Room temperature phase transition and luminescence behavior of a novel metal‐free ionic crystal [C7H16NO][ClO4] DOI
Xian Shi, Xiu‐Ni Hua, Zhuoer Cai

et al.

Zeitschrift für anorganische und allgemeine Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 9, 2024

Abstract Metal‐free ionic crystals have attracted tremendous attention for their environmental friendliness, biocompatibility, easy fabrication and structural variability. Herein, a metal‐free crystal [C 7 H 16 NO][ClO 4 ] ([C NO]=1‐methyl‐4‐piperidinemethanol) with dielectric transition at room temperature was designed constructed. Differential scanning calorimetry (DSC) proved that there exists reversible phase near 304 K, accompanied switchable behaviors between the low high states. The single structure show mechanism of such mainly results from dynamic motion perchlorate anions. compound is further shown to exhibit remarkable luminescent properties, characterized by prolonged lifetime 18.6 ns. This work offers valuable insights into construction phase‐transition involved switching blue luminescence properties.

Language: Английский

A novel Zero-Dimensional trimer framework with dielectric switching Characteristic in Organic-Inorganic hybrid materials DOI
Jian Chen, Zhuoer Cai, Yinan Zhang

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114642 - 114642

Published: May 1, 2025

Language: Английский

Citations

0
The phytochemical plumbagin: mechanism behind its “pleiotropic” nature and potential as an anticancer treatment DOI

Shikshya Swarupa Panda,

Bijesh K. Biswal

Archives of Toxicology, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 13, 2024

Language: Английский

Citations

1
Room temperature phase transition and luminescence behavior of a novel metal‐free ionic crystal [C7H16NO][ClO4] DOI
Xian Shi, Xiu‐Ni Hua, Zhuoer Cai

et al.

Zeitschrift für anorganische und allgemeine Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 9, 2024

Abstract Metal‐free ionic crystals have attracted tremendous attention for their environmental friendliness, biocompatibility, easy fabrication and structural variability. Herein, a metal‐free crystal [C 7 H 16 NO][ClO 4 ] ([C NO]=1‐methyl‐4‐piperidinemethanol) with dielectric transition at room temperature was designed constructed. Differential scanning calorimetry (DSC) proved that there exists reversible phase near 304 K, accompanied switchable behaviors between the low high states. The single structure show mechanism of such mainly results from dynamic motion perchlorate anions. compound is further shown to exhibit remarkable luminescent properties, characterized by prolonged lifetime 18.6 ns. This work offers valuable insights into construction phase‐transition involved switching blue luminescence properties.

Language: Английский

Citations

0