
like
Seebeck
effect
distinguishing
between
mechanisms.
By
clarifying
principles
behind
outlining
future
challenges,
work
aims
guide
design
systems
capable
sustaining
efficient
long-distance
thereby
paving
way
practical
applications
beyond.
Dalton Transactions,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Semiconductor
metal
oxides
detect
H
2
even
at
the
ppm
level
but
need
high
temperatures
and
oxygen.
MOFs/COFs
higher
concentrations,
work
lower
temperatures,
perform
very
well
under
inert
conditions.
Advanced Energy Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 28, 2025
Abstract
At
present,
electronic
devices
such
as
electric
vehicles
and
mobile
phones
have
increasing
requirements
for
battery
energy
density.
Lithium–sulfur
batteries
(LSBs)
a
high
theoretical
density
are
considered
potential
choice
realizing
the
next
generation
of
(2600
W
h
kg
−1
)
batteries.
However,
actual
LSBs
is
much
lower
than
due
to
poor
conductivity
sulfur,
serious
LiPSs
shuttle,
low
sulfur
utilization,
so
on.
Many
lightweight
materials
characterized
by
surface
area
designability.
The
reasonable
design
modify
can
reduce
proportion
inactive
substances
optimizing
electrochemical
performance,
which
crucial
improving
LSBs.
few
reviews
discuss
effect
on
from
perspective
whole
system.
Herein,
application
in
six
aspects:
liquid
electrolyte,
solid
cathode,
anode,
separator,
current
collector
discussed.
significance
use
further
improvement
summarized
prospected.
Polymer Engineering and Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 16, 2025
Abstract
Slow
rebound
polyurethane
foam
(SPUF)
has
developed
rapidly
because
of
its
excellent
performance
in
sound
insulation,
energy
absorption,
and
tactile
sensation.
However,
the
friction‐induced
electrostatic
charge
accumulation
occurs
easily
due
to
high
resistivity.
In
this
paper,
dimethyl
octadecyl
hydroxy
ethyl
ammonium
nitrate
(SN)
intercalated
reduced
graphene
oxide
(SN‐RGO)
were
prepared
as
conductive
agent.
The
antistatic
slow
(ASR‐PUF)
was
with
SN‐RGO/carbon
black
system
silicone‐modified
polyethylene
glycol
(Si‐APEG)
low
temperature
resistant
structures
SN‐RGO
investigated
by
Fourier
transform
infrared
spectra
(FT‐IR),
wide‐angle
X‐ray
diffraction
(WAXD),
scanning
electron
microscope
(SEM),
respectively.
effects
on
structures,
mechanical
properties,
low‐temperature
resistance,
property
ASR‐PUF
studied.
It
found
that
acts
heterogeneous
cell
nucleating
agent,
which
slightly
increases
apparent
core
density
decreases
porosity
ASR‐PUF.
addition
both
tensile
strength
elongation
at
break
ASR‐PUF,
little
effect
sensitive
index.
surface
resistance
1.1
×
10
8
Ω
a
content
4
wt%,
thereby
achieving
an
effect.
Highlights
agent
PU
foaming.
provide
good
properties
without
affecting
appropriate
exhibits
comprehensive
performance.
