Advances in Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 103499 - 103499
Published: March 1, 2025
Language: Английский
Small, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 20, 2024
Abstract Aqueous zinc metal batteries (AZMBs) are emerging as a powerful contender in the realm of large‐scale intermittent energy storage systems, presenting compelling alternative to existing ion battery technologies. They harness benefits zinc's high safety, natural abundance, and favorable electrochemical potential (−0.762 V vs Standard hydrogen electrode, SHE), alongside an impressive theoretical capacity (820 mAh g −1 5655 cm −3 ). However, performance ZMBs is impeded by several challenges, including poor compatibility with high‐loading cathodes persistent side reactions. These issues intricately linked inherent physicochemical properties anodes (ZMAs). Here, this review delves into traditional methods ZMAs production, encompassing extraction, electrodeposition, rolling processes. The discussion then progresses exploration cutting‐edge methodologies designed enhance ZMAs. categorized alloying, pre‐treatment substrate, advanced electrodeposition techniques, development composite utilizing powder. offers comparative analysis merits drawbacks various optimization strategies, highlighting beneficial outcomes achieved. It aspires inspire novel concepts for advancement innovation next‐generation zinc‐based solutions.
Language: Английский
Citations
10
ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 4, 2025
Gradient porous carbon has become a potential electrode material for energy storage devices, including the aqueous zinc-ion hybrid capacitor (ZIHC). Compared with sufficient studies on fabrication of ZIHCs high electrochemical performance, there is still lack in-depth understanding underlying mechanisms gradient structure storage, especially synergistic effect ultramicropores (<1 nm) and micropores (1-2 nm). Here, we report design principle used ZIHC based data-mining machine learning (ML) method. It clarified that combination 0.6-0.9 nm ultramicropore 1.6 micropore achieves highest specific capacity. Molecular dynamic simulation was further employed to investigate electric double-layer structures in several kinds electrified electrode/electrolyte interface. found Zn
Language: Английский
Citations
1
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160086 - 160086
Published: Feb. 1, 2025
Language: Английский
Citations
1
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 21, 2025
Abstract Developing sustainable energy storage systems is crucial for integrating renewable sources into the power grid. Aqueous zinc‐ion batteries (ZIBs) are becoming increasingly popular due to their safety, eco‐friendliness, and cost‐effectiveness. However, challenges remain in achieving realistic time per charge, long cycling life, high capacity practical conditions. Despite advancements cathode materials, issues such as dissolution side reactions limit performance. Optimizing architecture electrolyte composition essential address these challenges. Tailored formulations can stabilize electrode‐electrolyte interface (EEI enhance stability. This perspective reviews cathodes from past decades compares performance under different current densities. Emphasizing low density extended stability widespread adoption of ZIBs grid‐scale applications. By focusing on aspects, this aims bridge gap between research applications, offering insights optimizing material structure selecting matching electrolytes storage. work guides future developments ZIB technology, facilitating transition lab real‐world deployment.
Language: Английский
Citations
1
Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104161 - 104161
Published: March 1, 2025
Language: Английский
Citations
1
ACS Nano, Journal Year: 2025, Volume and Issue: unknown
Published: March 19, 2025
Rechargeable aqueous cadmium (Cd) metal batteries enabled by the Cd plating and stripping behaviors of anode show great promise for next-generation energy storage applications due to superior corrosion resistance, high specific capacity (476.5 mAh g-1), suitable redox potential (-0.4 V vs standard hydrogen electrode), cost-effectiveness anode. However, this field is still in its infancy, with limited scientific exploration numerous unresolved challenges. Therefore, bridge existing research gap batteries, study conducted a comprehensive investigation into electrochemical performance metal, utilizing stable low-cost CdSO4 solution as an electrolyte. It revealed that solvation structure Cd2+ transitions from [Cd(H2O)9]2+ [Cd(H2O)6(SO4)3]4- concentration increases 0.5 3 M. This transition reduces activity H2O around Cd2+, promotes charge transfer, enhances desolvation/solvation kinetics during plating/stripping processes. Consequently, when reached nearly saturated M, presents optimal corrosion-resistant dendrite-free capabilities, reflecting durable over 2000 h Coulombic efficiency 99.7%. Furthermore, Cd//V2O5 full cell achieves ultralong cycle life, maintaining 30,000 cycles minimal degradation. The reversibility exceptional affirm electrolyte foundation future development offering profound insights guidance advancing technology.
Language: Английский
Citations
1
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 24, 2025
Abstract Despite the advantages of low cost, safety, and environmental friendliness, aqueous zinc‐ion batteries (AZIBs) encounter challenges such as zinc dendrite formation, severe side reactions, electrolyte instability. Many effective additives exhibit limited solubility in water, thus reducing their practical application potential. In this study, a dissolution‐promoting strategy is proposed by introducing citric acid (CA) to enhance dissolution aspartame (APM), resulting sulfate electrolyte. Simulations experiments indicate that CA regulates both solvation structure Zn 2+ pH electrolyte, while APM preferentially integrates into electric double layer form solid interphase with CA, thereby suppressing hydrogen evolution reactions. Consequently, zinc‐zinc symmetric cell exhibits an extended lifespan over 4,500 h at 1.0 mA cm −2 /1.0 mAh . As result, AZIBs commercial foil MnO 2 enhanced rate capability improved capacity retention (75.6%) after 2,000 cycles. This study presents novel for stabilizing anodes offers comprehensive framework addressing fundamental AZIBs, advancing next‐generation energy storage systems.
Language: Английский
Citations
1
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 24, 2024
Abstract The application of zinc‐ion batteries (ZIBs) is seriously challenged by the poor stability Zn anode and cathode in aqueous solution, which closely associated with electrolyte structure water reactivity. Herein, issues both for can be simultaneously addressed via tuning solvation hybrid tripropyl phosphate (TPP) as co‐solvent. On anode, a robust poly‐inorganic solid interphase (SEI) layer comprised 3 (PO 4 ) 2 ‐ZnS‐ZnF species situ formed, effectively suppressing parasitic reaction dendrite evolution. For V O 5 cathode, notorious vanadium dissolution restricted improved achieved. optimized facilitates reversible redox kinetics at anode. Consequently, Zn||Zn cells display extended cycling lifespans over 3000 h 1 mA cm −2 , mAh . Zn||V full deliver high capacity 261.8 g −1 hold retention 73.6% upon 500 cycles even operated harsh conditions thin (10 µm) low negative/positive (N/P) ratio ≈4.3, also showcase impressive performance regard to rate storage performance, further emphasizing potential regulation tactics advancing commercialization ZIBs.
Language: Английский
Citations
7
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 1, 2024
Language: Английский
Citations
5
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 684, P. 439 - 448
Published: Jan. 7, 2025
Language: Английский
Citations
0