Synthesis of Cyclic (Alkyl)(amino)carbene-Stabilized Copper–Iron Heterobimetallic Complexes and Their Application in Pyridine Hydroboration DOI
Ankita Sharma, Vikas Tiwari, Ritu Yadav

et al.

Organometallics, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

In this report, we synthesized heterobimetallic complexes supported by cyclic and bicyclic (alkyl)(amino)carbenes (CAAC EtBICAAC) [(Me2CAAC)CuFe(η5-C5H5)(CO)2](1) [(EtBICAAC)CuFe(η5-C5H5)(CO)2] (2), respectively, featuring an iron–copper bond. Complex 1 demonstrates catalytic activity for selective 1,4-hydroboration reactions of pyridine derivatives. Detailed computational studies provide additional insights into the electronic structure 2 elucidate pathway.

Language: Английский

Synthesis of Cyclic (Alkyl)(amino)carbene-Stabilized Copper–Iron Heterobimetallic Complexes and Their Application in Pyridine Hydroboration DOI
Ankita Sharma, Vikas Tiwari, Ritu Yadav

et al.

Organometallics, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

In this report, we synthesized heterobimetallic complexes supported by cyclic and bicyclic (alkyl)(amino)carbenes (CAAC EtBICAAC) [(Me2CAAC)CuFe(η5-C5H5)(CO)2](1) [(EtBICAAC)CuFe(η5-C5H5)(CO)2] (2), respectively, featuring an iron–copper bond. Complex 1 demonstrates catalytic activity for selective 1,4-hydroboration reactions of pyridine derivatives. Detailed computational studies provide additional insights into the electronic structure 2 elucidate pathway.

Language: Английский

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